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1.
Plants (Basel) ; 13(10)2024 May 10.
Artigo em Inglês | MEDLINE | ID: mdl-38794385

RESUMO

Leaf chlorophyll content (LCC) is an important physiological index to evaluate the photosynthetic capacity and growth health of crops. In this investigation, the focus was placed on the chlorophyll content per unit of leaf area (LCCA) and the chlorophyll content per unit of fresh weight (LCCW) during the tuber formation phase of potatoes in Northern Shaanxi. Ground-based hyperspectral data were acquired for this purpose to formulate the vegetation index. The correlation coefficient method was used to obtain the "trilateral" parameters with the best correlation between potato LCCA and LCCW, empirical vegetation index, any two-band vegetation index constructed after 0-2 fractional differential transformation (step size 0.5), and the parameters with the highest correlation among the three spectral parameters, which were divided into four combinations as model inputs. The prediction models of potato LCCA and LCCW were constructed using the support vector machine (SVM), random forest (RF) and back propagation neural network (BPNN) algorithms. The results showed that, compared with the "trilateral" parameter and the empirical vegetation index, the spectral index constructed by the hyperspectral reflectance after differential transformation had a stronger correlation with potato LCCA and LCCW. Compared with no treatment, the correlation between spectral index and potato LCC and the prediction accuracy of the model showed a trend of decreasing after initial growth with the increase in differential order. The highest correlation index after 0-2 order differential treatment is DI, and the maximum correlation coefficients are 0.787, 0.798, 0.792, 0.788 and 0.756, respectively. The maximum value of the spectral index correlation coefficient after each order differential treatment corresponds to the red edge or near-infrared band. A comprehensive comparison shows that in the LCCA and LCCW estimation models, the RF model has the highest accuracy when combination 3 is used as the input variable. Therefore, it is more recommended to use the LCCA to estimate the chlorophyll content of crop leaves in the agricultural practices of the potato industry. The results of this study can enhance the scientific understanding and accurate simulation of potato canopy spectral information, provide a theoretical basis for the remote sensing inversion of crop growth, and promote the development of modern precision agriculture.

2.
Opt Express ; 32(6): 8919-8928, 2024 Mar 11.
Artigo em Inglês | MEDLINE | ID: mdl-38571137

RESUMO

The grating-based magneto-optical trap (GMOT) is a promising approach for miniaturizing cold-atom systems. However, the power consumption of a GMOT system dominates its feasibility in practical applications. In this study, we demonstrated a GMOT system based on planar elements that can operate with low power consumption. A high-diffraction-efficiency grating chip was used to cool atoms with a single incident beam. A planar coil chip was designed and fabricated with a low power consumption nested architecture. The grating and coil chips were adapted to a passive pump vacuum chamber, and up to 106 87Rb atoms were trapped. These elements effectively reduce the power consumption of the GMOT and have great potential for applications in practical cold-atom-based devices.

