1.
Chem Commun (Camb)
; 58(94): 13139-13142, 2022 Nov 24.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36349724
RESUMO
Despite decades of research on alkene ozonolysis, the kinetic network of the archetypal case of ethylene (CH2îCH2) with ozone (O3) still lacks consensus. In this work, experimental evidence of an elusive diradical pathway is provided through the detection of the 2-hydroperoxyacetaldehyde ketohydroperoxide and its decomposition product, glyoxal.