Nanotechnological approaches as a promising way for heavy metal mitigation in an aqueous system.

The ever-rising environmental problems because of heavy metals emerging from anthropogenic activities pose an impending threat to all biota globally. Considering their persistence and possibility in biomagnification, they are prominent among pollutants. There has been an apparent shift of research interest in advancing cost-effective and competent technologies to mitigate environmental contaminants, specifically heavy metals. In the recent two decades, tailored nanomaterials (NMs), nanoparticles, and NM-based adsorbents have been emerging for removing heavy metal pollution on a sustainable scale, especially the green synthesis of these nanoproducts effective and nonhazardous means. Hence, this review explores the various avenues in nanotechnology, an attempt to gauge nanotechnological approaches to mitigate heavy metals in the aqueous system, especially emphasizing the recent trends and advancements. Inputs on remediating heavy metal in sustainable and environmentally benign aspects recommended future directions to compensate for the voids in this domain have been addressed.

Emerging role of microalgae in heavy metal bioremediation.

Microalgae have been publicized for their diversified dominance responsiveness and bioaccumulation potential toward pollutants in an ecosystem. Also, algal's incredible capability as biocatalysts in environmental appliances has been well elucidated owing to their robustness and simple nutritional demand. Additionally, microalgae can deliver various collections of bio-based chemical compounds helpful for diversified applications, especially as green alternatives. The environment has been contaminated with various polluting agents; one principal polluting agent is heavy metals which are carcinogenic and show toxicity even in minimal quantity, cause unsatisfactory threats to the environmental ecosystem, including human and animal health. There is a prominent tendency to apply microalgae in the phytoremediation of heavy metals compounds because of its vast benefits, including great accessibility, cost-effective, excellent toxic metal eliminating efficiency, and nontoxic to the ecosystem. This review uncovers the most recent advancements and mechanisms associated with the bioremediation process and biosorption interaction of substantial harmful synthetic compounds processing microalgae species. Furthermore, future challenges and prospects in the utilization of microalgae in heavy metals bioremediation are also explored. The current review aims to give valuable information to aid the advancement of robust and proficient future microalgae-based heavy metal bioremediation innovations and summarizing a wide range of benefits socioeconomic scope to be employed in heavy metal compound removal in environment system.

Improved Long-Term Reliability of a Silica-Encapsulated Perovskite Quantum-Dot Light-Emitting Device with an Optically Pumped Remote Film Package.

In this study, inorganic perovskite (CsPbBr3) quantum dots are wrapped in SiO2 to provide better performance against external erosion. Long-term storage (250 days) is demonstrated with very little changes in the illumination capability of these quantum dots. While in the continuous aging procedure, different package architectures can achieve very different lifetimes. As long as 6000 h of lifetime can be expected from these quantum dots, but the blue shift of emission wavelength still needs more investigation.

High-Performance Rechargeable Aluminum-Selenium Battery with a New Deep Eutectic Solvent Electrolyte: Thiourea-AlCl3.

Aluminum-sulfur batteries (ASBs) have attracted substantial interest due to their high theoretical specific energy density, low cost, and environmental friendliness, while the traditional sulfur cathode and ionic liquid have very fast capacity decay, limiting cycling performance because of the sluggishly electrochemical reaction and side reactions with the electrolyte. Herein, we demonstrate, for the first time, excellent rechargeable aluminum-selenium batteries (ASeBs) using a new deep eutectic solvent, thiourea-AlCl3, as an electrolyte and Se nanowires grown directly on a flexible carbon cloth substrate (Se NWs@CC) by a low-temperature selenization process as a cathode. Selenium (Se) is a chemical analogue of sulfur with higher electronic conductivity and lower ionization potential that can improve the battery kinetics on the sluggishly electrochemical reaction and the reduction of the polarization where the thiourea-AlCl3 electrolyte can stabilize the side reaction during the reversible conversion reaction of Al-Se alloying processes during the charge-discharge process, yielding a high specific capacity of 260 mAh g-1 at 50 mA g-1 and a long cycling life of 100 times with a high Coulombic efficiency of nearly 93% at 100 mA g-1. The working mechanism based on the reversible conversion reaction of the Al-Se alloying processes, confirmed by the ex situ Raman, XRD, and XPS measurements, was proposed. This work provides new insights into the development of rechargeable aluminum-chalcogenide (S, Se, and Te) batteries.

Hybridizing Plasmonic Materials with 2D-Transition Metal Dichalcogenides toward Functional Applications.

