Non-targeted analysis based on quantitative prediction and toxicity assessment for emerging contaminants in tire particle leachates.

Non-targeted analysis (NTA) has great potential to screen emerging contaminants in the environment, and some studies have conducted in-depth investigation on environmental samples. Here, we used a NTA workflow to identify emerging contaminants in used tire particle (TP) leachates, followed by quantitative prediction and toxicity assessment based on hazard scores. Tire particles were obtained from four different types of automobiles, representing the most common tires during daily transportation. With the instrumental analysis of TP leachates, a total of 244 positive and 104 negative molecular features were extracted from the mass data. After filtering by a specialized emerging contaminants list and matching by spectral databases, a total of 51 molecular features were tentatively identified as contaminants, including benzothiazole, hexaethylene glycol, 2-hydroxybenzaldehyde, etc. Given that these contaminants have different mass spectral responses in the mass spectrometry, models for predicting the response of contaminants were constructed based on machine learning algorithms, in this case random forest and artificial neural networks. After five-fold cross-validation, the random forest algorithm model had better prediction performance (MAECV = 0.12, Q2 = 0.90), and thus it was chosen to predict the contaminant concentrations. The prediction results showed that the contaminant at the highest concentration was benzothiazole, with 4,875 µg/L in the winter tire sample. In addition, the joint toxicity assessment of four types of tires was conducted in this study. According to different hazard levels, hazard scores increasing by a factor 10 were developed, and hazard scores of all the contaminants identified in each TP leachate were summed to obtain the total hazard score. All four tires were calculated to have relatively high risks, with winter tires having the highest total hazard score of 40,751. This study extended the application of NTA research and led to the direction of subsequent targeting studies on highly concentrated and toxic contaminants.

Determination of organotin compounds in marine sediments from Arctic Svalbard and West Antarctic Fildes Peninsula.

This study investigated the contamination levels of five typical organotin compounds in Arctic and Antarctic marine sediments. Organotin total concentrations ranged from not detected (ND) to 37.9 ng Sn/g dw and from ND to 34.0 ng Sn/g dw in surface sediments of Svalbard and Fildes Peninsula, respectively. Dibutyltin accounted for 11.3 %-100 % of butyltins in Arctic sediments, whilst diphenyltin was the predominant phenyltin species in both Arctic and Antarctic. However, the concentrations of tributyltin and triphenyltin were lower than low-substituted organotins in the study areas, indicating the effectiveness of international ban on the use of triorganotin-based antifouling paints. No significant difference in organotin contamination was found between Arctic and Antarctic, although the time suffered from human interference was shorter in the Antarctic. Overall, these data can provide a diagnosis of recent organotin inputs in polar regions and serve as a baseline for future study assessing their local applications.

Machine learning-assisted assessment of key meteorological and crop factors affecting historical mulch pollution in China.

Degraded mulch pollution is of a great concern for agricultural soils. Although numerous studies have examined this issue from an environmental perspective, there is a lack of research focusing on crop-specific factors such as crop type. This study aimed to explore the correlation between meteorological and crop factors and mulch contamination. The first step was to estimate the amounts of mulch-derived microplastics (MPs) and phthalic acid esters (PAEs) during the rapid expansion period (1993-2012) of mulch usage in China. Subsequently, the Elastic Net (EN) and Random Forest (RF) models were employed to process a dataset that included meteorological, crop, and estimation data. At the national level, the RF model suggested that coldness in fall was crucial for MPs generation, while vegetables acted as a key factor for PAEs release. On a regional scale, the EN results showed that crops like vegetables, cotton, and peanuts remained significantly involved in PAEs contamination. As for MPs generation, coldness prevailed over all regions. Aridity became more critical for southern regions compared to northern regions due to solar radiation. Lastly, each region possessed specific crop types that could potentially influence its MPs contamination levels and provide guidance for developing sustainable ways to manage mulch contamination.

Occurrence and sources of microplastics and polycyclic aromatic hydrocarbons in surface sediments of Svalbard, Arctic.

