Thermally stable Ni foam-supported inverse CeAlOx/Ni ensemble as an active structured catalyst for CO2 hydrogenation to methane.

Nickel is the most widely used inexpensive active metal center of the heterogeneous catalysts for CO2 hydrogenation to methane. However, Ni-based catalysts suffer from severe deactivation in CO2 methanation reaction due to the irreversible sintering and coke deposition caused by the inevitable localized hotspots generated during the vigorously exothermic reaction. Herein, we demonstrate the inverse CeAlOx/Ni composite constructed on the Ni-foam structure support realizes remarkable CO2 methanation catalytic activity and stability in a wide operation temperature range from 240 to 600 °C. Significantly, CeAlOx/Ni/Ni-foam catalyst maintains its initial activity after seven drastic heating-cooling cycles from RT to 240 to 600 °C. Meanwhile, the structure catalyst also shows water resistance and long-term stability under reaction condition. The promising thermal stability and water-resistance of CeAlOx/Ni/Ni-foam originate from the excellent heat and mass transport efficiency which eliminates local hotspots and the formation of Ni-foam stabilized CeAlOx/Ni inverse composites which effectively anchored the active species and prevents carbon deposition from CH4 decomposition.

Analysis of Factors Influencing the Duration of Early Enteral Nutrition Support in Patients Diagnosed with Acute Pancreatitis.

Objective: This study aimed to assess the current status of early enteral nutrition (EN) support among patients diagnosed with acute pancreatitis (AP) and analyze the factors influencing its duration. The findings aimed to provide guidance for the development of tailored EN support protocols for pancreatitis patients. Methods: A convenience sampling method was employed, and 51 patients diagnosed with acute pancreatitis (AP) were enrolled from the Gastroenterology Department of Zhoushan Hospital between May 2020 and June 2021. Data analysis included the categorization of patients based on their early enteral nutrition (EN) support duration, followed by thorough statistical analysis, including logistic regression, to identify the factors impacting EN duration. Results: The mean duration of early EN support among AP patients was (93.57 ± 43.29) hours. A mere 13.73% of patients initiated EN within 48 hours of admission. Upon categorizing patients by the median duration of EN support, multiple logistic regression analysis revealed several significant risk factors influencing the duration of EN in AP patients, including patient age, underlying medical conditions, severity of pancreatitis, nutritional status, and blood lipase levels (P < .05). Conclusion: The study highlights the significant influence of disease severity and patients' functional status on the duration of early EN support in AP cases. It emphasizes the importance of a comprehensive patient assessment by medical professionals to determine the optimal timing for initiating EN support.

Surface-Phosphorylated Ceria for Chlorine-Tolerance Catalysis.

An improved fundamental understanding of active site structures can unlock opportunities for catalysis from conceptual design to industrial practice. Herein, we present the computational discovery and experimental demonstration of a highly active surface-phosphorylated ceria catalyst that exhibits robust chlorine tolerance for catalysis. Ab initio molecular dynamics (AIMD) calculations and in situ near-ambient pressure X-ray photoelectron spectroscopy (in situ NAP-XPS) identified a predominantly HPO4 active structure on CeO2(110) and CeO2(111) facets at room temperature. Importantly, further elevating the temperature led to a unique hydrogen (H) atom hopping between coordinatively unsaturated oxygen and the adjacent P═O group of HPO4. Such a mobile H on the catalyst surface can effectively quench the chlorine radicals (Cl•) via an orientated reaction analogous to hydrogen atom transfer (HAT), enabling the surface-phosphorylated CeO2-supported monolithic catalyst to exhibit both expected activity and stability for over 68 days during a pilot test, catalyzing the destruction of a complex chlorinated volatile organic compound industrial off-gas.

Recent advances in the theoretical studies on the electrocatalytic CO2 reduction based on single and double atoms.

Excess of carbon dioxide (CO2) in the atmosphere poses a significant threat to the global climate. Therefore, the electrocatalytic carbon dioxide reduction reaction (CO2RR) is important to reduce the burden on the environment and provide possibilities for developing new energy sources. However, highly active and selective catalysts are needed to effectively catalyze product synthesis with high adhesion value. Single-atom catalysts (SACs) and double-atom catalysts (DACs) have attracted much attention in the field of electrocatalysis due to their high activity, strong selectivity, and high atomic utilization. This review summarized the research progress of electrocatalytic CO2RR related to different types of SACs and DACs. The emphasis was laid on the catalytic reaction mechanism of SACs and DACs using the theoretical calculation method. Furthermore, the influences of solvation and electrode potential were studied to simulate the real electrochemical environment to bridge the gap between experiments and computations. Finally, the current challenges and future development prospects were summarized and prospected for CO2RR to lay the foundation for the theoretical research of SACs and DACs in other aspects.

