Can groundwater be protected from the pressure of china's urban growth?

Groundwater is expected to be more vulnerable to water-quality degradation in the future due to rapid urbanization. However, despite knowledge that protecting future groundwater resources is necessary for sustainable groundwater resource development, little is known about the role of groundwater policy in influencing the spatial distribution of urbanization. This study sheds light on how a policy that protects vulnerable groundwater could affect the distribution of urban expansion. Groundwater vulnerability to pollution under future climate change scenarios is used as a factor to generate urban expansion probability maps for China. The results indicate that there will be a significant and uneven urban growth by 2030, if current trends in urban expansion continue. The amount of urban land in 2030 will range from 2.9 to 4.2 times the urban area in 2010. Meanwhile, the urban expansion probability maps for projections with and without consideration of groundwater vulnerability in urban suitability are compared. The comparation shows that consideration of a groundwater policy would significantly alter the future spatial distribution of urban areas. Even with a weight of only 10% for groundwater vulnerability in the urban suitability consideration, the percentage of change area in the urban expansion probability distribution map can be as high as 60%. The probabilities of urban expansion are forecast to gradually transfer from the southeast coastal areas to inland areas as higher weight (from 10% to 50%) of groundwater vulnerability is given to urban suitability consideration. Our study demonstrates that groundwater protection from urbanization pressures can be achieved, provides support for policy and decision makers in evaluating options to modify existing urban expansion policies, and concludes that groundwater protection at the macro-scale is an appropriate policy goal.

Groundwater Complexity in Urban Catchments: Shenzhen, Southern China.

Groundwater interactions with surface water and sewers in an urban setting are complex, and classic hydrogeological approaches must be combined with anthropogenic elements to characterize them. The level of detail needed to understand these interactions is illustrated by the analysis of an urban subcatchment in the megacity of Shenzhen in southern China that has had a drastic urban expansion in the last 40 years. The study area is characterized by the Yanshanian granite that is widespread across southern-eastern China. The urban setting is studied using multitemporal analysis of satellite images, borehole investigations and field surveys. Given the local hydrostratigraphy, a conceptual model was developed to identify the physical and anthropogenic factors that regulate the urban groundwater system. Based on the conceptual model and the data collected from the field or compiled from the literature, the average annual effective recharge is estimated to be 290 mm/year, after the urbanization process. From rural to urban conditions, it is estimated that the effective recharge increased by 170% and sewers intercept at least 23% of the effective recharge. Groundwater captured by sewers reduces river flows and increases the required capacity and costs for waste water treatment plants.

Exploring the utility of Bayesian Networks for modelling cultural ecosystem services: A canoeing case study.

Modelling cultural ecosystem services is challenging as they often involve subjective and intangible concepts. As a consequence they have been neglected in ecosystem service studies, something that needs remedying if environmental decision making is to be truly holistic. We suggest Bayesian Networks (BNs) have a number of qualities that may make them well-suited for dealing with cultural services. For example, they define relationships between variables probabilistically, enabling conceptual and physical variables to be linked, and therefore the numerical representation of stakeholder opinions. We assess whether BNs are a good method for modelling cultural services by building one collaboratively with canoeists to predict how the subjective concepts of fun and danger are impacted on by weir modification. The BN successfully captured the relationships between the variables, with model output being broadly consistent with verbal descriptions by the canoeists. There were however a number of discrepancies indicating imperfect knowledge capture. This is likely due to the structure of the network and the abstract and laborious nature of the probability elicitation stage. New techniques should be developed to increase the intuitiveness and efficiency of probability elicitation. The limitations we identified with BNs are avoided if their structure can be kept simple, and it is in such circumstances that BNs can offer a good method for modelling cultural ecosystem services.

Integrated modelling for Sustainability Appraisal of urban river corridors: going beyond compartmentalised thinking.

