Ultrasensitive Acoustic Detection Using an Enlarged Fabry-Perot Cavity with a Graphene Diaphragm.

For exerting high sensitivity of ultrathin graphene to detection deformation, an enlarged backing air cavity (EBC) structure is developed to further enhance the mechanical sensitivity (SM) of a graphene-based Fabry-Perot (F-P) acoustic sensor. COMSOL acoustic field simulation on the air cavity size-dependent SM confirms the optimal length and radius of the EBC of 0.2 and 1.5 mm, respectively, with the maximum simulation SM of 26.16 nm/Pa@1 kHz. Acoustic experiments further demonstrate that the frequency response of the fabricated graphene-based F-P acoustic sensor after the use of the EBC is enhanced by 5.73-79.33 times in the range of 0.5-18 kHz, compared with the conventional one without the EBC. Especially the maximum SM is up to 187.32 nm/Pa@16 kHz, which is at least 17% higher than the SM values ranging from 1.1 to 160 nm/Pa in previously reported F-P acoustic sensors using various diaphragm materials. More acoustic characteristics are examined to highlight various merits of the EBC structure, including a signal-to-noise ratio (SNR) of 60-75 dB@0.5-18 kHz, a time stability of less than ±1.3% for 90 min, a detection resolution of 0.01 Hz, and a high-fidelity speech detection with a cross-correlation coefficient of greater than 0.9, thereby revealing its high-performance weak acoustic sensing and speech recognition applications.

Polymer Grafted Nanoparticle Composites with Enhanced Thermal and Mechanical Properties.

The distribution of filler particles within a polymer matrix nanocomposite has a profound influence on the properties and processability of the material. While filler aggregation and percolation can significantly enhance particular functionalities such as thermal and electrical conductivity, the formation of larger filler clusters and networks can also impair mechanical properties like strength and toughness and can also increase the difficulty of processing. Here, a strategy is presented for the preparation of functional composites that enhance thermal conductivity over polymer alone, without negatively affecting mechanical performance or processability. Thermal cross-linking of self-suspended polymer grafted nanoparticles is used to prepare highly filled (>50 vol %) macroscopic nanocomposites with homogeneously dispersed, non-percolating alumina particles in an organic matrix. The initial composites use low glass transition temperature polymer grafts and thus are flexible and easily shaped by thermoforming methods. However, after thermal aging, the resulting materials display high stiffness (>10 GPa) and enhanced thermal conductivity (>100% increase) and also possess mechanical strength similar to commodity plastics. Moreover, the covalent bonding between matrix and filler allows for the significant elevation of thermal conductivity despite the extensive interfacial area in the nanocomposite. The thermal aging of polymer grafted nanoparticles is therefore a promising method for producing easily processable, mechanically sturdy, and macroscopic nanocomposites with improved thermal conductivity.

Laser-sculptured ultrathin transition metal carbide layers for energy storage and energy harvesting applications.

Ultrathin transition metal carbides with high capacity, high surface area, and high conductivity are a promising family of materials for applications from energy storage to catalysis. However, large-scale, cost-effective, and precursor-free methods to prepare ultrathin carbides are lacking. Here, we demonstrate a direct pattern method to manufacture ultrathin carbides (MoCx, WCx, and CoCx) on versatile substrates using a CO2 laser. The laser-sculptured polycrystalline carbides (macroporous, ~10-20 nm wall thickness, ~10 nm crystallinity) show high energy storage capability, hierarchical porous structure, and higher thermal resilience than MXenes and other laser-ablated carbon materials. A flexible supercapacitor made of MoCx demonstrates a wide temperature range (-50 to 300 °C). Furthermore, the sculptured microstructures endow the carbide network with enhanced visible light absorption, providing high solar energy harvesting efficiency (~72 %) for steam generation. The laser-based, scalable, resilient, and low-cost manufacturing process presents an approach for construction of carbides and their subsequent applications.

Cavitation inception of water with solid nanoparticles: A molecular dynamics study.

