Interindividual- and blood-correlated sweat phenylalanine multimodal analytical biochips for tracking exercise metabolism.

In situ monitoring of endogenous amino acid loss through sweat can provide physiological insights into health and metabolism. However, existing amino acid biosensors are unable to quantitatively assess metabolic status during exercise and are rarely used to establish blood-sweat correlations because they only detect a single concentration indicator and disregard sweat rate. Here, we present a wearable multimodal biochip integrated with advanced electrochemical electrodes and multipurpose microfluidic channels that enables simultaneous quantification of multiple sweat indicators, including phenylalanine and chloride, as well as sweat rate. This combined measurement approach reveals a negative correlation between sweat phenylalanine levels and sweat rates among individuals, which further enables identification of individuals at high metabolic risk. By tracking phenylalanine fluctuations induced by protein intake during exercise and normalizing the concentration indicator by sweat rates to reduce interindividual variability, we demonstrate a reliable method to correlate and analyze sweat-blood phenylalanine levels for personal health monitoring.

MXene-Induced Flexible, Water-Retention, Semi-Interpenetrating Network Hydrogel for Ultra-Stable Strain Sensors with Real-Time Gesture Recognition.

As water-saturated polymer networks, hydrogels are a growing family of soft materials that have recently become promising candidates for flexible electronics application. However, it remains still difficult for hydrogel-based strain sensors to achieve the organic unity of mechanical properties, electrical conductivity, and water retention. To address this challenge, based on the template, the excellent properties of MXene nanoflakes (rich surface functional groups, high specific surface area, hydrophilicity, and conductivity) are fully utilized in this study to prepare the P(AA-co-AM)/MXene@PDADMAC semi-interpenetrating network (semi-IPN) hydrogel. The proposed hydrogel continues to exhibit excellent strain response and flexibility after 30 days of storage at room temperature, and its performance do not decrease after 1100 cycles. Considering these characteristics, a hydrogel-based device for converting sign language into Chinese characters is successfully developed and optimized using machine learning. Therefore, this study provides novel insight and application directions for hydrogel families.

CMOS-Compatible Tellurium/Silicon Ultra-Fast Near-Infrared Photodetector.

High-quality photodetectors are always the main way to obtain external information, especially near-infrared sensors play an important role in remote sensing communication. However, due to the limitation of Silicon (Si) wide bandgap and the incompatibility of most near infrared photoelectric materials with traditional integrated circuits, the development of high performance and wide detection spectrum near infrared detectors suitable for miniaturization and integration is still facing many obstacles. Herein, the monolithic integration of large area tellurium optoelectronic functional units is realized by magnetron sputtering technology. Taking advantage of the type II heterojunction constructed by tellurium (Te) and silicon (Si), the photogenerated carriers are effectively separated, which prolongs the carrier lifetime and improves the photoresponse by several orders of magnitude. The tellurium/silicon (Te/Si) heterojunction photodetector demonstrates excellent detectivity and ultra-fast turn-on time. Importantly, an imaging array (20 × 20 pixels) based on the Te/Si heterojunction is demonstrated and high-contrast photoelectric imaging is realized. Because of the high contrast obtained by the Te/Si array, in comparison with the Si arrays, it significantly improve the efficiency and accuracy of the subsequent processing tasks when the electronic pictures are applied to artificial neural network (ANN) to simulate the artificial vision system.

Concept design, technical performance, and GHG emissions analysis of petroleum coke direct chemical looping hydrogen highly integrated with gasification for methanol production process.

Petroleum coke gasification for methanol production process has excellent application prospects for the clean utilization of high­sulfur coke while limiting pollutant emissions from coke combustion. However, the process still suffers from high-energy use and a large CO2 generation caused by composition adjustment. This study proposes a novel petroleum coke chemical looping hydrogen-assisted gasification process for methanol production. Mass-energy coupling is realized by replacing the water gas shift unit with the chemical looping hydrogen unit, and the high temperature gasified gas heats the fuel reactor and in turn the feedstock. Two chemical looping hydrogen scenarios with an operating pressure of 3.0 and 0.1 MPa are considered. The methanol exergy can be increased from 484 to 1030 and 1028 MW by doubling the petroleum coke consumption through the chemical looping integration. The exergy efficiency of the new process is correspondingly increased from 51.6 to 57.1 and 55.2 % with 63.02 and 63.71 % reductions in direct CO2 emissions, as compared to the only gasification route. The calculated life cycle energy consumption and greenhouse gases emissions of the new processes are 40.02/43.84 GJ/t and 693/1055 kg CO2 eq/t, 15.14/7.05 % and 49.09/22.45 % lower than that of the benchmark process. The integration of high-pressure chemical looping technology can introduce significant technical and environmental benefits for methanol production from the petroleum coke.

