Unravelling capability of two-stage thermophilic anaerobic membrane bioreactors for high organic loading wastewater: Effect of support media addition and irreversible fouling.

This study investigated the effects of adding polyvinyl alcohol (PVA) beads on the performance of methanogenic reactors and the fouling behavior of a two-stage thermophilic anaerobic membrane bioreactor (ThAnMBR) for treating wastewater at a feed chemical oxygen demand (COD) of 10 g/L. The PVA-added methanogenic reactor exhibited stable operation performance and offered a relatively low volatile fatty acid concentration effluent with a higher COD removal than the system without PVA addition. The predominant microbial communities in both methanogenic reactors were similar and were assigned to the genus Methanosaeta, followed by Clostridia, which was the predominant genus in the hydrolytic reactor. Ultrafiltration in the PVA-added system offered higher effluent quality and lower fouling resistance. The system was able to operate with hydraulically removable fouling, without any chemical cleaning requirements; however, an elevated flux caused the system to suffer from hydraulically irreversible fouling. PVA beads exhibit their structural stability over long-term operation.

Carbon black retention in saturated natural soils: Effects of flow conditions, soil surface roughness and soil organic matter.

We evaluated factors affecting the transport, retention, and re-entrainment of carbon black nanoparticles (nCBs) in two saturated natural soils under different flow conditions and input concentrations using the two-site transport model and Kelvin probe force microscopy (KPFM). Soil organic matter (SOM) was found to create unfavorable conditions for the retention. Despite an increased flow velocity, the relative stability of the estimated maximum retention capacity in soils may suggest that flow-induced shear stress forces were insufficient to detach nCB. The KPFM observation revealed that nCBs were retained at the grain boundary and on surface roughness, which brought about substantial discrepancy between theoretically-derived attachment efficiency factors and the ones obtained by the experiments using the two-site transport model. Thus, decreasing ionic strength and increasing solution pH caused re-entrainment of only a small fraction of retained nCB in the soil columns.