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1.
Nature ; 616(7957): 452-456, 2023 04.
Artigo em Inglês | MEDLINE | ID: mdl-36858074

RESUMO

Some active asteroids have been proposed to be formed as a result of impact events1. Because active asteroids are generally discovered by chance only after their tails have fully formed, the process of how impact ejecta evolve into a tail has, to our knowledge, not been directly observed. The Double Asteroid Redirection Test (DART) mission of NASA2, in addition to having successfully changed the orbital period of Dimorphos3, demonstrated the activation process of an asteroid resulting from an impact under precisely known conditions. Here we report the observations of the DART impact ejecta with the Hubble Space Telescope from impact time T + 15 min to T + 18.5 days at spatial resolutions of around 2.1 km per pixel. Our observations reveal the complex evolution of the ejecta, which are first dominated by the gravitational interaction between the Didymos binary system and the ejected dust and subsequently by solar radiation pressure. The lowest-speed ejecta dispersed through a sustained tail that had a consistent morphology with previously observed asteroid tails thought to be produced by an impact4,5. The evolution of the ejecta after the controlled impact experiment of DART thus provides a framework for understanding the fundamental mechanisms that act on asteroids disrupted by a natural impact1,6.

2.
RSC Adv ; 8(35): 19381-19388, 2018 May 25.
Artigo em Inglês | MEDLINE | ID: mdl-35540991

RESUMO

In the proposed study, an efficient method for a carbon dot@ß-cyclodextrin (C-dot@ß-CD)-based fluorescent probe was developed for the analyses of catechol (CC) and hydroquinone (HQ) at trace levels in water samples. The properties of C-dot@ß-CD nanocomposites were characterized by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The sensing behaviors of C-dot@ß-CD toward CC and HQ were investigated by fluorescence spectroscopy. Based on the host-guest chemistry between C-dot@ß-CD and phenolic compounds, which can quench C-dot@ß-CD fluorescence, the prepared C-dot@ß-CD nanocomposites could be used for the sensitive and selective detection of CC or HQ across a wide linear range (0.1 to 10 µM) with detection limits of 47.9 and 20.2 nM, respectively. These results showed that the synthesized C-dot@ß-CD nanocomposite exhibited strong fluorescence and high degree of water solubility and thus, it is suitable for use as a nanoprobe for detecting CC or HQ in real water samples.

3.
Food Chem ; 224: 353-358, 2017 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-28159279

RESUMO

A novel method for the detection of dimethoate based on the peroxidase-like activity of silver-nanoparticles-modified oxidized multiwalled carbon nanotubes (AgNPs/oxMWCNTs) has been developed. The synthesized AgNPs/oxMWCNTs showed excellent peroxidease-like catalytic activity in hydrogen peroxide-Amplex red (AR) system (AR is oxidized to resorufinat, with the resorufin fluorescence at 584nm being used to monitor the catalytic activity). After dimethoate was added to AgNPs/oxMWCNTs, the interaction between dimethoate and the AgNPs inhibited the catalytic activity of AgNPs/oxMWCNTs. The decrease in fluorescence was used for the detection of dimethoate in the range of 0.01-0.35µgmL-1 (R2=0.998) with a detection limit of 0.003µgmL-1 (signal/noise=3). This method exhibited good selectivity for the detection of dimethoate even in the presence of high concentration of other pesticides. Consequently, the method was applied to measure the concentration of dimethoate residue in lake water and fruit, thus obtaining satisfactory results.


Assuntos
Dimetoato/análise , Nanopartículas Metálicas/química , Nanotubos de Carbono/química , Prata/química , Fluorometria , Análise de Alimentos , Frutas/química , Peróxido de Hidrogênio/metabolismo , Lagos/química , Limite de Detecção , Praguicidas/análise
4.
Nature ; 526(7573): 402-5, 2015 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-26416730

RESUMO

The factors shaping cometary nuclei are still largely unknown, but could be the result of concurrent effects of evolutionary and primordial processes. The peculiar bilobed shape of comet 67P/Churyumov-Gerasimenko may be the result of the fusion of two objects that were once separate or the result of a localized excavation by outgassing at the interface between the two lobes. Here we report that the comet's major lobe is enveloped by a nearly continuous set of strata, up to 650 metres thick, which are independent of an analogous stratified envelope on the minor lobe. Gravity vectors computed for the two lobes separately are closer to perpendicular to the strata than those calculated for the entire nucleus and adjacent to the neck separating the two lobes. Therefore comet 67P/Churyumov-Gerasimenko is an accreted body of two distinct objects with 'onion-like' stratification, which formed before they merged. We conclude that gentle, low-velocity collisions occurred between two fully formed kilometre-sized cometesimals in the early stages of the Solar System. The notable structural similarities between the two lobes of comet 67P/Churyumov-Gerasimenko indicate that the early-forming cometesimals experienced similar primordial stratified accretion, even though they formed independently.

5.
Nature ; 523(7558): 63-6, 2015 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-26135448

RESUMO

Pits have been observed on many cometary nuclei mapped by spacecraft. It has been argued that cometary pits are a signature of endogenic activity, rather than impact craters such as those on planetary and asteroid surfaces. Impact experiments and models cannot reproduce the shapes of most of the observed cometary pits, and the predicted collision rates imply that few of the pits are related to impacts. Alternative mechanisms like explosive activity have been suggested, but the driving process remains unknown. Here we report that pits on comet 67P/Churyumov-Gerasimenko are active, and probably created by a sinkhole process, possibly accompanied by outbursts. We argue that after formation, pits expand slowly in diameter, owing to sublimation-driven retreat of the walls. Therefore, pits characterize how eroded the surface is: a fresh cometary surface will have a ragged structure with many pits, while an evolved surface will look smoother. The size and spatial distribution of pits imply that large heterogeneities exist in the physical, structural or compositional properties of the first few hundred metres below the current nucleus surface.

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