Benzo(a)pyrene parallel measurements in PM1 and PM2.5 in the coastal zone of the Gulf of Gdansk (Baltic Sea) in the heating and non-heating seasons.

Parallel measurements of PM1 and PM2.5 aerosols were conducted in the urbanized coastal zone of the southern Baltic Sea. The main aim of the research was to assess and determine annual, seasonal (heating and non-heating), and daily concentration variability of benzo(a)pyrene in aerosols, these being the most dangerous constituents to human health. The average annual concentration of benzo(a)pyrene (B(a)P) was equal to 2.6 ng·m-3 in PM1 and 4.6 ng·m-3 in PM2.5, and both values were several times higher than the level of 1 ng·m-3 which was set out in the CAFE Directive. High mean daily concentrations of B(a)P persisted for 50 and 65% of the study period in PM1 and PM2.5, respectively. In order to determine the sources of B(a)P in both aerosol fractions, organic (OC) and elemental (EC) carbon concentrations were examined. The highest concentrations of all carbon species were reported during the heating season under local or regional land advection and at low air temperatures. The origin of pollutants was the same and was primarily related to the combustion of fossil fuels in the communal-utility sector. During the non-heating period, the role of transportation, both land and marine, increased and may have been significant in creating higher concentrations of carbon compounds in PM1 and PM2.5. Regardless of the size of the aerosol fractions, B(a)P loads introduced into the Baltic coastal zone were several times higher during the heating period compared to the non-heating season. Graphical abstract ᅟ.

Factors determining dry deposition of total mercury and organic carbon in house dust of residents of the Tri-city and the surrounding area (Baltic Sea coast).

The purpose of this study was to find out what factors determine the deposition levels of mercury and organic carbon in household dust in the Tri-city region (southern Baltic Sea coast). Analyses were performed on samples collected over the period of 2 years, from 2013 to 2015, always in the heating season. The deposition of organic carbon was between 4and 210 mg m-2 month-1, while mercury deposition ranged from 4 to 1336 ng m-2 month-1. Deposition of mercury in household dust during the heating season was three times lower and deposition of organic carbon one and a half times lower than outdoor deposition obtained in the Baltic Sea region by other researchers. In the non-heating period, deposition of mercury in household dust was similar to outdoor deposition while deposition of OC was one and a half times higher. Both of the analyzed dust components reached higher deposition in rural areas than in cities, and both mercury and organic carbon were found to have higher deposition in single-family houses than in buildings housing several families. The increased level of OC was conditioned by the vicinity of the building to a road or street with a high level of traffic, and dust collected on the ground floor had higher Hg depositions. The presence of plants and pets, as well as smoking more than ten cigarettes per day, resulted in higher depositions of both the compounds present in household dust within the Tri-city region.

Identification of cyanobacteria and microalgae in aerosols of various sizes in the air over the Southern Baltic Sea.

Bioaerosols were collected between April and November 2015 on land (Gdynia) and at sea (Southwestern Baltic), using six-step microbiological pollutant sampler. It was determined that picoplanktonic cyanobacteria of the genus Synechococcus, Synechocystis, Aphanocapsa, Aphanothece, Microcystis, Merismopedia, Woronichinia and Cyanodictyon were the most commonly found in aerosols both over land and at sea. Chlorophyta were also numerous (Chlorella vulgaris, Stichococcus bacillaris), as were Bacillariophyta and Ochrophyta (Phaeodactylum sp., Navicula cf. perminuta and Nannochloropsis cf. gaditana). As primary production and phytoplankton concentration in sea water grew, so did the diversity of the microorganisms identified in bioaerosols. Over the sea cyanobacteria and microalgae occurred more often in large aerosols (>3.3µm). Over land they were mainly the components of smaller particles. In respirable particles species both capable of producing harmful secondary metabolites and potentially toxic ones were identified. We assume that bioaerosols pose the actual threat to human health in Baltic Sea region.