Sustainability Appraisal (SA) is a complex task that involves integration of social, environmental and economic considerations and often requires trade-offs between multiple stakeholders that may not easily be brought to consensus. Classical SA, often compartmentalised in the rigid boundary of disciplines, can facilitate discussion, but can only partially inform decision makers as many important aspects of sustainability remain abstract and not interlinked. A fully integrated model can overcome compartmentality in the assessment process and provides opportunity for a better integrative exploratory planning process. The objective of this paper is to explore the benefit of an integrated modelling approach to SA and how a structured integrated model can be used to provide a coherent, consistent and deliberative platform to assess policy or planning proposals. The paper discusses a participative and integrative modelling approach to urban river corridor development, incorporating the principal of sustainability. The paper uses a case study site in Sheffield, UK, with three alternative development scenarios, incorporating a number of possible riverside design features. An integrated SA model is used to develop better design by optimising different design elements and delivering a more sustainable (re)-development plan. We conclude that participatory integrated modelling has strong potential for supporting the SA processes. A high degree of integration provides the opportunity for more inclusive and informed decision-making regarding issues of urban development. It also provides the opportunity to reflect on their long-term dynamics, and to gain insights on the interrelationships underlying persistent sustainability problems. Thus the ability to address economic, social and environmental interdependencies within policies, plans, and legislations is enhanced.

Assessing TCE source bioremediation by geostatistical analysis of a flux fence.

Mass discharge across transect planes is increasingly used as a metric for performance assessment of in situ groundwater remediation systems. Mass discharge estimates using concentrations measured in multilevel transects are often made by assuming a uniform flow field, and uncertainty contributions from spatial concentration and flow field variability are often overlooked. We extend our recently developed geostatistical approach to estimate mass discharge using transect data of concentration and hydraulic conductivity, so accounting for the spatial variability of both datasets. The magnitude and uncertainty of mass discharge were quantified by conditional simulation. An important benefit of the approach is that uncertainty is quantified as an integral part of the mass discharge estimate. We use this approach for performance assessment of a bioremediation experiment of a trichloroethene (TCE) source zone. Analyses of dissolved parent and daughter compounds demonstrated that the engineered bioremediation has elevated the degradation rate of TCE, resulting in a two-thirds reduction in the TCE mass discharge from the source zone. The biologically enhanced dissolution of TCE was not significant (~5%), and was less than expected. However, the discharges of the daughter products cis-1,2, dichloroethene (cDCE) and vinyl chloride (VC) increased, probably because of the rapid transformation of TCE from the source zone to the measurement transect. This suggests that enhancing the biodegradation of cDCE and VC will be crucial to successful engineered bioremediation of TCE source zones.

Bringing diverse knowledge sources together--a meta-model for supporting integrated catchment management.

Integrated catchment management (ICM), as promoted by recent legislation such as the European Water Framework Directive, presents difficult challenges to planners and decision-makers. To support decision-making in the face of high complexity and uncertainty, tools are required that can integrate the evidence base required to evaluate alternative management scenarios and promote communication and social learning. In this paper we present a pragmatic approach for developing an integrated decision-support tool, where the available sources of information are very diverse and a tight model coupling is not possible. In the first instance, a loosely coupled model is developed which includes numerical sub-models and knowledge-based sub-models. However, such a model is not easy for decision-makers and stakeholders to operate without modelling skills. Therefore, we derive from it a meta-model based on a Bayesian Network approach which is a decision-support tool tailored to the needs of the decision-makers and is fast and easy to operate. The meta-model can be derived at different levels of detail and complexity according to the requirements of the decision-makers. In our case, the meta-model was designed for high-level decision-makers to explore conflicts and synergies between management actions at the catchment scale. As prediction uncertainties are propagated and explicitly represented in the model outcomes, important knowledge gaps can be identified and an evidence base for robust decision-making is provided. The framework seeks to promote the development of modelling tools that can support ICM both by providing an integrated scientific evidence base and by facilitating communication and learning processes.

Optimization of bacterial whole cell bioreporters for toxicity assay of environmental samples.