3.
Plant Dis ; 2024 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-38687573

RESUMO

Kiwifruit is widely cultivated for its high vitamin C content and nutritional value. In January 2022, root rot symptoms were found in about 30% of Actinidia chinensis cv. Jinyan plants grafted on A. deliciosa rootstocks in an orchard located in Sanming (26.32°N, 117.23°E), Fujian Province of China. The affected plants appeared stunted, with brown and decaying roots, some of which were covered with white hyphae. To isolate the pathogen, the surfaces of typical symptomatic roots were sterilized for 30 s using 75% ethanol, followed by four rinses in sterile water, placing on potato dextrose agar (PDA), and incubating away from light at 25°C for 7 days. 16 Globisporangium-like isolates were obtained through hyphal tip isolation, displaying a milky-white appearance with irregular protuberances on the surface, and yellow-white backs with radial fold lines. The isolates were then cultured on corn meal agar for 5 days at 25°C in dark for morphological characteristics. Under microscope, the hyphae appeared as long strips without septa and 4.1 to 8.2 µm wide (average 6.7 µm), containing irregularly sized spherical droplets. Both terminal and intercalary hyphae swellings were observed; these appeared either spherical or subspherical, with some having projections. Their dimensions were 12.3 to 27.6 µm (average 17.3 µm). The oospores were mostly spherical, either plerotic or aplerotic, 11.8 to 22.3 µm wide (average 18.9 µm), with occasional projections. The antheridia were rod-shaped and curved, with one end attached to the oogonia. Amplification of the sequences of internal transcribed spacer (ITS) regions and cytochrome c oxidase subunit I (COI) were conducted using the primers ITS1/ITS4 (White et al. 1990) and OomCoxI-Levlo/OomCoxI-Levup (Robideau et al. 2011), respectively. The sequencing results revealed identical ITS and COI sequences in all 16 isolates. BLASTn analysis of the 969-bp ITS sequence ON202808 showed 99.38-99.59% similarity (965/971bp, 967/971bp) with the KJ162353 and AY598701 sequences from Globisporangium spinosum isolates, while the 700-bp COI sequence ON075783 showed 100% and 99.41% identity (680/680bp, 676/680bp) with the GenBank sequences HQ708835 and HQ708832, respectively, from G. spinosum. Phylogenetic analysis also showed that the obtained isolate (termed MA16) clustered with isolates from G. spinosum on the same evolutionary branch. For pathogenicity testing, four-month-old healthy Jinyan (A. chinensis) plants grown in sterilized media were transferred to sterile petri dishes covered with wet filter paper, and their roots were inoculated with a 5-mm-wide disk of MA16 when cultivated on PDA medium for 5 days. Miliang-1 (A. deliciosa) and Hongyang (A. chinensis) plants were treated similarly. The control groups each included three plants that were inoculated with non-colonized PDA. The plants were kept at 25 °C with a 12-/12-h light/dark cycle for 10 days when the inoculated plants exhibited root rot symptoms similar to those seen in the field, together with rotting and browning of the leaves. The control plants appeared healthy with no symptoms. After re-isolated from infected tissues, the pathogen was verified to be G. spinosum according to its ITS sequence, thus fulfilling the Koch's postulates. Recently, Pythium spinosum has been classified as G. spinosum according to whole-genome sequencing and phylogenomic analysis (Nguyen et al. 2022). Based on the morphological features and pathogenicity results, MA16 was identified as G. spinosum (van der Plaats-Niterink 1981; Huo et al. 2023). This report appears to be the first description of kiwifruit root rots caused by G. spinosum in China, and its identification will assist the development of strategies to counteract the disease.

4.
Discov Nano ; 19(1): 72, 2024 Apr 29.
Artigo em Inglês | MEDLINE | ID: mdl-38684632

RESUMO

Spin-orbit couplings (SOCs), originating from the relativistic corrections in the Dirac equation, offer nonlinearity in the classical limit and are capable of driving chaotic dynamics. In a nanoscale quantum dot confined by a two-dimensional parabolic potential with SOCs, various quantum scar states emerge quasi-periodically in the eigenstates of the system, when the ratio of confinement energies in the two directions is nearly commensurable. The scars, displaying both quantum interference and classical trajectory features on the electron density, due to relativistic effects, serve as a bridge between the classical and quantum behaviors of the system. When the strengths of Rashba and Dresselhaus SOCs are identical, the chaos in the classical limit is eliminated as the classical Hamilton's equations become linear, leading to the disappearance of all quantum scar states. Importantly, the quantum scars induced by SOCs are robust against small perturbations of system parameters. With precise control achievable through external gating, the quantum scar induced by Rashba SOC is fully controllable and detectable.