Due to the distinct environment condition and geographic location, Svalbard has been recognized as a potential pollution reservoir in the Arctic. In this study, 8 surface sediment samples were collected from two fjords in Svalbard (Kongsfjorden and Rijpfjorden) in 2017, and they were searched for microplastics and polycyclic aromatic hydrocarbons (PAHs). PAHs were also investigated in 10 soil samples of Ny-Ålesund for local anthropogenic source analysis. The level of microplastics and other anthropogenic particles ranged from not detected (ND) to 4.936 particles/kg dry weight (DW). Fiber was the only shape of the microplastics found and three polymers (polyester, rayon and cellulose) were detected, which suggested that fisheries-related debris and textile materials were possible sources of microplastics and anthropogenic particles. For PAHs, the level of ∑26PAH was 9.2 ng/g to 67.1 ng/g (DW), and were dominated by lnP and BghiP, indicating petroleum combustion source. Further analysis revealed that traffic emissions from cars and diesel combustion from a local power plant were major sources of PAHs in soils of Ny-Alesund, while traffic emissions from ships were the dominate source of PAHs in sediments of Kongsfjorden and Rijpfjorden. A higher level of PAHs was observed in Ny-Alesund, confirming an anthropogenic input, while transport via ocean currents might contribute to the higher abundance of microplastics in Rijpfjorden. Further research and even long-term observation of pollutants are needed to fully understand the pollution status in polar regions.

Fibrous and filmy microplastics exert opposite effects on the mobility of nanoplastics in saturated porous media.

This study explored the influence of fibrous and filmy polyethylene terephthalate (PET) on the transportation of nanoplastics (NPs) in saturated porous media. With the strong electrostatic repulsion, the negatively charged PET fibers (-57.5 mV) improved the transport of NPs, and the mass percentage of NPs recovered from the effluent (Meff) increased from 69.3% to 86.7%. However, PET films (-49.7 mV) showed the opposite result, that is, Meff decreased from 69.3% to 57.0%. X-ray micro-computed tomography quantitatively revealed the change in effective porosity of porous media before and after adding various PET MPs. The addition of 10 mm fiber increased the porosity from 0.39 to 0.43, whereas the addition of 10 × 10 mm2 film reduced the porosity from 0.39 to 0.29. The fiber-facilitated transport of NPs is presumably due to the formation of new connected pores between fibers and sand grains, whereas the film-inhibited transport of NPs may be due to the partial truncation of transport path of NPs. Overall, the effect of coexisting MPs on the mobility of NPs strongly relies on the shape and size of MPs.

Ecological Risk Assessment of Trace Metal in Pacific Sector of Arctic Ocean and Bering Strait Surface Sediments.

The arctic region is a remote area with relatively few anthropogenic inputs, but there is increasing concern over toxic trace metal contamination in the Arctic Ocean. In this study, distribution characteristics of eight trace metals in the surface sediment of the Pacific Sector of the Arctic Ocean and Bering Strait are analyzed. The geochemical baseline value of each metal element is explored using the relative cumulative frequency curve method; the enrichment factor (EF), geo-accumulation index (Igeo) and potential ecological risk index (RI) are applied to assess the ecological risk level of the trace metals. According to the results, Cu, As and Hg had a little more content variation, and their contents in some areas were significantly higher than the previous reports. EF values show an obvious enrichment of element As, followed by Cr element with the moderate enrichment; the enrichment of the other six elements are not related to human activity. The Igeo value shows a moderately contaminated to heavily contaminated level of As and a moderately contaminated level of Cr. According to the potential ecological risk indexes in each site, most sites are at a low ecological risk level except five sites with RI/baseline values exceeding 150 which are at a moderate ecological risk level.

Investigation of microplastic pollution in Arctic fjord water: a case study of Rijpfjorden, Northern Svalbard.

Microplastic contamination is an emerging issue in the marine environment including the Arctic. However, the occurrence of microplastics in the Arctic fjords remains less understood. Sample collections were conducted by trawling horizontally in surface water (0-0.4-m depth) and trawling vertically in the water column (0-200-m depth) to investigate the abundance, composition, and distribution of microplastics in the Rijpfjorden, Northern Svalbard, in the summer of 2017. Laser Direct Infrared chemical imaging technique was applied for the counting and identification of microplastic particles. A total of 1010 microplastic particles and 14 mesoplastics were identified from 41,038 particles in eight samples from the Rijpfjorden. The abundance of microplastics larger than 300 µm was 0.15 ± 0.19 n/m3 in surface water, and 0.15 ± 0.03 n/m3 in the water column of the Rijpfjorden. The microplastic particles identified in Rijpfjorden water consisted of 10 types of polymers. The dominant microplastics are polyurethane, polyethylene, polyvinyl acetate, polystyrene, polypropylene, and alkyd varnish. Historical ship activities and newly melted sea ice might be major sources of microplastics in the seawater of Rijpfjorden. In general, contamination of microplastics larger than 300 µm in Rijpfjorden water is at a low level in comparison to other polar waters. Further research is needed to confirm the origin and fate of microplastics below 300 µm in Arctic fjords.