Tuning Ionic Liquid-Based Catalysts for CO2 Conversion into Quinazoline-2,4(1H,3H)-diones.

Carbon capture and storage (CCS) and carbon capture and utilization (CCU) are two kinds of strategies to reduce the CO2 concentration in the atmosphere, which is emitted from the burning of fossil fuels and leads to the greenhouse effect. With the unique properties of ionic liquids (ILs), such as low vapor pressures, tunable structures, high solubilities, and high thermal and chemical stabilities, they could be used as solvents and catalysts for CO2 capture and conversion into value-added chemicals. In this critical review, we mainly focus our attention on the tuning IL-based catalysts for CO2 conversion into quinazoline-2,4(1H,3H)-diones from o-aminobenzonitriles during this decade (2012~2022). Due to the importance of basicity and nucleophilicity of catalysts, kinds of ILs with basic anions such as [OH], carboxylates, aprotic heterocyclic anions, etc., for conversion CO2 and o-aminobenzonitriles into quinazoline-2,4(1H,3H)-diones via different catalytic mechanisms, including amino preferential activation, CO2 preferential activation, and simultaneous amino and CO2 activation, are investigated systematically. Finally, future directions and prospects for CO2 conversion by IL-based catalysts are outlined. This review is benefit for academic researchers to obtain an overall understanding of the synthesis of quinazoline-2,4(1H,3H)-diones from CO2 and o-aminobenzonitriles by IL-based catalysts. This work will also open a door to develop novel IL-based catalysts for the conversion of other acid gases such as SO2 and H2S.

Tuning Functionalized Ionic Liquids for CO2 Capture.

The increasing concentration of CO2 in the atmosphere is related to global climate change. Carbon capture, utilization, and storage (CCUS) is an important technology to reduce CO2 emissions and to deal with global climate change. The development of new materials and technologies for efficient CO2 capture has received increasing attention among global researchers. Ionic liquids (ILs), especially functionalized ILs, with such unique properties as almost no vapor pressure, thermal- and chemical-stability, non-flammability, and tunable properties, have been used in CCUS with great interest. This paper focuses on the development of functionalized ILs for CO2 capture in the past decade (2012~2022). Functionalized ILs, or task-specific ILs, are ILs with active sites on cations or/and anions. The main contents include three parts: cation-functionalized ILs, anion-functionalized ILs, and cation-anion dual-functionalized ILs for CO2 capture. In addition, classification, structures, and synthesis of functionalized ILs are also summarized. Finally, future directions, concerns, and prospects for functionalized ILs in CCUS are discussed. This review is beneficial for researchers to obtain an overall understanding of CO2-philic ILs. This work will open a door to develop novel IL-based solvents and materials for the capture and separation of other gases, such as SO2, H2S, NOx, NH3, and so on.

Covalent Organic Frameworks with Ionic Liquid-Moieties (ILCOFs): Structures, Synthesis, and CO2 Conversion.

CO2, an acidic gas, is usually emitted from the combustion of fossil fuels and leads to the formation of acid rain and greenhouse effects. CO2 can be used to produce kinds of value-added chemicals from a viewpoint based on carbon capture, utilization, and storage (CCUS). With the combination of unique structures and properties of ionic liquids (ILs) and covalent organic frameworks (COFs), covalent organic frameworks with ionic liquid-moieties (ILCOFs) have been developed as a kind of novel and efficient sorbent, catalyst, and electrolyte since 2016. In this critical review, we first focus on the structures and synthesis of different kinds of ILCOFs materials, including ILCOFs with IL moieties located on the main linkers, on the nodes, and on the side chains. We then discuss the ILCOFs for CO2 capture and conversion, including the reduction and cycloaddition of CO2. Finally, future directions and prospects for ILCOFs are outlined. This review is beneficial for academic researchers in obtaining an overall understanding of ILCOFs and their application of CO2 conversion. This work will open a door to develop novel ILCOFs materials for the capture, separation, and utilization of other typical acid, basic, or neutral gases such as SO2, H2S, NOx, NH3, and so on.