In a study to optimize bacterial whole cell biosensors (bioreporters) for the detection of environmental contaminants, we constructed a toxicity sensing strain Acinetobacter baylyi ADP1_recA_lux. The ADP1_recA_lux is a chromosomally based bioreporter which makes the sensing system stable and negates the need for antibiotics to maintain the trait. The AOP1_recA_lux is activated to express bioluminescence when it is exposed to DNA damaging toxicants. Since the ADP1_recA_lux constantly expresses a baseline level of bioluminescence, false negative results are avoided. The host strain, A. baylyi ADP1, is an ideal model strain typical of water and soil bacteria occurring in the natural environment, and it is more robust than E. coli in terms of viability, maintenance, and storage. The expression of reporter genes - luxCDABE cloned from Photorhabdus luminescens - is robust in a broad range of temperature (10-40 degrees C). The ADP1_recA_lux was used to detect a variety of toxic or potentially toxic compounds including mitomycin C (MMC), methyl methanesulfonate, ethidium bromide, H2O2, toluene, single-wall nanocarbon tubes (SWNCT), nano Au colloids (20 nm), pyrene, beno[a]pyrene, and UV light. These exposures revealed that the ADP1_recA_lux was able to detect both genotoxicity and cytoxicity, qualitatively and quantitatively. The optimal induction time of the ADP1_recA_lux bioreporter was 3 h, and the detection limits for MMC and benezo[a]pyrene were 1.5 nM and 0.4 nM, respectively. The ADP1_recA_lux was also used to detect toxicity of groundwater contaminated by a mixture of phenolic compounds, and the bioreporter toxicity detection was in a good agreement with chemical analysis. The optimized whole cell bioreporter ADP1_recA_lux could be valuable in providing a simple, rapid, stable, quantitative, robust, and costly efficient approach for the detection of toxicity in environmental samples.

Using secondary data to analyse socio-economic impacts of water management actions.

This paper provides an analysis of the socio-economic impacts of river restoration schemes, and is novel in considering how a wide range of socio-economic variables can be used to understand impacts on the entire resident population within an area. A control-impacted approach was applied to explore differences in socio-economic characteristics of areas within which a restoration scheme had been carried out compared to areas without such a scheme. The results show that significant differences exist between control and impacted areas for a range of socio-economic variables. However, due to constraints in the methods and the data available, there are currently limitations in the extent to which socio-economic impacts of river restoration schemes can be fully explored. Additional datasets that become available in the future may increase the ability to detect associations between improvements in the water environment and socio-economic benefits. However, whilst the secondary data used in this paper are potentially powerful, they should be used alongside other techniques for assessing the impacts of decisions as part of future frameworks to deliver sustainable water management.

Channel flow and trichloroethylene treatment in a partly iron-filled fracture: experimental and model results.

Technical developments have now made it possible to emplace granular zero-valent iron (Fe(0)) in fractured media to create a Fe(0) fracture reactive barrier (Fe(0) FRB) for the treatment of contaminated groundwater. To evaluate this concept, we conducted a laboratory experiment in which trichloroethylene (TCE) contaminated water was flushed through a single uniform fracture created between two sandstone blocks. This fracture was partly filled with what was intended to be a uniform thickness of iron. Partial treatment of TCE by iron demonstrated that the concept of a Fe(0) FRB is practical, but was less than anticipated for an iron layer of uniform thickness. When the experiment was disassembled, evidence of discrete channelised flow was noted and attributed to imperfect placement of the iron. To evaluate the effect of the channel flow, an explicit Channel Model was developed that simplifies this complex flow regime into a conceptualised set of uniform and parallel channels. The mathematical representation of this conceptualisation directly accounts for (i) flow channels and immobile fluid arising from the non-uniform iron placement, (ii) mass transfer from the open fracture to iron and immobile fluid regions, and (iii) degradation in the iron regions. A favourable comparison between laboratory data and the results from the developed mathematical model suggests that the model is capable of representing TCE degradation in fractures with non-uniform iron placement. In order to apply this Channel Model concept to a Fe(0) FRB system, a simplified, or implicit, Lumped Channel Model was developed where the physical and chemical processes in the iron layer and immobile fluid regions are captured by a first-order lumped rate parameter. The performance of this Lumped Channel Model was compared to laboratory data, and benchmarked against the Channel Model. The advantages of the Lumped Channel Model are that the degradation of TCE in the system is represented by a first-order parameter that can be used directly in readily available numerical simulators.

Biodegradation processes in a laboratory-scale groundwater contaminant plume assessed by fluorescence imaging and microbial analysis.

