1.
Adv Exp Med Biol
; 611: 449-50, 2009.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19400261
2.
Chemistry
; 15(1): 67-70, 2009.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19016563
Assuntos
Metionina/química , Peptídeos/química , Fenilalanina/análogos & derivados , Benzofenonas/química , Benzofenonas/efeitos da radiação , Ciclização , Conformação Molecular , Peptídeos/síntese química , Fenilalanina/química , Espectroscopia de Infravermelho com Transformada de Fourier , Estereoisomerismo , Difração de Raios X
3.
Acc Chem Res
; 35(5): 297-304, 2002 May.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12020167
RESUMO
The photochemical nucleophile-olefin combination, aromatic substitution (photo-NOCAS) reaction has been a cornerstone of research in our laboratory for several years. In this Account we present an overview of the mechanistic exploration and rationalization of this photoinduced electron transfer reaction. We have investigated the mechanism and defined the synthetic scope and limitations by variations in reaction conditions and structural modification of the substrates. During our studies, we have come across several other pathways in competition with the photo-NOCAS reaction that dominate once specific conditions are altered. These alternative reactions are also discussed briefly.