Cellulose cryogels from herbal residues for oily wastewater purification.

Recycling herbal residues for oily wastewater purification is a potential way to use the wastes to treat wastes. Cellulose extracted from herbal residues is a fine material for cryogel fabrication. However, the cellulose cryogels were not suitable for oily wastewater treatment due to their amphiphilicity. To address this issue, the cryogels were modified with methyltrimethoxysilane (MTMS), which made them hydrophobic and reduced their surface energy. In this study, the herbal residues (Ficus microcarpa L. f) were used in cryogel preparation for the first time. The cryogels exhibit super lightweight and low density. The modified cryogels show excellent sorption capacity for free oils, especially silicone oil (51.22 g/g), and outperformed some recent sorbents. They also effectively separated water-in-toluene emulsion stabilized by Span 80, with a separation efficiency of 98.57 % and a flux of 1474.67 L/m2h. This study demonstrated a novel application of waste herbal residues in the field of environmental remediation.

High-performance biochar derived from the residue of Chaga mushroom (Inonotus obliquus) for pollutants removal.

A high-performance biochar derived from the residue of Chaga mushroom (Inonotus obliquus) was reported in this study. Inonotus obliquus residues were used to prepare biochar, and the optimal synthesis conditions were obtained by response surface methodology. The specific surface area, pore volume, and average pore size of the optimal biochar (Zn-IORBC) was 1676.78 m2/g, 1.87 cm3/g, and 3.88 nm, respectively. Methylene blue (MB) and tetracycline (TC) were selected to estimate the adsorption performance of Zn-IORBC. The adsorption process was suitable for the pseudo-second-order model and Langmuir model. Zn-IORBC could maintained a large amount of TC adsorption (the lowest value was 686.20 mg/g in mountain spring water) in different natural water. The maximum adsorption capacity of TC and MB was 947.42 and 1033.66 mg/g. The adsorption mechanism was contributed to the electrostatic attraction, hydrogen bonding, π-π interactions, and pore-filling. Zn-IORBC is an effective adsorbent for high-performance pollutants removal.