Flow reactors containing quartz sand colonized with biofilm were set up as physical model aquifers to allow degrading plumes of acetate or phenol to be formed from a point source. A noninvasive fluorescent tracer technique was combined with chemical and biological sampling in order to quantify transport and biodegradation processes. Chemical analysis of samples showed a substantial decrease in carbon concentration between the injection and outflow resulting primarily from dilution but also from biodegradation. Two-dimensional imaging of the aqueous oxygen [O2(aq)] concentration field quantified the depletion of O2(aq) within the contaminant plume and provided evidence for microbial respiration associated with biodegradation of the carbon source. Combined microbiological, chemical, and O2(aq) imaging data indicated that biodegradation was greatest at the plume fringe. DNA profiles of bacterial communities were assessed by temperature gradient gel electrophoresis, which revealed that diversity was limited and that community changes observed depended on the carbon source used. Spatial variation in activity within the plume could be quantitatively accounted for by the changes observed in active cell numbers rather than differences in community structure, the total biomass present, or the increased enzyme activity of individual cells. Numerical simulations and comparisons with the experimental data were used to test conceptual models of plume processes. Results demonstrated that plume behavior was best described by growth and decay of active biomass as a single functional group of organisms represented by active cell counts.

A modelling approach to determine the origin of urban ground water.

A simple modelling approach was developed to link patterns of urban land-use with ground water flow and chemistry in three dimensions and was applied to characterize the origin of recharge in the aquifer beneath the old industrial city of Nottingham, UK. The approach involved dividing land uses into types, and times into periods, and assigning the recharge from each an individual tracer-solute with a unit concentration. The computer code MT3DMS was used to track the multiple tracer-solutes in transient, three-dimensional simulations of the important urban aquifer. A depth-specific hydrochemical dataset collected in parallel supported the model predictions. At depth under the industrial area studied, a large component of ground water originated of older agricultural origin, with relatively low nitrate concentrations. Shallower ground water originated mainly from residential and industrial areas, with higher nitrate concentrations probably arising from leaking sewers and contaminated land. The results highlighted the spectrum of ground water from different origins that amalgamate even at short well screens in a non-pumped borehole and remind us that the non-point-source pollution of ground water from anthropogenic activities will involve more years of slow degradation of quality.

Evaluating the risks of methyl tertiary butyl ether (MTBE) pollution of urban groundwater.

MTBE, a fuel oxygenate added to gasoline in parts of the USA, appears to have imposed significant adverse impacts on groundwater. In the UK, the impacts of MTBE are not well known in part because insufficient data has been presented to allow an accurate assessment. With the recognition of urban groundwater as a potentially valuable resource due to the growing pressure on rural groundwater, there is need for pollution risks to urban groundwater to be evaluated for contaminants such as MTBE. This paper presents the application of a risk-based water management tool called Borehole Optimisation System (BOS) in the evaluation of the risk of MTBE to urban groundwater at city scale using Nottingham city as our case study. The risk model was validated by comparison of its predictions with observations of MTBE detections for about 1100 boreholes in England and Wales. The output of the risk analysis was the production of a map showing the predicted MTBE concentration at all locations in the city. The results indicate that MTBE does not currently pose a major risk to urban groundwater although there may be a potential risk to groundwater in the southern part of the city where most industries are concentrated.

Persistence of fermentative process to phenolic toxicity in groundwater.

The fermentation process is an important component in the biodegradation of organic compounds in natural and contaminated systems. Comparing with terminal electron-accepting processes (TEAPs), however, research on fermentation processes has to some extent been ignored in the past decades, particularly on the persistence of fermentation process in the presence of toxic organic pollutants. Both field and laboratory studies, presented here, showed that microbial processes in a groundwater-based system exhibited a differential inhibitory response to toxicity of phenolic compounds from coal tar distillation, thus resulting in the accumulation of volatile fatty acids (VFAs) and hydrogen. This indicated that fermentation processes could be more resistant to phenol toxicity than the subsequent TEAPs such as methanogenesis and sulfate reduction, thus providing us with more options for enhancing bioremediation processes.

The impact of additives found in industrial formulations of TCE on the wettability of sandstone.