Selective Ru Adsorption on SnO2/CeO2 Mixed Oxides for Efficient Destruction of Multicomponent Volatile Organic Compounds: From Laboratory to Practical Possibility.

Ru-based catalysts have been extensively employed for the catalytic destruction of chlorinated volatile organic compounds (VOCs), but their versatility for other routine VOCs' destruction has been less explored. Herein, we show that Ru-decorated SnO2/CeO2 mixed oxides can sustain H2O and HCl poisonings and are endowed with extraordinary versatility for a wide range of VOCs' destruction. Selective adsorption of Ru on the cassiterite SnO2 and CeO2 nanorods through a Coulomb force can rationally tune the oxidation and dechlorination centers on decorated catalysts, where the epitaxial growth of RuOx on top of SnO2 is endowed with excellent dechlorination ability and that on CeO2 is functional as an oxidation center; the latter could also activate H2O to provide sufficient H protons for HCl formation. Our developed Ru/SnO2/CeO2 catalyst can steadily destruct mono-chlorobenzene, ortho-dichlorobenzene, trichloroethylene, dichloromethane, epichlorohydrin, N-hexane, ethyl acetate, toluene, and their mixtures at an optimum temperature of 300 °C, and its monolithic form is also functional at this temperature with few dioxins being detected in the off-gas. Our results imply that the Ru-decorated SnO2/CeO2 catalyst can meet the demands of regenerative catalytic oxidation for the treatment of a wide range of VOCs from industrial exhausts.

Hydrothermal-treated Pt/Al2O3 as an excellent catalyst for toluene total oxidation.

The preparation of highly active supported noble metal catalysts with a low noble metal loading has always been the ultimate goal of researchers working on catalysis. Hydrothermally treated Pt/Al2O3 (Pt/Al2O3-H) exhibits better catalytic activity than that (Pt/Al2O3-C) treated via the conventional calcination approach. At the high space velocity of 100,000 mL/(g∙hr), the temperature that correspond to 50% toluene conversion (T50) of Pt/Al2O3-H is 115°C lower than that of Pt/Al2O3-C, and the turnover frequency (TOF) value can reach 0.0756 sec-1. The mechanism by which the hydrothermal approach enhances Pt/Al2O3 activity has been investigated. The structure associated with the high catalytic activity of Pt nanoparticles (NPs) can be retained via hydrothermal treatment. Furthermore, the support is transformed to AlO(OH) with numerous surface hydroxyl groups, which in turn can facilitate the adsorption of toluene. And the synergistic effects of Pt NPs and AlO(OH) increases the contents of Pt in oxidation state and active oxygen, which are beneficial for toluene oxidation.

3D hollow Bi2O3@CoAl-LDHs direct Z-scheme heterostructure for visible-light-driven photocatalytic ammonia synthesis.

In this paper, the novel 3D hollow Z-scheme heterojunction photocatalysts based on Bi2O3 and CoAl layered double hydroxides (Bi2O3@CoAl-LDHs) were prepared for efficient visible-light-driven photocatalytic ammonia synthesis. The synthesized nanohybrid exhibits excellent photocatalytic ammonia synthesis performance (48.7 µmol·L-1·h-1) and structural stability, which is primarily attributed to the fact that Z-scheme heterojunction significantly enhanced lifetime of photogenerated carriers (6.22 ns) and transfer efficiency of surface photogenerated electrons (72.5%). Strict control experiments and nitrogen isotope labeling results show that nitrogen and hydrogen in the produced ammonia come from nitrogen and water in the reactant respectively. Electron paramagnetic resonance (EPR) experiments and density functional theory (DFT) calculations further reveal that the built-in electric field due to the difference between Bi2O3 and CoAl-LDHs is the key to constructing the Z-scheme heterojunction. In addition, results of partial density of states (PDOS) show that Co in Bi2O3@CoAl-LDHs composite is the active site for photocatalytic N2 fixation.

Preparation of hydrophobic hierarchical pore carbon-silica composite and its adsorption performance toward volatile organic compounds.