Cavitation in liquid with impurities is important in heterogeneous nucleation applications. One of the most widely existing kinds of impurities is solid particles, which can be found in natural water from rivers and specially prepared water such as nanofluids. Understanding the effects caused by the existence of nanoparticles on cavitation in water is vital to the rapidly developed nanotechnologies and medical researches. In this study, cavitation in water with nanoparticles is investigated through molecular dynamics simulations. The effects by nanoparticle materials and sizes on cavitation are discussed by using SiO2 and polyethylene spherical nanoparticles with different diameters. The nucleation rate and the formation of critical bubbles in cavitation are studied via the Voronoi tessellation and the mean first passage time methods. The hydrogen bond network in water is also analyzed. Results reveal that SiO⁠2 and polyethylene nanoparticles may destabilize the hydrogen bond network in water. With the same particle size, cavitation in water with polyethylene nanoparticles is promoted to a greater extent than that with SiO2 nanoparticles. With the same nanoparticle material, cavitation is promoted with the increase in particle size in a range spanning half to ten times the critical bubble radius. Beyond this range, particle size has little influence on cavitation. Reasons for those effects on cavitation due to the presence of solid nanoparticles are discussed by analysing the changes of hydrogen bonds network in water.

Self-Assembly of Large-Area 2D Polycrystalline Transition Metal Carbides for Hydrogen Electrocatalysis.

Low-dimensional (0/1/2 dimension) transition metal carbides (TMCs) possess intriguing electrical, mechanical, and electrochemical properties, and they serve as convenient supports for transition metal catalysts. Large-area single-crystalline 2D TMC sheets are generally prepared by exfoliating MXene sheets from MAX phases. Here, a versatile bottom-up method is reported for preparing ultrathin TMC sheets (≈10 nm in thickness and >100 µm in lateral size) with metal nanoparticle decoration. A gelatin hydrogel is employed as a scaffold to coordinate metal ions (Mo5+ , W6+ , Co2+ ), resulting in ultrathin-film morphologies of diverse TMC sheets. Carbonization of the scaffold at 600 °C presents a facile route to the corresponding MoCx , WCx , CoCx , and to metal-rich hybrids (Mo2- x Wx C and W/Mo2 C-Co). Among these materials, the Mo2 C-Co hybrid provides excellent hydrogen evolution reaction (HER) efficiency (Tafel slope of 39 mV dec-1 and 48 mVj = 10 mA cm-2 in overpotential in 0.5 m H2 SO4 ). Such performance makes Mo2 C-Co a viable noble-metal-free catalyst for the HER, and is competitive with the standard platinum on carbon support. This template-assisted, self-assembling, scalable, and low-cost manufacturing process presents a new tactic to construct low-dimensional TMCs with applications in various clean-energy-related fields.

Laser-Induced Molybdenum Carbide-Graphene Composites for 3D Foldable Paper Electronics.

Versatile and low-cost manufacturing processes/materials are essential for the development of paper electronics. Here, a direct-write laser patterning process is developed to make conductive molybdenum carbide-graphene (MCG) composites directly on paper substrates. The hierarchically porous MCG structures are converted from fibrous paper soaked with the gelatin-mediated inks containing molybdenum ions. The resulting Mo3 C2 and graphene composites are mechanically stable and electrochemically active for various potential applications, such as electrochemical ion detectors and gas sensors, energy harvesters, and supercapacitors. Experimentally, the electrical conductivity of the composite is resilient to mechanical deformation with less than 5% degradation after 750 cycles of 180° repeated folding tests. As such, the direct laser conversion of MCGs on papers can be applicable for paper-based electronics, including the 3D origami folding structures.

Titanium Disulfide Coated Carbon Nanotube Hybrid Electrodes Enable High Energy Density Symmetric Pseudocapacitors.

While electrochemical supercapacitors often show high power density and long operation lifetimes, they are plagued by limited energy density. Pseudocapacitive materials, in contrast, operate by fast surface redox reactions and are shown to enhance energy storage of supercapacitors. Furthermore, several reported systems exhibit high capacitance but restricted electrochemical voltage windows, usually no more than 1 V in aqueous electrolytes. Here, it is demonstrated that vertically aligned carbon nanotubes (VACNTs) with uniformly coated, pseudocapacitive titanium disulfide (TiS2 ) composite electrodes can extend the stable working range to over 3 V to achieve a high capacitance of 195 F g-1 in an Li-rich electrolyte. A symmetric cell demonstrates an energy density of 60.9 Wh kg-1 -the highest among symmetric pseudocapacitors using metal oxides, conducting polymers, 2D transition metal carbides (MXene), and other transition metal dichalcogenides. Nanostructures prepared by an atomic layer deposition/sulfurization process facilitate ion transportation and surface reactions to result in a high power density of 1250 W kg-1 with stable operation over 10 000 cycles. A flexible solid-state supercapacitor prepared by transferring the TiS2 -VACNT composite film onto Kapton tape is demonstrated to power a 2.2 V light emitting diode (LED) for 1 min.