The wettability of aquifer rocks is a key physical parameter which exerts an important control on the transport, residual trapping, distribution and eventual fate of chlorinated hydrocarbon solvents (CHSs) released into the subsurface. Typically chlorinated solvents are assumed to be non-wetting in water saturated rocks and unconsolidated sediments. However industrially formulated solvent products are often combined with basic additives such as alkylamines to improve their performance; and the mineral surfaces of aquifer rocks and sediments usually possess a range of acid and hydrogen-bonding adsorption sites. The presence of these sites provides a mechanism whereby the basic additives in CHSs can be adsorbed at the solvent phase/solid phase interface. Given the amphiphilic molecular structure of these additives, this may result in changes in the wetting conditions of the solid phase. The aim of this study was therefore to test this conjecture for two classes of additives (alkylamines and quaternary ammonium salts) that are often encountered in industrial solvent formulations. Wettability assessments were made on sandstone cores by means of measurements of spontaneous and forced water drainage and spontaneous and forced water imbibition and through contact angle measurements on a smooth quartz surface. No solvent/additive combination produced solvent wetting conditions, though dodecylamine and octadecylamine significantly reduced the water wetting preference of sandstone which frequently resulted in neutral wetting conditions. The large volume of spontaneous water drainage observed in wettability experiments involving cetyltrimethylammonium bromide and octadecyltrimethylammonium bromide, suggested that the sandstone cores in these tests remained strongly water wetting. However equilibrium static contact angles of around 60 degrees were measured on quartz suggesting that the sandstone surfaces should be close to neutral wetting conditions. This paradox was finally resolved by noting that contact between the solvent mixture and water in the sandstone core resulted in a final solvent phase which had an extremely low interfacial tension. It is therefore suspected that the observed spontaneous drainage of solvent from the core was driven by gravitational and buoyancy forces rather than strong water wetting conditions. Finally it was noted that the mobilisation of iron oxide coatings from the sandstone surface had a considerable influence in reducing the interfacial tension and in the formation and stabilisation of TCE/water emulsions.

Non-agricultural sources of groundwater nitrate: a review and case study.

Nitrate is often seen as an agricultural pollutant of groundwater and so is expected to be at higher concentrations in the groundwaters surrounding a city than in those beneath it. However the difference between rural and urban nitrate concentrations is often small, due to the non-agricultural sources of nitrogen that are concentrated in cities. This paper illustrates the source and significance of non-agricultural nitrogen for groundwater and presents a case study of nitrate loading in the city of Nottingham. Major sources of nitrogen in urban aquifers are related to wastewater disposal (on-site systems and leaky sewers), solid waste disposal (landfills and waste tips). The major sources of nitrogen in the Nottingham area are mains leakage and contaminated land with approximately 38% each of a total load of 21 kg N ha(-1) year(-1).

Dissolved oxygen imaging in a porous medium to investigate biodegradation in a plume with limited electron acceptor supply.

A novel combination of noninvasive imaging with an oxygen sensitive fluorescent indicator was developed to investigate the biodegradation processes occurring at the fringe of a solute plume, where the supply of oxygen was limited. A thin transparent porous matrix (156 x 120 x 3 mm) was made from quartz plates and quartz sand (212-300 microm) and enriched with acetate-degrading bacteria. A degrading plume developed from a continuous acetate source in the uniform flow field containing dissolved oxygen. Ruthenium (II)-dichlorotris(1,10-phenanthroline) (Ru(phen)3Cl2), a water-soluble fluorescent dye, was used as an indicator of dissolved oxygen. The fluorescence intensity was dependent on the concentration of oxygen because the dissolved oxygen acted as collisional quencher. The oxygen distribution was interpreted from images recorded by a CCD camera. These two-dimensional experimental results showed quantitatively how the oxygen concentrations decreased strongly at the narrow plume fringe and that oxygen was depleted at the core of the plume. Separately, dispersivity was measured in a series of nonreactive transport experiments, and biodegradation parameters were evaluated by batch experiments. Two-dimensional numerical simulations with MT3D/RT3D used these parameters, and the predicted oxygen distributions were compared with the experimental results. This measurement method provides a novel approach to investigate details of solute transport and biodegradation in porous media.

Changes in interfacial tension of chlorinated solvents following flow through U.K. soils and shallow aquifer material.