5.
Nano Lett ; 24(13): 3937-3944, 2024 Apr 03.
Artigo em Inglês | MEDLINE | ID: mdl-38526847

RESUMO

Integrating high-κ dielectrics with a small equivalent oxide thickness (EOT) with two-dimensional (2D) semiconductors for low-power consumption van der Waals (vdW) heterostructure electronics remains challenging in meeting both interface quality and dielectric property requirements. Here, we demonstrate the integration of ultrathin amorphous HfOx sandwiched within vdW heterostructures by the selective thermal oxidation of HfSe2 precursors. The self-cleaning process ensures a high-quality interface with a low interface state density of 1011-1012 cm-2 eV-1. The synthesized HfOx displays excellent dielectric properties with an EOT of ∼1.5 nm, i.e., a high κ of ∼16, an ultralow leakage current of 10-6 A/cm2, and an impressively high breakdown field of 9.5 MV/cm. This facilitates low-power consumption vdW heterostructure MoS2 transistors, demonstrating steep switching with a low subthreshold swing of 61 mV/decade. This one-step integration of high-κ dielectrics into vdW sandwich heterostructures holds immense potential for developing low-power consumption 2D electronics while meeting comprehensive dielectric requirements.

6.
Nano Lett ; 24(3): 975-982, 2024 Jan 24.
Artigo em Inglês | MEDLINE | ID: mdl-38189647

RESUMO

Ferroelectric memristors hold immense promise for advanced memory and neuromorphic computing. However, they face limitations due to low readout current density in conventional designs with low-conductive ferroelectric channels, especially at the nanoscale. Here, we report a ferroelectric-mediated memristor utilizing a 2D MoS2 nanoribbon channel with an ultrascaled cross-sectional area of <1000 nm2, defined by a ferroelectric BaTiO3 nanoribbon stacked on top. Strikingly, the Schottky barrier at the MoS2 contact can be effectively tuned by the charge transfers coupled with quasi-zero-dimensional polarization charges formed at the two ends of the nanoribbon, which results in distinctive resistance switching accompanied by multiple negative differential resistance showing the high-current density of >104 A/cm2. The associated space charges in BaTiO3 are minimized to ∼3.7% of the polarization charges, preserving nonvolatile polarization. This achievement establishes ferroelectric-mediated nanoscale semiconductor memristors with high readout current density as promising candidates for memory and highly energy-efficient in-memory computing applications.

7.
J Environ Manage ; 351: 119887, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38169255

RESUMO

Comprehensive regional remote analysis tends to neglect lakes in exorheic basins on the Qinghai-Tibetan Plateau (QTP), and a concurrent lack of discussions on whether there exist imbalanced explanations for the driving forces of both internal and external lakes is also present. We integrate multisourced lake datasets, high-resolution information, and available altimetry datasets to establish multiple mathematical models to meta-simulate lake volume changes, extend current lake variation datasets, and quantify the imbalance of variations and factors driving the water mass budget. The results showed that the primary cause of lake variations in QTP is net precipitation (57.75 ± 31.46%), followed by glacier runoff (33.53 ± 31.42%), and permafrost (8.34 ± 7.87%). Even though glacier runoff is currently considered as a weak factor of lake variation, heterogeneous results call for remaining attention in glacier-induced lake basins. Imbalance embodying in lake variability but not in contributions of driving factors, which calls for special lake management ways in different watersheds.


Assuntos
Lagos , Modelos Teóricos , Tibet , Camada de Gelo
8.
Small ; 20(3): e2304010, 2024 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-37726234

RESUMO

Van der Waals (vdW) heterostructures are composed of atomically thin layers assembled through weak (vdW) force, which have opened a new era for integrating materials with distinct properties and specific applications. However, few studies have focused on whether and how anisotropic materials affect heterostructure system. The study introduces anisotropic and isotropic materials in a heterojunction system to change the in-plane symmetry, offering a new degree of freedom for modulating its properties. The sample is fabricated by manually stacking ReS2 and WS2 flakes prepared by mechanical exfoliation. Raman spectra and photoluminescence measurements confirm the formation of an effective heterojunction, indicating interlayer coupling of the system. The anisotropy and asymmetry of the WS2 -ReS2 heterostructure system can be adjusted by the introduction of isotropic WS2 and anisotropic ReS2 , which can be proved by the change of the polarized Raman pattern. In the transient absorption measurement, the transient absorption spectra of WS2 -ReS2 heterostructure are red-shifted compared to those of WS2 monolayer, and the charge transfer is observed in the heterostructure. These results show the potential of anisotropic 2D materials in anisotropy modulation of heterostructures, which may promote future electronic or photonic application.