Non-targeted analysis for organic components of microplastic leachates.

Organic components of microplastic leachates were investigated in an integrated non-targeted analysis study that included statistical analysis on leachates generated under different leaching scenarios. Leaching experiments were undertaken with simulated gastric fluid (SGF), river water, and seawater with common polymer types, including polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, and polyester fabrics comprising both raw and recycled materials. Totals of 111.0 ± 26.7, 98.5 ± 20.3, and 53.5 ± 4.7 different features were tentatively identified as compounds in SGF, freshwater, and seawater leachates, respectively, of which 5 compounds were confirmed by reference standards. The leaching capacities of the media were compared, and the clusters of structurally related features leached in the same medium were studied. For leachates generated from raw and recycled plastics, volcano plots and Pearson's Chi-squared tests were used to identify characteristic features. More characteristic features (3-20) had an average intensity across all recycled plastics that were significantly higher (p < 0.05) than that (1-3) of raw plastics under different conditions. The results indicate that gastric solution is more likely to leach components from microplastics, and there exists the difference of leachate's organic composition between raw and recycled materials, providing new insights into understanding microplastic environmental effects.

Genome sequencing of biocontrol strain Bacillus amyloliquefaciens Bam1 and further analysis of its heavy metal resistance mechanism.

Plant growth-promoting rhizobacteria (PGPR) or Biocontrol strains inevitably encounter heavy metal excess stress during the product's processing and application. Bacillus amyloliquefaciens Bam1 was a potential biocontrol strain with strong heavy metal resistant ability. To understand its heavy metal resistance mechanism, the complete genome of Bam1 had been sequenced, and the comparative genomic analysis of Bam1 and FZB42, an industrialized PGPR and biocontrol strain with relatively lower heavy metal tolerance, was conducted. The comparative genomic analysis of Bam1 and the other nine B. amyloliquefaciens strains as well as one Bacillus velezensis (genetically and physiologically very close to B. amyloliquefaciens) was also performed. Our results showed that the complete genome size of Bam1 was 3.95 Mb, 4219 coding sequences were predicted, and it possessed the highest number of unique genes among the eleven analyzed strains. Nine genes related to heavy metal resistance were detected within the twelve DNA islands of Bam1, while only two of them were detected within the seventeen DNA islands of FZB42. When compared with B. amyloliquefaciens type strain DSM7, Bam1 lacked contig L, whereas FZB42 lacked contig D and I, as well as just possessed contig B with a very small size. Our results could also deduce that Bam1 promoted its essential heavy metal resistance mainly by decreasing the import and increasing the export of heavy metals with the corresponding homeostasis systems, which are regulated by different metalloregulators. While Bam1 promoted its non-essential heavy metal resistance mainly by the activation of some specific or non-specific exporters responding to different heavy metals. The variation of the genes related to heavy metal resistance and the other differences of the genomes, including the different number and arrangement of contigs, as well as the number of the heavy metal resistant genes in Prophages and Genomic islands, led to the significant different resistance of Bam1 and FZB42 to heavy metals.

Occurrence, distribution and risk assessment of organophosphate ester flame retardants and plasticizers in surface seawater of the West Pacific.

Twenty-eight samples of surface seawater were collected from the West Pacific Ocean during 2019 using a high-volume solid-phase extraction with high-throughput organic analysis (Hi-throat/Hi-volume SPE) method, and concentrations of 10 organophosphate ester flame retardants and plasticizers (OPEs) were determined. The total OPE concentration in the samples was 3.02-48.4 ng L-1 (mean 25.0 ± 10.5 ng L-1), with tris(2-chloroethyl) phosphate (TCEP) being the largest contributor. Cluster analysis results showed off-shore input from the coast of East and Southeast Asia was an important source of these chemicals. Tri-p-tolyl phosphate (TpTP) should also be considered for long-term monitoring, because of its high detection frequency. Results of a risk assessment indicated low ecological risk to species in the West Pacific Ocean for TPhP and ΣOPEs. Hazard quotients (HQs) were all <1, indicating that the health risk to humans from these chemicals was at acceptable levels.

Female-Specific Association of Plasma N-Terminal Pro-Brain Natriuretic Peptide With Organ Dysfunction and Prognosis in Sepsis: A Retrospective Study.