The interfacial tension (IFT) that arises at the interface between water and an immiscible organic liquid is a key parameter affecting the transport and subsequent fate of the organic liquid in water-saturated porous media. In this paper, data are presented that show how contact between a range of soil types and chlorinated hydrocarbon solvent (CHS) dense nonaqueous phase liquids (DNAPLs) can affect DNAPL/water IFT values. The soils examined are indicative of U.K. soil types and shallow aquifer materials. The solvents investigated were tetrachloroethylene (PCE) and trichloroethylene (TCE). Lab grade, recovered field DNAPL and industrial waste chlorinated solvent mixtures were used. The data from batch and column experiments invariably revealed that water/DNAPL IFT values change following contact with unsaturated soils. In the majority of cases, the IFT values increase following soil exposure. However, after contact with an organic-rich soil, the IFT of the lab grade solvents decreased. The experimental evidence suggests that these reductions are linked to the removal of organic material from the soil and its subsequent incorporation into the solvent IFT increases in the case of lab solvents are shown to be linked to the removal of stabilizers (added by the manufacturers to obviate degradation) that are removed by adsorption to soil mineral surfaces. Similarly, it is conjectured that adsorption of surface-active compounds from the industrial waste samples to soil surfaces is responsible for increases in the IFT in these samples. Finally, it was observed that invading CHSs are capable of dissolving and subsequently mobilizing in-situ soil contaminants. GC/MS analysis revealed these mobilized soil contaminants to be polyaromatic hydrocarbons and phthalate esters.

Microbial contamination of two urban sandstone aquifers in the UK.

Development of urban groundwater has historically been constrained by concerns about its quality. Rising urban water tables and overabstraction from rural aquifers in the UK have led to a renewed interest in urban groundwater, particularly the possibility of finding water of acceptable quality at depth. This study assessed the microbial quality of groundwater collected from depth-specific intervals over a 15-month period within the Permo-Triassic Sherwood Sandstone aquifers underlying the cities of Nottingham and Birmingham. Sewage-derived bacteria (thermotolerant coliforms, faecal streptococci and sulphite-reducing clostridia) and viruses (enteroviruses, Norwalk-like viruses, coliphage) were regularly detected to depths of 60 m in the unconfined sandstone and to a depth of 91 m in the confined sandstone. Microbial concentrations varied temporally and spatially but increased frequency of contamination with depth coincided with geological heterogeneities such as fissures and mudstone bands. Significantly, detection of Norwalk-like viruses and Coxsackievirus B4 in groundwater corresponded with seasonal variations in virus discharge to the sewer system. The observation of low levels of sewage-derived microbial contaminants at depth in the Triassic Sandstone aquifer is explained by the movement of infinitesimal proportions of bulk (macroscopic) groundwater flow along preferential pathways (e.g., fissures, bedding planes). The existence of very high microbial populations at source (raw sewage) and their extremely low detection limits at the receptor (multilevel piezometer) enable these statistically extreme (microscopic) flows to be traced. Rapid penetration of microbial contaminants into sandstone aquifers, not previously reported, highlights the vulnerability of sandstone aquifers to microbial contamination.

Physical modelling of solute transport in porous media: evaluation of an imaging technique using UV excited fluorescent dye.

The development and evaluation of a 2-dimensional physical model, which is designed to assist in the characterisation of complex solute transport problems in porous media, is described. The laboratory model is a transparent 2-dimensional porous media of nominal thickness and uses a non-invasive imaging technique in conjunction with a fluorescent dye tracer (sodium fluorescein) to monitor solute movements. Under ultraviolet (UV) illumination the dye emits visible light which is imaged by a CCD (Charge Coupled Device) camera. The image is processed to estimate the 2-dimensional distribution of tracer concentrations. The system can successfully model a simple contaminant plume within a homogenous porous matrix constructed from glass beads (60-100 microm). Experimental results show that transverse dispersion coefficient was 3.9 x 10(-10) m2/s when sodium fluorescein transported in porous matrix with a walter velocity of 5.71 x 10(-6) m/s. The low transverse dispersion coefficient suggests that the molecular diffusion of solute cannot be neglected under low velocity of the water. The advantages of using UV rather than an ordinary light system are a reduction in noise and experimental errors. Errors due to light dispersion within the model are shown to be negligible for the current model. Since contaminant with aromatic rings are usually fluorescent and biological samples can be labelled by fluorescent dye, this imaging technique using UV excited fluorescent dye will be used to investigate biodegradation process in porous media.