The Moderating Effect of Compassionate Mindfulness on the Psychological Needs and Emotions of Generation Y in the 21st Century in Taiwan.

During the 2020 COVID-19 pandemic in Taiwan, 6.5% of Generation Y required medical treatment for emotional and stress-related mental disorders. This study explores the moderating effect of mindfulness training on psychological needs and emotions to propose effective measures to promote the mental health of Generation Y. This study was carried out by questionnaire, using the data of respondents born in 1980-1999, collected in three different periods for quantitative analysis with compassionate mindfulness as the main variable. The results show that the compassionate mindfulness effect on emotion regulation varies greatly among different educational levels. However, it still plays a positive role in the psychological needs of Generation Y. Most members of Generation Y who receive compassionate mindfulness training have fewer basic needs and more interpersonal trust. They pay more attention to individual-oriented self-realization. Compassionate mindfulness has a greater positive moderating effect on the mental health of women aged 30-39 and those who are highly educated. Compassionate mindfulness has a more positive moderating effect on the psychological needs of members of Generation Y who were born more recently. During the COVID-19 pandemic, providing compassionate mindfulness has a significant positive effect on the prevention of mental disorders of Generation Y in Taiwan.

Depression Risk Factors for Knowledge Workers in the Post-Capitalist Society of Taiwan.

This study aimed to examine the depression risk factors for knowledge workers aged 20-64 in the post-capitalist society of Taiwan. Interview data from 2014 and 2019 were adopted for quantitative analysis of the depression risk by demographic and individual characteristics. The results showed that the depression risks of knowledge workers were not affected by demographic variables in a single period. From 2014 to 2019, the prevalence of high depression risk in knowledge workers aged 20-64 years increased over time. The more attention is paid to gender equality in society, the less the change in the gender depression index gap may be seen. Positive psychological state and family relationships are both depression risk factors and depression protective factors. Being male, married, religious, and aged 45-49 years old were found to be critical risk factors. Variables of individual characteristics could effectively predict depression risk.

On the degradation of (micro)plastics: Degradation methods, influencing factors, environmental impacts.

Plastics and microplastics are difficult to degrade in the natural environment due to their hydrophobicity, the presence of stable covalent bonds and functional groups that are not susceptible to attack. In nature, microplastics are more likely to attract other substances due to their large specific surface area, which further prevents degradation from occurring. Some of these substances are toxic and harmful, and can be spread to various organisms through the food chain along with the microplastics to cause harm to them. Degradation is an effective way to eliminate plastic pollution, and a comprehensive understanding of the methods and mechanisms of plastic degradation is necessary, because it is the result of synergistic effects of several degradation methods, both in nature and in consideration of future engineering applications. The authors firstly summarize the degradation methods of (micro)plastics; secondly, review the influence of intrinsic properties and environmental factors during the degradation process; finally, discuss the environmental impact of the degradation products of (micro)plastics. It is evident that the degradation of (micro)plastics still has many challenges to overcome, and there are no mature and effective methods that can be applied in engineering practice or widely used in nature. Therefore, there is an urgent need for research on the degradation of (micro)plastics.

The Digital Divide and Active Aging in China.

