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J Hazard Mater ; 118(1-3): 259-63, 2005 Feb 14.
Artigo em Inglês | MEDLINE | ID: mdl-15721553

RESUMO

Activated carbon has been prepared from molasses, a natural precursor of vegetable origin resulting from the sugar industry in Morocco. The preparation of the activated carbon from the molasses has been carried out by impregnation of the precursor with sulphuric acid, followed by carbonisation at varying conditions (temperature and gas coverage) in order to optimize preparation parameters. The influence of activation conditions was investigated by determination of adsorption capacity of methylene blue and iodine, the BET surface area, and the pore volume of the activated carbon were determined while the micropore volume was determined by the Dubinin-Radushkevich (DR) equation. The activated materials are mainly microporous and reveal the type I isotherm of the Brunauer classification for nitrogen adsorption. The activated carbons properties in this study were found for activation of the mixture (molasses/sulphuric acid) in steam at 750 degrees C. The samples obtained in this condition were highly microporous, with high surface area (> or =1200 m2/g) and the maximum adsorption capacity of methylene blue and iodine were 435 and 1430 mg/g, respectively.


Assuntos
Carbono/isolamento & purificação , Melaço , Adsorção , Indústria Alimentícia , Porosidade , Ácidos Sulfúricos/química , Temperatura , Eliminação de Resíduos Líquidos
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