Experimental Investigation on the Effects of Mineral Water Composition on the Leaching of Cement-Based Materials.

The common phenomenon observed for concrete in aggressive water is leaching, which involves the dissolution of cement hydration products. Many studies have focused on leaching in demineralised water or acid attacks, but mineral water still deserves further investigation. In most standards, the aggressiveness of a given water body is determined by its pH and not its composition. The effect of the calcium content of the water on degradation is yet to be determined. In this paper, the leaching of Portland cement-based mortar was induced by two types of drinking water with different calcium contents and buffer capacity in controlled conditions. The Langelier saturation index (LSI) was used to describe water aggressiveness based on the calco-carbonic equilibrium. The studied waters had the same pH but LSIs of +0.5 and -1.0 corresponding to scaling with respect to aggressive water; demineralised water was used as a reference. Microstructural damage was checked by TGA and X-ray microtomography. Macroscopic measurements were used to monitor global degradation. The soft water caused a 53% deeper deterioration of the mortar sample than the hard water. Soft water-induced leaching was found to be similar yet slower to leaching via demineralised water (with a mass loss of -2.01% and -2.16% after 200 days, respectively). In contrast, hard water induced strongly time-dependent leaching, and the damage was located close to the surface. The roughness of leached specimens was 18% higher in hard water than in soft water. The formation of calcite on the sample surface not only affects the leaching rate by creating a protective surface layer, but it could also act as a calcium ion pump.

Effect of Retarders on the Reactivity and Hardening Rate of Alkali-Activated Blast Furnace Slag Grouts.

Sodium silicate-activated slags have the potential to harden quickly, which limits their practical use in grouting and deep soil mixing works. The open time of grouts is defined as the time period when their rheological properties allow their storage, pumping, and injection into the soil. In this work, the impact of the H2O/Na2O ratio and two acids (citric and boric acid) on the reactivity and hardening rates of slag-based grouts was studied. The H2O/Na2O ratio had a minimal impact on the open time but prolonged the setting time, as observed by ultrasonic characterization. Both acids were effective in delaying the structuration time, as revealed by oscillatory rheology and reaction advancement; however, they caused a decrease in the elastic modulus. Adding the acids resulted in a decrease in the pH of the medium, which may be linked to the extended open time. The analysis of the ion concentration of Ca, Si, and Al disclosed the mode of action of the two retarders.

Chemical Shrinkage of Low Water to Cement (w/c) Ratio CEM I and CEM III Cement Pastes Incorporating Silica Fume and Filler.

Chemical shrinkage (CS) is the reason behind early age cracking, a common problem for concrete with low water to cement ratios (w/c < 0.35) known as Ultra-High- and High-Performance Concrete (U-HPC). However, to avoid the crack development initiated by autogenous shrinkage, a precise measurement of CS is required, as the values obtained can determine the correct amount of internal curing agent to be added in the mixture to avoid crack formation. ASTM C1608 is the standardized method for performing CS tests. In this study, recommendations are provided to improve the reliability of results obtained with this standard method, such as good compaction of samples and the use of superplasticizer (SP) for low w/c ratios (≤0.2). Cement pastes with CEM I and CEM III have been tested at different w/c ratios equal to 0.2, 0.3 and 0.4 with and without the addition of superplasticizer. CS results following ASTM-C1608 dilatometry showed that the presence of mineral additions such as silica fume and filler reduced the chemical shrinkage, while CS increased with increasing w/c. Low w/c ratio pastes of CEM III had slightly higher CS rates than CEM I, while the opposite was noticed at higher w/c. SEM images illustrated the importance of a careful compaction and SP use.

Mesoscale analysis of failure in quasi-brittle materials: comparison between lattice model and acoustic emission data.

The purpose of this paper is to analyse the development and the evolution of the fracture process zone during fracture and damage in quasi-brittle materials. A model taking into account the material details at the mesoscale is used to describe the failure process at the scale of the heterogeneities. This model is used to compute histograms of the relative distances between damaged points. These numerical results are compared with experimental data, where the damage evolution is monitored using acoustic emissions. Histograms of the relative distances between damage events in the numerical calculations and acoustic events in the experiments exhibit good agreement. It is shown that the mesoscale model provides relevant information from the point of view of both global responses and the local failure process. © 2015 The Authors. International Journal for Numerical and Analytical Methods in Geomechanics published by John Wiley & Sons Ltd.

Validation of a thermal bias control technique for Coda Wave Interferometry (CWI).

The Coda Wave Interferometry (CWI) analysis serves to monitor the variation of propagation velocity in a heterogeneous medium with high precision (10(-3)% in relative terms). In combination with acoustoelastic theory, this type of analysis offers an NDT method for stress evaluation and/or damage detection. Since the CWI method is intended to evaluate extreme levels of accuracy, the presence of bias under certain circumstances can undermine evaluation results and/or test repeatability. In this paper, we offer a bias control technique involving the use of a second (reference) specimen for CWI analysis that is designed to compensate: (1) the thermally-induced velocity variation due to environmental temperature fluctuations; and (2) bias originating from experimental procedures. The presentation of this technique contains both a theoretical analysis and experimental protocol for the purpose of implementation. Furthermore, comparisons of experimental results have been included in order to demonstrate the utility of this bias control technique under laboratory conditions.

Study of stress-induced velocity variation in concrete under direct tensile force and monitoring of the damage level by using thermally-compensated Coda Wave Interferometry.

In this paper, we describe an experimental study of concrete behavior under a uniaxial tensile load by use of the thermally-compensated Coda Wave Interferometry (CWI) analysis. Under laboratory conditions, uniaxial tensile load cycles are imposed on a cylindrical concrete specimen, with continuous ultrasonic measurements being recorded within the scope of bias control protocols. A thermally-compensated CWI analysis of multiple scattering waves is performed in order to evaluate the stress-induced velocity variation. Concrete behavior under a tensile load can then be studied, along with CWI results from both its elastic performance (acoustoelasticity) and plastic performance (microcracking corresponding to the Kaiser effect). This work program includes a creep test with a sustained, high tensile load; the acoustoelastic coefficients are estimated before and after conducting the creep test and then used to demonstrate the effect of creep load.