Recently, 2D transition metal dichalcogenides (TMDs) have become intriguing materials in the versatile field of photonics and optoelectronics because of their strong light-matter interaction that stems from the atomic layer thickness, broadband optical response, controllable optoelectronic properties, and high nonlinearity, as well as compatibility. Nevertheless, the low optical cross-section of 2D-TMDs inhibits the light-matter interaction, resulting in lower quantum yield. Therefore, hybridizing the 2D-TMDs with plasmonic nanomaterials has become one of the promising strategies to boost the optical absorption of thin 2D-TMDs. The appeal of plasmonics is based on their capability to localize and enhance the electromagnetic field and increase the optical path length of light by scattering and injecting hot electrons to TMDs. In this regard, recent achievements with respect to hybridization of the plasmonic effect in 2D-TMDs systems and its augmented optical and optoelectronic properties are reviewed. The phenomenon of plasmon-enhanced interaction in 2D-TMDs is briefly described and state-of-the-art hybrid device applications are comprehensively discussed. Finally, an outlook on future applications of these hybrid devices is provided.

Deep Eutectic Solvent-Assisted Synthesis of Ternary Heterojunctions for the Oxygen Evolution Reaction and Photocatalysis.

Hierarchical nano-/microstructured photocatalysts have drawn attention for enhanced photocatalytic performance. Deep eutectic solvents (DESs) have been used as a green sustainable media to act as both solvent and structure-inducing agent in the synthesis of hierarchical nanomaterials. In this work, the DESs-assisted synthesis of flower-structured BiOCl/BiVO4 (BOC/BVO) with g-C3 N4 (BOC/BVO/g-CN) ternary heterojunctions was achieved by using a simple wet-chemical method, providing good acidic and alkaline oxygen evolution reaction (OER) catalysts. BOC/BVO/g-CN-15 achieved an enhanced photocatalytic activity for OER with an overpotential of 570 mV in 1 m H2 SO4 and 220 mV in 1 m KOH electrolyte at a current density of 10 mA cm-2 with excellent stability and extraordinary durability of the catalyst. The ternary heterojunctions displayed extended lifetimes for photogenerated charges and enhanced the separation efficiency of photogenerated electron-hole pairs, which is helpful to enhance the photocatalytic OER. Furthermore, the photocatalytic performance of the ternary heterojunctions in aqueous solution was demonstrated through photocatalytic dye degradation of methyl orange (MO) as a model pollutant, resulting in 95 % degradation of 20 ppm of MO in 210 min under the irradiation of a 35 W Xe arc lamp. This work not only provides new insight into the design of catalysts by using green solvents but also into the design of highly efficient metal-free OER photocatalysts for applications in acidic and alkaline media.

Ultra-fast photodetectors based on high-mobility indium gallium antimonide nanowires.

Because of tunable bandgap and high carrier mobility, ternary III-V nanowires (NWs) have demonstrated enormous potential for advanced applications. However, the synthesis of large-scale and highly-crystalline InxGa1-xSb NWs is still a challenge. Here, we achieve high-density and crystalline stoichiometric InxGa1-xSb (0.09 < x < 0.28) NWs on amorphous substrates with the uniform phase-purity and <110 >-orientation via chemical vapor deposition. The as-prepared NWs show excellent electrical and optoelectronic characteristics, including the high hole mobility (i.e. 463 cm2 V-1 s-1 for In0.09Ga0.91Sb NWs) as well as broadband and ultrafast photoresponse over the visible and infrared optical communication region (1550 nm). Specifically, the In0.28Ga0.72Sb NW device yields efficient rise and decay times down to 38 and 53 µs, respectively, along with the responsivity of 6000 A W-1 and external quantum efficiency of 4.8 × 106 % towards 1550 nm regime. High-performance NW parallel-arrayed devices can also be fabricated to illustrate their large-scale device integrability for next-generation, ultrafast, high-responsivity and broadband photodetectors.

Selection Role of Metal Oxides into Transition Metal Dichalcogenide Monolayers by a Direct Selenization Process.