9.
Adv Mater ; 35(32): e2302318, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37165732

RESUMO

Mainstream non-volatile memory (NVM) devices based on floating gate structures or phase-change/ferroelectric materials face inherent limitations that compromise their suitability for long-term data storage. To address this challenge, a novel memory device based on light-programmed lattice engineering of thin rhenium disulfide (ReS2 ) flakes is proposed. By inducing sulfur vacancies in the ReS2 channel through light illumination, the device's electrical conductivity is modified accordingly and multiple conductance states for data storage therefore are generated. The device exhibits more than 128 distinct states with linearly increasing conductance, corresponding to a sevenfold increase in storage density. Through further optimization to achieve atomic-level precision in defect creation, it is possible to achieve even higher storage densities. These states are extremely stable in vacuum or inert ambient showing long retention of >10 years, while they can be erased upon exposure to the air. The ReS2 memory device can maintain its stability over multiple program-erase operation cycles and shows superior wavelength discrimination capability for incident light in the range of 405-785 nm. This device represents a significant contribution to NVM technology by offering the ability to store information in multistate memory and enabling filter-free color image recorder applications.

10.
Opt Express ; 31(2): 1692-1704, 2023 Jan 16.
Artigo em Inglês | MEDLINE | ID: mdl-36785199

RESUMO

We present an atom-based approach for determining microwave electric and magnetic fields by using a single rubidium vapor cell in a microwave waveguide. For a 87Rb cascade three-level system employed in our experiment, a weak probe laser driving the lower transition, 5S1/2→5P3/2, is first used to measure the microwave magnetic field based on the atomic Rabi resonance. When a counter-propagating strong coupling laser is subsequently turned on to drive the Rydberg transition, 5P3/2→67D5/2, the same probe laser is then used as a Rydberg electromagnetically induced transparency (EIT) probe to measure the microwave electric field by investigating the resonant microwave dressed Autler-Townes splitting (ATS). By tuning the hyperfine transition frequency of the ground state using an experimentally feasible static magnetic field, we first achieved a measurement of the microwave electric and magnetic field strength at the same microwave frequency of 6.916 GHz. Based on the ideal relationship between the electric and magnetic field components, we obtained the equivalent microwave magnetic fields by fitting the inversion to the measured microwave electric fields, which demonstrated that the results were in agreement with the experimental measurement of the microwave magnetic fields in the same microwave power range. This study provides new experimental evidence for quantum-based microwave measurements of electric and magnetic fields by a single sensor in the same system.

11.
Sci Adv ; 8(47): eabo4492, 2022 Nov 25.
Artigo em Inglês | MEDLINE | ID: mdl-36427300

RESUMO

Fractional crystallization plays a critical role in generating the differentiated continental crust on Earth. However, whether efficient crystal-melt separation can occur in viscous felsic magmas remains a long-standing debate because of the difficulty in discriminating between differentiated melts and complementary cumulates. Here, we found large (~1 per mil) potassium isotopic variation in 54 strongly peraluminous high-silica (silicon dioxide >70 weight %) leucogranites from the Himalayan orogen, with potassium isotopes correlated with trace elemental proxies (e.g., strontium, rubidium/strontium, and europium anomaly) for plagioclase crystallization. Quantitative modeling requires up to ~60 to 90% fractional crystallization to account for the progressively light potassium isotopic composition of the fractionated leucogranites, while plagioclase accumulation results in enrichment of heavy potassium isotopes in cumulate leucogranites. Our findings strongly support fractional crystallization of high-silica magmas and highlight the great potential of potassium isotopes in studying felsic magma differentiation.