Carbon-silica materials with hierarchical pores consisting of micropores and mesopores were prepared by introducing nanocarbon microspheres derived from biomass sugar into silica gel channels in a hydrothermal environment. The physicochemical properties of the materials were characterized by nitrogen physical adsorption (BET), scanning electron microscopy (SEM), and thermogravimetric (TG), and the adsorption properties of various organic waste gases were investigated. The results showed that microporous carbon materials were introduced successfully into the silica gel channels, thus showing the high adsorption capacity of activated carbon in high humidity organic waste gas, and the high stability and mechanical strength of the silica gel. The dynamic adsorption behavior confirmed that the carbon-silica material had excellent adsorption capacity for different volatile organic compounds (VOCs). Furthermore, the carbon-silica material exhibited excellent desorption characteristics: adsorbed toluene was completely desorbed at 150°C, thereby showing superior regeneration characteristics. Both features were attributed to the formation of hierarchical pores.

CO2 Photoreduction to CH4 Performance Under Concentrating Solar Light.

We demonstrate a method for the enhancement of CO2 photoreduction. As the driving force of a photocatalytic reaction is from solar light, the basic idea is to use concentration technology to raise the incident solar light intensity. Concentrating a large-area light onto a small area cannot only increase light intensity, but also reduce the catalyst amount, as well as the reactor volume, and increase the surface temperature. The concentration of light can be realized by different devices. In this manuscript, it is realized by a Fresnel lens. The light penetrates the lens and is concentrated on a disc-shaped catalyst. The results show that both the reaction rate and the total yield are efficiently increased. The method can be applied to most CO2 photoreduction catalysts, as well as to similar reactions with a low reaction rate at natural light.

Effect of Ni-V loading on the performance of hollow anatase TiO2 in the catalytic combustion of dichloromethane.

A catalyst based on mixed V-Ni oxides supported on TiO2 (Ni-V/TiO2) was obtained using the sol-gel method. Its catalytic performance relative to dichloromethane (DCM) degradation was investigated. Characterization and analysis were conducted using transmission electron microscopy, H2 temperature-programmed reduction, pyridine-Fourier transform infrared spectroscopy (FTIR) characterization, and X-ray diffraction. Results showed that the original hollow anatase structure of pure TiO2 was well-maintained after Ni-V loading. The loading of NiO-VOx not only significantly improved the stability of pure TiO2 but also inhibited the formation of the by-product monochloromethane (MCM). Among the series of Ni-V/TiO2 catalysts, 4%Ni-V/TiO2 possessed the highest catalytic activity, with 90% DCM conversion at only 203°C. No by-products and no significant changes in the catalytic activity were observed during combustion of DCM after 100 hr of a continuous stability test. Furthermore, thermogravimetric analysis (O2-TG) and energy dispersive spectrometer (EDS) characterization of the used 4%Ni-V/TiO2 catalyst revealed that no coke deposition or chlorine species could be detected on the catalyst surface.

TiO2-SiO2 supported MnWO x catalysts by liquid-phase deposition for low-temperature NH3-SCR.

NH3-SCR is an environmentally important reaction for the abatement of NO x from different resources. MnO2-based catalyst has attracted significant attention due to the excellent activity. In this paper, a series of MnWO x /TiO2-SiO2 catalysts were prepared by liquid-phase deposition method. The catalysts were characterized by N2 adsorption/desorption, XRD, TEM, XPS, FT-IR, H2-TPR, TG and water adsorption capacity. The existence of SiO2 improved the SO2 and H2O resistance of the MnWO x /TiO2-SiO2 catalyst without decreasing the NH3-SCR activity. Under the reaction conditions of 260°C and 60 000 ml gcata h-1 gas hourly space velocity (GHSV), the NO conversion was kept stable at about 95% for 140 min on stream. The excellent performance of MnWO x /TiO2-SiO2 catalyst is considered to be originated from the texture properties and active species dispersion improvement by SiO2 in the support and low-temperature preparation.

Preparation of metallic monolithic Pt/FeCrAl fiber catalyst by suspension spraying for VOCs combustion.

We report a facile and general strategy for the preparation of metallic monolithic catalysts. Our strategy involved subjecting the surfaces of FeCrAl fibers to thermal treatment and the spraying of Pt nanoparticles suspension liquid. The catalyst exhibited high catalytic activity and good stability in the combustion of volatile organic compounds to CO2 and H2O at mild temperature. The exceptional activity of the catalyst can be attributed to the well-adhered alumina coating that formed on the surfaces of the FeCrAl fibers after thermal treatment and the highly dispersed Pt nanoparticles on the surface of the alumina coating.

Mesoporous MnCeOx solid solutions for low temperature and selective oxidation of hydrocarbons.

