Multi-molecular 14C evidence for mineral control on terrestrial carbon storage and export.

Compound- and compound class-specific radiocarbon analysis of source-diagnostic 'biomarker' molecules has emerged as a powerful tool to gain insights into terrestrial carbon cycling. While most studies thus far have focused on higher plant biomarkers (i.e. plant leaf-wax n-alkanoic acids and n-alkanes, lignin-derived phenols), tracing paedogenic carbon is crucial given the pivotal role of soils in modulating ecosystem carbon turnover and organic carbon (OC) export. Here, we determine the radiocarbon (14C) ages of glycerol dialkyl glycerol tetraethers (GDGTs) in riverine sediments and compare them to those of higher plant biomarkers as well as markers of pyrogenic (fire-derived) carbon (benzene polycarboxylic acids, BPCAs) to assess their potential as tracers of soil turnover and export. GDGT Δ14C follows similar relationships with basin properties as vegetation-derived lignin phenols and leaf-wax n-alkanoic acids, suggesting that the radiocarbon ages of these compounds are significantly impacted by intermittent soil storage. Systematic radiocarbon age offsets are observable between the studied biomarkers, which are likely caused by different mobilization pathways and/or stabilization by mineral association. This article is part of the Theo Murphy meeting issue 'Radiocarbon in the Anthropocene'.

Cosmogenic in situ 14C-10Be reveals abrupt Late Holocene soil loss in the Andean Altiplano.

Soil sustainability is reflected in a long-term balance between soil production and erosion for a given climate and geology. Here we evaluate soil sustainability in the Andean Altiplano where accelerated erosion has been linked to wetter climate from 4.5 ka and the rise of Neolithic agropastoralism in the millennium that followed. We measure in situ cosmogenic 14C directly on cultivated hilltops to quantify late Holocene soil loss, which we compare with background soil production rates determined from cosmogenic 26Al and 10Be. Our Monte Carlo-based inversion method identifies two scenarios to account for our data: an increase in erosion rate by 1-2 orders of magnitude between ~2.6 and 1.1 ka, or a discrete event stripping ~1-2 m of soil between ~1.9 and 1.1 ka. Coupled environmental and cultural factors in the Late Holocene signaled the onset of the pervasive human imprint in the Andean Altiplano seen today.

Climate control on terrestrial biospheric carbon turnover.

Terrestrial vegetation and soils hold three times more carbon than the atmosphere. Much debate concerns how anthropogenic activity will perturb these surface reservoirs, potentially exacerbating ongoing changes to the climate system. Uncertainties specifically persist in extrapolating point-source observations to ecosystem-scale budgets and fluxes, which require consideration of vertical and lateral processes on multiple temporal and spatial scales. To explore controls on organic carbon (OC) turnover at the river basin scale, we present radiocarbon (14C) ages on two groups of molecular tracers of plant-derived carbon-leaf-wax lipids and lignin phenols-from a globally distributed suite of rivers. We find significant negative relationships between the 14C age of these biomarkers and mean annual temperature and precipitation. Moreover, riverine biospheric-carbon ages scale proportionally with basin-wide soil carbon turnover times and soil 14C ages, implicating OC cycling within soils as a primary control on exported biomarker ages and revealing a broad distribution of soil OC reactivities. The ubiquitous occurrence of a long-lived soil OC pool suggests soil OC is globally vulnerable to perturbations by future temperature and precipitation increase. Scaling of riverine biospheric-carbon ages with soil OC turnover shows the former can constrain the sensitivity of carbon dynamics to environmental controls on broad spatial scales. Extracting this information from fluvially dominated sedimentary sequences may inform past variations in soil OC turnover in response to anthropogenic and/or climate perturbations. In turn, monitoring riverine OC composition may help detect future climate-change-induced perturbations of soil OC turnover and stocks.

Two MATLAB programs for computing paleo-elevations and burial ages from paired-cosmogenic nuclides.

Methods based on cosmic-ray produced nuclides are key to improve our understanding of the Earth surface dynamic. Measuring multiple cosmogenic nuclides in the same rock sample has a great potential, but data interpretation requires rigorous and often complex mathematical treatments. In order to make progress on this topic, this paper presents two easy-to-use MATLAB© programs permitting to derive information from pairs of cosmogenic nuclides (26Al-10Be or 10Be-21Ne) measured in rock samples that have been exposed to cosmic rays in the past: "Paleoaltitude.m" and "Burial.m". •"Paleoaltitude.m" computes paleoelevations from a sample whose burial age is known. This new paleoaltimetry method is presented in detail in Blard et al. [1]. The present article also develops the mathematical approach.•Since the elevation of exposure may affect the accuracy of a burial age [1], the second MATLAB© script "Burial.m" is designed to compute burial ages from 26Al-10Be or 10Be-21Ne pairs, taking into account the position of a sample (elevation and latitude) during its preburial exposure history.

Lake Tauca highstand (Heinrich Stadial 1a) driven by a southward shift of the Bolivian High.

Heinrich events are characterized by worldwide climate modifications. Over the Altiplano endorheic basin (high tropical Andes), the second half of Heinrich Stadial 1 (HS1a) was coeval with the highstand of the giant paleolake Tauca. However, the atmospheric mechanisms underlying this wet event are still unknown at the regional to global scale. We use cosmic-ray exposure ages of glacial landforms to reconstruct the spatial variability in the equilibrium line altitude of the HS1a Altiplano glaciers. By combining glacier and lake modeling, we reconstruct a precipitation map for the HS1a period. Our results show that paleoprecipitation mainly increased along the Eastern Cordillera, whereas the southwestern region of the basin remained relatively dry. This pattern indicates a southward expansion of the easterlies, which is interpreted as being a consequence of a southward shift of the Bolivian High. The results provide a new understanding of atmospheric teleconnections during HS1 and of rainfall redistribution in a changing climate.