12.
Nanoscale Adv ; 4(18): 3756-3763, 2022 Sep 13.
Artigo em Inglês | MEDLINE | ID: mdl-36133320

RESUMO

Secondary ion batteries rely on two-dimensional (2D) electrode materials with high energy density and outstanding rate capability. Rb- and Cs-ion batteries (RIBs and CIBs) are late-model batteries. Herein, using first-principles calculations, the potential performance of H-MoS2 as a 2D electrode candidate in RIBs and CIBs has been investigated. The M-top site on 2D H-MoS2 possesses the most stable metal atom binding sites, and after adsorbing Rb and Cs atoms, its Fermi level goes up to the conduction band, indicating a semiconductor-to-metal transition. The maximal theoretical capacities of RIBs and CIBs are 372.05 (comparable to those of commercial graphite-based LIBs) and 223.23 mA h g-1, respectively, due to the strong adsorption capability of H-MoS2 for Rb and Cs ions. Noticeably, the diffusion barriers of Rb and Cs on H-MoS2 are 0.037 and 0.036 eV, respectively. Such a low diffusion barrier gives MoS2-based RIBs and CIBs high rate capability. In addition, H-MoS2 also has the characteristics of suitable open-circuit voltage, low expansion, good cycle stability, low cost, and easy experimental realization. These results indicate that MoS2-based RIBs and CIBs are innovative batteries with great potential, and may provide opportunities for cross-application of energy storage and multiple disciplines.

13.
Adv Mater ; 34(15): e2200032, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-35194847

RESUMO

The functional reconfiguration of transistors and memory in homogenous ferroelectric devices offers significant opportunities for implementing the concepts of in-memory computing and logic-memory monolithic integration. Thus far, reconfiguration is realized through programmable doping profiles in the semiconductor channel using multiple-gate operation. This complex device architecture limits further scaling to match the overall chip requirements. Here, reconfigurable memory/transistor functionalities in a ferroelectric-gated van der Waals transistor by controlling the behavior of ferroelectric oxygen vacancies at the interface are demonstrated. Short- and long-term memory functions are demonstrated by modulating the border oxygen vacancy distribution and the associated charge dynamics. The quasi-nonvolatile long-term memory exhibits data retention of over 105 s and endurance of up to 5 × 105 cycles, verifying its applicability as a potential device platform for neuromorphic networks. More importantly, by modulating the ferroelectricity of the interfacial domains with the interactions of oxygen vacancies, a hysteresis-free logic transistor is realized with a subthermionic subthreshold swing down to 46 mV dec-1 , which resembles a negative-capacitance field-effect transistor. The new concept of achieving functional reconfiguration with prior device performance in a single-gate ferroelectric field-effect transistor is of great advantage in future integrated circuit applications.

14.
Environ Sci Technol ; 56(2): 1053-1068, 2022 01 18.
Artigo em Inglês | MEDLINE | ID: mdl-34942073

RESUMO

People spend increasing amounts of time at home, yet the indoor home environment remains understudied in terms of potential exposure to toxic trace metals. We evaluated trace metal (and metalloid) concentrations (As, Cu, Cr, Mn, Ni, Pb, and Zn) and health risks in indoor dust from homes from 35 countries, along with a suite of potentially contributory residential characteristics. The objective was to determine trace metal source inputs and home environment conditions associated with increasing exposure risk across a range of international communities. For all countries, enrichments compared to global crustal values were Zn > Pb > Cu > As > Cr > Ni; with the greatest health risk from Cr, followed by As > Pb > Mn > Cu > Ni > Zn. Three main indoor dust sources were identified, with a Pb-Zn-As factor related to legacy Pb sources, a Zn-Cu factor reflecting building materials, and a Mn factor indicative of natural soil sources. Increasing home age was associated with greater Pb and As concentrations (5.0 and 0.48 mg/kg per year of home age, respectively), as were peeling paint and garden access. Therefore, these factors form important considerations for the development of evidence-based management strategies to reduce potential risks posed by indoor house dust. Recent findings indicate neurocognitive effects from low concentrations of metal exposures; hence, an understanding of the home exposome is vital.