OBJECTIVES: The plasma level of N-terminal pro-brain natriuretic peptide is regulated by sex hormones. It has been controversial whether N-terminal pro-brain natriuretic peptide is a prognosis marker for sepsis. The aim of this study is to examine the sex-dependent association of plasma N-terminal pro-brain natriuretic peptide with organ dysfunction and mortality of sepsis patients. DESIGN: In this retrospective study, the association between plasma N-terminal pro-brain natriuretic peptide concentration on the day of sepsis diagnosis and the degree of organ dysfunction, occurrence of septic shock, or 30-day mortality in both male and female patients was analyzed. SETTING: This study was conducted in the Sepsis Laboratory at the Huaihe Hospital of Henan University in China. PATIENTS: Diagnoses of sepsis, and septic shock, were based on the recently revised criteria (Sepsis 3.0). All sepsis patients (517) hospitalized in the respiratory ICU of the Huaihe Hospital from June 2016 to December 2019 were enrolled in this study. INTERVENTIONS: None. MEASUREMENTS AND MAIN RESULTS: No significant difference was found in the age, occurrence rate of septic shock, 30-day mortality, or degree of organ dysfunction between male and female patients. Median concentration of plasma N-terminal pro-brain Natriuretic peptide was higher by 93.48% in female than male patients. A significant association was found between N-terminal pro-brain natriuretic peptide and septic shock or 30-day mortality in female, but not in male patients of community- or hospital-acquired sepsis. N-terminal pro-brain natriuretic peptide levels correlated to functional deficiencies of the cardiac and nervous systems, only in female patients. CONCLUSIONS: The plasma N-terminal pro-brain natriuretic peptide level is a female-specific prognosis indicator of septic shock and mortality.

Distribution of eight organophosphorus pesticides and their oxides in surface water of the East China Sea based on high volume solid phase extraction method.

In this study, we reported the occurrence of eight organophosphorus pesticides (OPPs) in the East China Sea. Forty samples were collected and analysed with a high volume solid phase extraction method (Hi-throat/Hi-volume SPE) in the early summer of 2020. All the target OPPs were detected in the surface water at one or more stations in the East China Sea, and the concentrations of ΣOPPs were in the range 0.0775-3.09 ng/L (mean: 0.862 ± 0.624 ng/L). Terbufos sulfone and fenthion were the main pollutants in this area, probably resulting from pesticide use in China and other countries. The off-shore input from coastal regions was suggested to be a major source of OPP pollution in the East China Sea, and the movement of ocean currents played an important role in their transportation because around 0.86 t OPPs passed through the Tsushima Strait from the East China Sea each month. An ecological risk assessment showed that these OPPs presented a high risk to species in the East China Sea, whereas they posed no health risk to humans under both the median and high exposure scenario.

Antarctic Adélie penguin feathers as bio-indicators of geographic and temporal variations in heavy metal concentrations in their habitats.

Seabird feathers are effective indicators of heavy metal contamination. To propose a biological detection method suitable for the long-term monitoring of heavy metals in the Antarctic environment, eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in Adélie penguin feathers from different body parts, years, and molting grounds in the Antarctic were investigated in this study. It is found that the concentrations of heavy metals in the feathers showed differences among the body part of origin. The levels of the eight elements in the abdomen and back feathers were approximately the same, but some elements of them were significantly higher than those in the tail feathers. The Hg and Cd concentrations in the abdomen and back feathers increased from root to tip, regardless of the sampling year or molting ground. Based on a structural analysis of the feathers, Hg and Cd were mainly distributed in the feather vane rather than the shaft. The methylmercury content accounted for 83%-97% of the total mercury content in all feather samples, regardless of location, year, or body part, thereby supporting the assumption that mercury entering the feather was predominantly methylated and indicating that a relatively toxic form of Hg is excreted through the feathers. The heavy metals in feathers from the same molting ground showed significant differences over the sampling years. The average concentrations of As, Cr, Cu, Ni, and Zn increased significantly from 2015 to 2019, whereas those of Cd, Hg, and Pb tended to decrease. The concentrations of the eight elements in Adélie feathers from three molting grounds varied greatly, possibly in relation to their living areas and dietary structures. Feathers from the Ross Sea site had the highest Cd, Cu, Hg, Ni, and Zn concentrations, the highest As and Cr concentrations were detected in feathers from the Zhongshan site, and feathers from the Great Wall site showed higher Pb concentrations than those from the other two sites. This study established a long-term, nondestructive, and efficient method for monitoring heavy metal contamination in the polar environment in the future.

Occurrence and risk assessment of emerging contaminants in a water reclamation and ecological reuse project.

