Self-Healing Transparent Poly(dimethyl)siloxane with Tunable Mechanical Properties: Toward Enhanced Aging Materials for Space Applications.

When exposed to the geostationary orbit, polymeric materials tend to degrade on their surface due to the appearance of cracks. Implementing the self-healing concept in polymers going to space is a new approach to enhancing the lifespan of materials that cannot be replaced once launched. In this study, the elaboration of autonomous self-healing transparent poly(dimethylsiloxane) (PDMS) materials resistant to proton particles is presented. The PDMS materials are functionalized with various compositions of urea and imine moieties, forming dynamic covalent and/or supramolecular networks. The hydrogen bonds induced by the urea ensure the formation of a supramolecular network, while the dynamic covalent imine bonds are capable of undergoing exchange reactions. Materials with a broad range of mechanical properties were obtained depending on the composition and structure of the PDMS networks. As coating applications in a spatial environment were mainly targeted, the surface properties of the polymer are essential. Thus, percentages of scratch recovery were determined by AFM. From these data, self-healing kinetics were extracted and rationalized based on the polymer structures. The obtained data were in good agreement with the relaxation times determined by rheology in stress relaxation experiments. Moreover, the accelerated aging of materials under proton irradiation, simulating a major part of the geostationary environment, revealed a strong limitation or disappearance of cracks while keeping the transparency of the PDMS. These promising results open routes to prepare new flexible autonomous polymeric materials for space applications.

Improvement of the Thermal and Optical Performances of Protective Polydimethylsiloxane Space Coatings with Cellulose Nanocrystal Additives.

This work investigates the possibility of using cellulose nanocrystals (CNCs) as biobased nanoadditives in protective polydimethylsiloxane (PDMS) space coatings, to improve the thermal and optical performances of the material. CNCs produced from wood pulp were functionalized in different conditions with the objective to improve their dispersibility in the PDMS matrix, increase their thermal stability and provide photoactive functions. Polysiloxane, cinnamate, chloroacetate and trifluoroacetate moieties were accordingly anchored at the CNCs surface by silylation, using two different approaches, or acylation with different functional vinyl esters. The modified CNCs were thoroughly characterized by FT-IR spectroscopy, solid-state NMR spectroscopy and thermogravimetric analysis, before being incorporated into a PDMS space coating formulation in low concentration (0.5 to 4 wt %). The cross-linked PDMS films were subsequently investigated with regards to their mechanical behavior, thermal stability and optical properties after photoaging. Results revealed that the CNC additives could significantly improve the thermal stability of the PDMS coating, up to 140 °C, depending on the treatment and CNC concentration, without affecting the mechanical properties and transparency of the material. In addition, the PDMS films loaded with as low as 1 wt % halogenated nanoparticles, exhibited an improved UV-stability after irradiation in geostationary conditions.