Assuntos
Metaloides , Metais Pesados , Oligoelementos , China , Poeira/análise , Monitoramento Ambiental , Humanos , Metaloides/análise , Medição de Risco , Oligoelementos/análise
15.
Adv Mater ; 34(15): e2108425, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-34913205

RESUMO

Motivated by the high expectation for efficient electrostatic modulation of charge transport at very low voltages, atomically thin 2D materials with a range of bandgaps are investigated extensively for use in future semiconductor devices. However, researchers face formidable challenges in 2D device processing mainly originated from the out-of-plane van der Waals (vdW) structure of ultrathin 2D materials. As major challenges, untunable Schottky barrier height and the corresponding strong Fermi level pinning (FLP) at metal interfaces are observed unexpectedly with 2D vdW materials, giving rise to unmodulated semiconductor polarity, high contact resistance, and lowered device mobility. Here, FLP observed from recently developed 2D semiconductor devices is addressed differently from those observed from conventional semiconductor devices. It is understood that the observed FLP is attributed to inefficient doping into 2D materials, vdW gap present at the metal interface, and hybridized compounds formed under contacting metals. To provide readers with practical guidelines for the design of 2D devices, the impact of FLP occurring in 2D semiconductor devices is further reviewed by exploring various origins responsible for the FLP, effects of FLP on 2D device performances, and methods for improving metallic contact to 2D materials.

16.
ACS Appl Mater Interfaces ; 13(45): 54294-54300, 2021 Nov 17.
Artigo em Inglês | MEDLINE | ID: mdl-34739218

RESUMO

Two-dimensional (2D) transition-metal dichalcogenide (TMDC)-based semiconducting van der Waals (vdW) heterostructures are considered as potential candidates for next-generation nanoelectronics due to their unique and tunable properties. Controlling the carrier type and band alignment in 2D TMDCs and their vdW heterostructures is critical for realizing heterojunctions with the desired performances and functionalities. In this report, controlling the carrier type and band alignment in a vertical MoTe2/MoS2 heterojunction is presented via thickness engineering and surface charge transfer doping. A highly rectifying p-n diode and a nonrectifying n-n junction are obtained with different MoTe2 thicknesses due to their different doping conditions. A vertical tunnel diode is subsequently achieved with a controlled oxygen plasma treatment, which selectively induces degenerate p-type doping to MoTe2, whereas the intrinsic n-type characteristic of MoS2 is maintained during the treatment. These techniques to realize multifunctional diodes are universal and applicable to emerging nanoelectronics based on 2D materials.

17.
Environ Sci Technol ; 55(19): 13387-13399, 2021 10 05.
Artigo em Inglês | MEDLINE | ID: mdl-34546733

RESUMO

Blood lead (Pb) poisoning remains a global concern, particularly for children in their early developmental years. Broken Hill is Australia's oldest operating silver-zinc-lead mine. In this study, we utilized recent advances in machine learning to assess multiple algorithms and identify the most optimal model for predicting childhood blood Pb levels (BLL) using Broken Hill children's (<5 years of age) data (n = 23,749) from 1991 to 2015, combined with demographic, socio-economic, and environmental influencing factors. We applied model-agnostic methods to interpret the most optimal model, investigating different environmental and human factors influencing childhood BLL. Algorithm assessment showed that stacked ensemble, a method for automatically and optimally combining multiple prediction algorithms, enhanced predictive performance by 1.1% with respect to mean absolute error (p < 0.01) and 2.6% for root-mean-squared error (p < 0.01) compared to the best performing constituent algorithm (random forest). By interpreting the model, the following information was acquired: children had higher BLL if they resided within 1.0 km to the central mine area or 1.37 km to the railroad; year of testing had the greatest interactive strength with all other factors; BLL increased faster in Aboriginal than in non-Aboriginal children at 9-10 and 12-18 months of age. This "stacked ensemble + model-agnostic interpretation" framework achieved both prediction accuracy and model interpretability, identifying previously unconnected variables associated with elevated childhood BLL, offering a marked advantage over previous works. Thus, this approach has a clear value and potential for application to other environmental health issues.