Water reclamation and ecological reuse is gradually becoming a popular solution to address the high pollutant loads and insufficient ecological flow of many urban rivers. However, emerging contaminants in water reuse system and associated human health and ecological risks need to be assessed. This study determined the occurrence and human health and ecological risk assessments of 35 emerging contaminants during one year, including 5 types of persistent organic pollutants (POPs), 5 pharmaceutical and personal care products (PPCPs), 7 endocrine disrupting chemicals (EDCs) and 18 disinfection by-products (DBPs), in a wastewater treatment plant (WWTP) and receiving rivers, as well as an unimpacted river for comparison. Results showed that most of PPCPs and EDCs, especially antibiotics, triclosan, estrogens and bisphenol A, occurred frequently at relatively high concentrations, and they were removed from 20.5% to 88.7% with a mean of 58.9% via WWTP. The highest potential noncarcinogenic and carcinogenic risks in different reuse scenarios were assessed using maximal detected concentrations, all below the acceptable risk limits, with the highest total combined risk value of 9.21 × 10-9 and 9.98 × 10-7, respectively. Ecological risk assessment was conducted using risk quotient (RQ) method and indicated that several PPCPs, EDCs and haloacetonitriles (HANs) pose high risk (RQ > 1) to aquatic ecology in the rivers, with the highest RQ up to 83.8. The study suggested that ecological risks need to be urgently addressed by updating and optimizing the process in WWTPs to strengthen the removal efficiencies of emerging contaminants. The study can serve as a reference for safer water reuse in the future, while further studies could be conducted on the health risk of specific groups of people, exposure parameters in water reuse, as well as more emerging contaminants.

Distribution, sources and transport of organophosphorus flame retardants in the water and sediment of Ny-Ålesund, Svalbard, the Arctic.

Organophosphorus flame retardants (PFRs) are contaminants of emerging concern which have been detected globally. However, little information on PFRs in the Arctic freshwater environment is currently available. In this study, both hydrophilic and hydrophobic PFRs in the water and sediment of four areas (town, surroundings, coastal marine water, and glacier melt runoff) near Ny-Ålesund Svalbard were investigated by time-integrated passive sampling (water) and grab sampling (sediment). Seven kinds of PFRs were found in the Arctic waters with individual freely dissolved concentrations from 0.007 ng L-1 to 355 ng L-1, and the concentrations of chlorinated PFRs were 3-4 orders of magnitude higher than those of non-chlorinated PFRs. The distribution of different PFRs in freshwater showed significant spatial differences among the different areas, and the town was found to have most kinds of PFRs and highest PFRs concentrations. The sources and transport of different kinds of PFRs were explored based on a spatial overlay analysis of the contaminant distributions, environmental conditions, and PFR applications. As a result, human settlements, industrial activities, atmospheric deposition, and transportation in Ny-Ålesund were proposed to be related to the pollution of different PFRs at Ny-Ålesund. The PFRs in the inshore marine water were found to be affected by both local ship contamination and ocean current transport. Furthermore, nine PFRs were detected in the sediments of Ny-Ålesund. Accumulation of different PFRs in the Arctic sediment was found to be dominated by their physico-chemical properties (polarity).

A multi-criteria evaluation system for arable land resource assessment.

This study proposed a multi-criteria evaluation system for arable land resources by combining the soil integrated fertility index (IFI) with a soil cleanliness index (based on heavy metals and metalloid content). A total of 16 typical arable land units in Chongming District, China, were evaluated using the proposed evaluation system based on 104 collected soil samples in 16 towns. The comprehensive soil evaluation scores of arable lands in 16 towns were in the range of 90.7 to 99.2 with a mean of 96.2, indicating that the arable land in all 16 towns was at the level of excellent (≥ 90.0). Lower cleanliness indices had a significant impact on the final evaluation score. In comparison with single-index evaluation systems (i.e., the IFI or soil cleanliness index), the proposed multi-criteria system better reflects the quality of the soil. In the practice of arable land requisition and subsidy policy, the proposed multi-criteria evaluation system not only encourages farmers to preserve arable lands during farming but also helps agricultural authorities make effective and reliable management decisions.

Characterizing spatial distribution of chlorophyll a in the Southern Ocean on a circumpolar cruise in summer.