The development of noble-metal-free heterogeneous catalysts that can realize the aerobic oxidation of C-H bonds at low temperature is a profound challenge in the catalysis community. Here we report the synthesis of a mesoporous Mn0.5Ce0.5Ox solid solution that is highly active for the selective oxidation of hydrocarbons under mild conditions (100-120 °C). Notably, the catalytic performance achieved in the oxidation of cyclohexane to cyclohexanone/cyclohexanol (100 °C, conversion: 17.7%) is superior to those by the state-of-art commercial catalysts (140-160 °C, conversion: 3-5%). The high activity can be attributed to the formation of a Mn0.5Ce0.5Ox solid solution with an ultrahigh manganese doping concentration in the CeO2 cubic fluorite lattice, leading to maximum active surface oxygens for the activation of C-H bonds and highly reducible Mn(4+) ions for the rapid migration of oxygen vacancies from the bulk to the surface.

Constructing Hierarchical Interfaces: TiO2-Supported PtFe-FeO(x) Nanowires for Room Temperature CO Oxidation.

In this communication, we report a facile approach to constructing catalytic active hierarchical interfaces in one-dimensional (1D) nanostructure, exemplified by the synthesis of TiO2-supported PtFe-FeO(x) nanowires (NWs). The hierarchical interface, constituting atomic level interactions between PtFe and FeO(x) within each NW and the interactions between NWs and support (TiO2), enables CO oxidation with 100% conversion at room temperature. We identify the role of the two interfaces by probing the CO oxidation reaction with isotopic labeling experiments. Both the oxygen atoms (Os) in FeO(x) and TiO2 participate in the initial CO oxidation, facilitating the reaction through a redox pathway. Moreover, the intact 1D structure leads to the high stability of the catalyst. After 30 h in the reaction stream, the PtFe-FeO(x)/TiO2 catalyst exhibits no activity decay. Our results provide a general approach and new insights into the construction of hierarchical interfaces for advanced catalysis.

Promoting effect of vanadium on catalytic activity of Pt/Ce-Zr-O diesel oxidation catalysts.

A series of Pt-V/Ce-Zr-O diesel oxidation catalysts was prepared using the impregnation method. The catalytic activity and sulfur resistance of Pt-V/Ce-Zr-O were investigated in the presence of simulated diesel exhaust. The effect of vanadium on the structure and redox properties of the catalysts was also investigated using the Brunauer-Emmett-Teller method, X-ray diffraction, H2 temperature-programmed reduction, CO temperature-programmed desorption, X-ray photoelectron spectroscopy, and Energy Dispersive Spectroscopy. Results showed that the Pt particles were well dispersed on the Ce-Zr-O carrier through the vanadium isolation effect, which significantly improved the oxidation activity toward CO and hydrocarbons. An electron-withdrawing phenomenon occurred from V to Pt, resulting in an increase in the metallic nature of platinum, which was beneficial to hydrocarbon molecular activation.

Cu-Mn-Ce ternary mixed-oxide catalysts for catalytic combustion of toluene.

Cu-Mn, Cu-Mn-Ce, and Cu-Ce mixed-oxide catalysts were prepared by a citric acid sol-gel method and then characterized by XRD, BET, H2-TPR and XPS analyses. Their catalytic properties were investigated in the toluene combustion reaction. Results showed that the Cu-Mn-Ce ternary mixed-oxide catalyst with 1:2:4 mole ratios had the highest catalytic activity, and 99% toluene conversion was achieved at temperatures below 220°C. In the Cu-Mn-Ce catalyst, a portion of Cu and Mn species entered into the CeO2 fluorite lattice, which led to the formation of a ceria-based solid solution. Excess Cu and Mn oxides existed on the surface of the ceria-based solid solution. The coexistence of Cu-Mn mixed oxides and the ceria-based solid solution resulted in a better synergetic interaction than the Cu-Mn and Cu-Ce catalysts, which promoted catalyst reducibility, increased oxygen mobility, and enhanced the formation of abundant active oxygen species.

Ionic liquid-mediated synthesis of meso-scale porous lanthanum-transition-metal perovskites with high CO oxidation performance.

Lanthanum-transition-metal perovskites with robust meso-scale porous frameworks (meso-LaMO3) are synthesized through the use of ionic liquids. The resultant samples demonstrate a rather high activity for CO oxidation, by taking advantage of unique nanostructure-derived benefits. This synthesis strategy opens up a new opportunity for preparing functional mesoporous complex oxides of various compositions.