With the rapid development of society, especially the advent of intelligent technology of life services, the ability of the elderly to adapt to modern digital life is getting weaker and weaker, the dilemma of the "digital divide" for the elderly has aroused heated public debate. In the era of aging and information superposition, in-depth study of the multi-dimensional impact of the digital divide on the elderly has become an effective content of China's active aging strategy. Based on the micro-data of the Chinese General Social Survey in 2017, this paper uses the entropy right method to construct the digital divide index system for the elderly over 60 years of age from the perspective of essential equipment, Internet utilization degree, and Basic Internet usage skills. At the same time, this paper constructs China's comprehensive index of active aging from three aspects: health, social participation, and guarantee of the elderly, to study the impact of the digital divide on China's active aging. The following conclusions have been drawn: the digital divide among the elderly significantly inhibits China's active aging. The digital divide reduces the level of physical and mental health and social participation of older persons and inhibits the level of guarantee of older persons, thus impeding their active aging. In addition, it also reduces the overall life satisfaction of the elderly. The use of the Internet, skills, and other digital technology abilities of the elderly have effectively promoted active aging. The more Internet access devices older people have, the higher their level of social participation. The higher the Internet frequency of the elderly, the healthier the body and mind. Furthermore, the greater the level of physical and mental health and social participation of older groups who use online payments. The digital divide among the elderly inhibits the process of China's active aging, and the unique course and stage characteristics of the development of the aging of the Chinese population require us to pay full attention to the relationship between the digital divide and active aging and how to construct a "digital-friendly" aging system is an essential issue for China's social development to consider.

Spatial and seasonal variations in biofilm formation on microplastics in coastal waters.

At present, microplastics (MPs) have gradually become a hot issue in marine environmental pollution and may pose a potential threat to marine ecosystems. Since MPs are not easily biodegradable, they can provide the attachment substrates for various organisms, which will affect their floating and transport, and may also lead to the invasion of harmful microorganisms. In this study, polypropylene, polyethylene, polylactic acid pellets, and glass particles were exposed for 6 weeks in different seasons at three stations in the Yellow Sea, China. The results showed that the total amounts of biofilms significantly varied among seasons and functional zones and that the temperature of seawater was the main influencing factor. A variety of biological communities (especially diatoms and bacteria) and extracellular polymeric substances were observed on the MP surfaces using scanning electron microscopy and confocal laser scanning microscopy. Sequencing analysis indicated that the structure and composition of microbial communities on MPs mainly varied with seasons and locations. In addition, most of the microorganisms were generally attached to the surface and were not any specific selection of plastic by different chemical compositions. However, the bacteria inhabiting microplastics harbored distinct metabolisms. Our results suggest that low-density MPs may settle quickly in summer in some eutrophic areas.

Research progress of nanoplastics in freshwater.

With the mass production and use of plastic products, which leads to their continuous entry into the water environment, the problem of environmental pollution has been paid more and more attention by scholars from different countries. In recent years, a large number of studies have focused on microplastics, but few on nanoplastics (NPs). However, NPs are smaller in size, have a higher affinity for cells, and surface and volume ratios are higher than those of microplastics. NPs may also enter biological tissues, blood and cells, which may cause greater potential harm to organisms. In this paper, firstly, the environmental fate of NPs accumulation and deposition is summarized, and further research is needed in the future; secondly, the current techniques for NPs extraction and characterization of NPs extraction and characterization are summarized. At present, the analytical methods of NPs are in the primary stage, and lack of standardized and accurate methods; finally, the toxic effects of NPs on biological morphology, behavior and reproduction are discussed. It has been found that the small size and high surface area of NPs make them more toxic to organisms than microplastics. However, most of the current toxicological studies of NPs on freshwater organisms could not be simulated in real environment.

The Effect of China's Health Insurance on the Labor Supply of Middle-aged and Elderly Farmers.

Social security primarily improves residents' welfare and ensures labor market sustainability. This study presents a new view of the association between health insurance and labor supply by using data from the China Health and Retirement Longitudinal Study. The results reveal that the health insurance system has a remarkable effect on labor supply. The health insurance coverage tends to encourage middle-aged and elderly farmers to increase their farm labor participation rate and working time, especially for their household agricultural labor participation rate and working time. However, it also reduces the non-farm labor participation rate and working time. Different types of health insurance have diverse effects on labor supply. The new cooperative medical insurance has a stronger pull-back effect. It encourages the middle-aged and elderly farmers to leave the urban non-farm sector and transfer to rural areas to engage in their household agricultural work. The urban employee medical insurance encourages farmers to reduce self-employed labor supply and increase employed work. The supplemental health insurance tends to reduce the labor supply of farm employed and non-farm labor supply, but improve the farm labor supply. Furthermore, urban resident medical insurance and government medical insurance encourage farmers to quit directly from the labor market. In conclusion, the health insurance system is facilitating change in the labor market. Policy-makers should pay full attention to such impacts while improving the health insurance system's design and operation in China.