The spatial variation of chlorophyll a in the Southern Ocean (SO) was of great significance. Sea surface chlorophyll a concentrations was measured by Ferry Box monitoring system on the Chinese polar research vessel Xue Long, which circumnavigated the Antarctic continent in a clockwise direction during the austral summer 2013-2014 (November 2013-April 2014). The concentrations of chlorophyll a indicated a relatively uniform distribution of 0.049-11.647 mg m-3 (mean 0. 869 mg m-3, n = 152,751). The highest chlorophyll a concentrations (mean 1.847 mg m-3) was found in the Ross sea (RS). In addition, six high-chlorophyll a hot spots were recognized. Analysis revealed that phytoplankton bloom could be controlled by multiple factors in different regions, and the chlorophyll a bloom is attributed to the combined effect of surface and subsurface processes such as, continental shelf, sea ice melting, Circumpolar Deep Water (CDW) upwelling, suitabletemperature, and nutrient injection from subsurface to the surface. The topographic effects, sea ice melting and CDW upwelling may play a major role in controlling primary productivity in the SO. Among of all, CDW upwelling may be the most important role improving primary productivity. This study presented the phytoplankton distribution patterns and the relation with potential growth-controlling factors in the SO, which will provide more insight in the mechanisms that control global warming to reduce global CO2 the atmosphere into the ocean interior.

Organophosphorus flame retardants and persistent, bioaccumulative, and toxic contaminants in Arctic seawaters: On-board passive sampling coupled with target and non-target analysis.

Organic pollutants in the Arctic seas have been of concern to many researchers; however, the vast dynamic marine water poses challenges to their comprehensive monitoring within appropriate spatial and temporal scales in the Arctic. In this study, on-board passive sampling of organic pollutants using a self-developed device coupled with triolein-embedded cellulose acetate membranes (TECAMs) was performed during an Arctic cruise. The TECAM extracts were used for target analysis of organophosphorus flame retardants (PFRs), and non-target screening of persistent, bioaccumulative, and toxic (PBT) contaminants using two-dimensional gas chromatography with time-of-flight mass spectrometry (GC × GC-TOFMS). Sixteen chemicals were screened out as PBT contaminants from the 1500 features in the non-target analysis and further identified. Consequently, two chlorinated PFRs (tris(chloroisopropyl)phosphate and tris(1,3-dichloroisopropyl)phosphate) and four PBT contaminants (4-tert-butylphenol, 2-isopropylnaphthalene, 1,1,3-trimethyl-3-phenylindane, and 1-phenylnonan-1-one) were accurately quantified, with the temporally and spatially integrated concentrations ranging from 0.83 ng L-1 to 20.82 ng L-1 in the seawaters. Sources and transport of the contaminants were studied, and ocean current transport (West Spitsbergen Current, WSC) and local sources (human settlement, Arctic oil exploitation, and petroleum fuel emissions) were found to contribute to the presence of the different contaminants. Finally, annual transport fluxes of the contaminants from the North Atlantic to the Arctic Ocean by WSC were estimated, and the results indicate that their hazard to the Arctic should be concerned.

Correction to: Risk exposure assessment of per- and polyfluoroalkyl substances (PFASs) in drinking water and atmosphere in central eastern China.

The original publication of this paper contains a mistake.

Risk exposure assessment of per- and polyfluoroalkyl substances (PFASs) in drinking water and atmosphere in central eastern China.

We examined per- and polyfluoroalkyl substances (PFASs) in air from eight cities, and in water from six drinking-water treatment plants (DWTPs), in central eastern China. We analyzed raw and treated water samples from the DWTPs for 17 ionic PFASs with high-performance liquid chromatography/negative-electrospray-ionization tandem mass spectrometry (HPLC/(-)ESI-MS/MS), and analyzed the gas and particle phases of atmospheric samples for 12 neutral PFASs by gas chromatography-mass spectrometry (GC-MS). Perfluorooctanoic acid (PFOA) and perfluorohexanoic acid (PFHxA) were the dominant compounds in drinking water, and fluorotelomer alcohols (FTOHs) dominated in atmospheric samples. Of all the compounds in the treated water samples, the concentration of PFOA, at 51.0 ng L-1, was the highest. Conventional treatments such as coagulation (COA), flocculation (FOC), sedimentation (SED), and sand filtration (SAF) did not remove PFASs. Advanced treatments, however, including ultrafiltration (UF) and activated carbon (AC), removed the majority of PFASs except for shorter-chain PFASs such as perfluorobutanoic acid (PFBA) and perfluoropentanoic acid (PFPA). We also investigated human exposure to PFASs via drinking water and the atmosphere and found that the mean daily intake of PFASs was 0.43 ng kg-1 day-1.