Assuntos
Intoxicação por Chumbo , Chumbo , Algoritmos , Criança , Exposição Ambiental/análise , Humanos , Chumbo/análise , Aprendizado de Máquina
18.
Data Brief ; 37: 107151, 2021 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-34124323

RESUMO

Here we detail the soil to vegetable transfer factor (uptake) data and calculation procedures for vegetable trace metal uptake estimation that are presented in Taylor et al. (2021). Firstly, we present the literature review of trace metal uptake data, describing uptake from soil to vegetable produce determined in global experimental studies. After selecting the uptake factors most applicable to the VegeSafe dataset, using similar soil trace metal concentrations and studies that consider only the edible parts of plants, we applied these uptake factors to VegeSafe soils. Using this approach, we were able to estimate trace metal concentrations in home grown produce across the 3,609 homes included in our VegeSafe study. Using Australian and global food standards, we calculated the soil trace metal concentrations that would potentially result in exceedance of Australian and global food safety criteria. Our process followed the method detailed in the Australian soil guidelines (NEPM, 2013). Also presented are the numbers of individual samples and vegetable gardens that are likely to exceed food safety criteria in the three largest cities of Australia: Sydney, Melbourne and Brisbane. Individual household vegetable garden trace metal uptake data were aggregated across standarised geographic areas (Statistical Area Level 3) as established by the Australian Bureau of Statistics to visualise the geospatial distribution of potential trace metal risk from home produce. These modelled data provide the basis for prioritising locations, trace metals and soils for future empirically-based studies of trace metal contamination in home-grown produce.

19.
Chem Asian J ; 16(13): 1756-1761, 2021 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-33991065

RESUMO

P-type doping is of critical importance for the realization of certain high-performance electrical and optoelectronic devices based on molybdenum disulfide (MoS2 ). Charge transfer doping is a feasible strategy for tuning the conductance properties via facile treatment. In this work, the electrical properties of few-layer MoS2 were modulated with titanium(IV) bis(ammonium lactato) dihydroxide molecules (denoted as TALH) via physisorption. The functional groups such as electronegative hydroxyl (-OH) and carboxylate groups (-COO) included in TALH molecules are expected to induce p-doping effect through surface charge transfer when being attached to MoS2 . The p-doping is proved by X-ray photoelectron spectroscopy (XPS) with the downshift of Mo 3d and S 2p peaks. Control experiments and density functional theory calculations validate that the p-type doping mainly originated from the -OH group in TALH, which drew electrons from MoS2 . These results suggest that functional group-mediated p-doping effect show a path to modulate the carrier transition in MoS2, and enrich the molecule series for device modification.

20.
Environ Int ; 155: 106582, 2021 10.
Artigo em Inglês | MEDLINE | ID: mdl-33940394

RESUMO

We launched the VegeSafe program in 2013 to assist Australians concerned about exposure to contaminants in their soils and gardens. VegeSafe analyses garden soils provided by citizens for trace metals at our laboratory at little to no cost, with easy-to-follow guidance on any intervention required. The response was overwhelming-Australians submitted 17,256 soils from 3,609 homes, and in turn VegeSafe researchers now have unparalleled household-scale data, providing new insights into urban trace metal contamination. The results are sobering, with 35% of homes, particularly those that are older, painted and located in inner cities having soils above the Australian residential guideline (300 mg/kg) for the neurotoxic trace metal lead (Pb). Exposure pathway, blood Pb concentration and vegetable uptake modelling showed the communities in these locations were most at risk. VegeSafe is transformative: 94% of participants better understood contaminants, 83% felt safer in their home environment and 40% undertook remedial action based on their results. The two-way nature of this program enables education of citizens about environmental contaminants, advances public health, and delivers impactful science.


Assuntos
Ciência do Cidadão , Metais Pesados , Poluentes do Solo , Austrália , Cidades , Monitoramento Ambiental , Jardins , Humanos , Metais Pesados/análise , Solo , Poluentes do Solo/análise
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