Direct reduction of metal oxides into a few transition metal dichalcogenide (TMDCs) monolayers has been recently explored as an alternative method for large area and uniform deposition. However, not many studies have addressed the characteristics and requirement of the metal oxides into TMDCs by the selenization/sulfurization processes, yielding a wide range of outstanding properties to poor electrical characteristics with nonuniform films. The large difference implies that the process is yet not fully understood. In particular, the selenization/sulfurization at low temperature leads to poor crystallinity films with poor electrical performance, hindering its practical development. A common approach to improve the quality of the selenized/sulfurized films is by further increasing the process temperature, thus requiring additional transfer in order to explore the electrical properties. Here, we show that by finely tuning the quality of the predeposited oxide the selenization/sulfurization temperature can be largely decreased, avoiding major substrate damage and allowing direct device fabrication. The direct relationship between the role of selecting different metal oxides prepared by e-beam evaporation and reactive sputtering and their oxygen deficiency/vacancy leading to quality influence of TMDCs was investigated in detail. Because of its outstanding physical properties, the formation of tungsten diselenide (WSe2) from the reduction of tungsten oxide (WO x) was chosen as a model for proof of concept. By optimizing the process parameters and the selection of metal oxides, layered WSe2 films with controlled atomic thickness can be demonstrated. Interestingly, the domain size and electrical properties of the layered WSe2 films are highly affected by the quality of the metal oxides, for which the layered WSe2 film with small domains exhibits a metallic behavior and the layered WSe2 films with larger domains provides clear semiconducting behavior. Finally, an 8'' wafer scale-layered WSe2 film was demonstrated, giving a step forward in the development of 2D TMDC electronics in the industry.

Perovskite Quantum Dots with Near Unity Solution and Neat-Film Photoluminescent Quantum Yield by Novel Spray Synthesis.

In this study, a novel perovskite quantum dot (QD) spray-synthesis method is developed by combining traditional perovskite QD synthesis with the technique of spray pyrolysis. By utilizing this new technique, the synthesis of cubic-shaped perovskite QDs with a homogeneous size of 14 nm is demonstrated, which shows an unprecedented stable absolute photoluminescence quantum yield ≈100% in the solution and even in the solid-state neat film. The highly emissive thin films are integrated with light emission devices (LEDs) and organic light emission displays (OLEDs). The color conversion type QD-LED (ccQD-LED) hybrid devices exhibit an extremely saturated green emission, excellent external quantum efficiency of 28.1%, power efficiency of 121 lm W-1 , and extraordinary forward-direction luminescence of 8 500 000 cd m-2 . The conceptual ccQD-OLED hybrid display also successfully demonstrates high-definition still images and moving pictures with a 119% National Television System Committee 1931 color gamut and 123% Digital Cinema Initiatives-P3 color gamut. These very-stable, ultra-bright perovskite QDs have the properties necessary for a variety of useful applications in optoelectronics.

Thermally Strained Band Gap Engineering of Transition-Metal Dichalcogenide Bilayers with Enhanced Light-Matter Interaction toward Excellent Photodetectors.

Integration of strain engineering of two-dimensional (2D) materials in order to enhance device performance is still a challenge. Here, we successfully demonstrated the thermally strained band gap engineering of transition-metal dichalcogenide bilayers by different thermal expansion coefficients between 2D materials and patterned sapphire structures, where MoS2 bilayers were chosen as the demonstrated materials. In particular, a blue shift in the band gap of the MoS2 bilayers can be tunable, displaying an extraordinary capability to drive electrons toward the electrode under the smaller driven bias, and the results were confirmed by simulation. A model to explain the thermal strain in the MoS2 bilayers during the synthesis was proposed, which enables us to precisely predict the band gap-shifted behaviors on patterned sapphire structures with different angles. Furthermore, photodetectors with enhancement of 286% and 897% based on the strained MoS2 on cone- and pyramid-patterned sapphire substrates were demonstrated, respectively.

Lead-Free Perovskite Nanowire Array Photodetectors with Drastically Improved Stability in Nanoengineering Templates.

Organometal halide perovskite materials have triggered enormous attention for a wide range of high-performance optoelectronic devices. However, their stability and toxicity are major bottleneck challenges for practical applications. Substituting toxic heavy metal, that is, lead (Pb), with other environmentally benign elements, for example, tin (Sn), could be a potential solution to address the toxicity issue. Nevertheless, even worse stability of Sn-based perovskite material than Pb-based perovskite poses a great challenge for further device fabrication. In this work, for the first time, three-dimensional CH3NH3SnI3 perovskite nanowire arrays were fabricated in nanoengineering templates, which can address nanowire integration and stability issues at the same time. Also, nanowire photodetectors have been fabricated and characterized. Intriguingly, it was discovered that as the nanowires are embedded in mechanically and chemically robust templates, the material decay process has been dramatically slowed down by up to 840 times, as compared with a planar thin film. This significant improvement on stability can be attributed to the effective blockage of diffusion of water and oxygen molecules within the templates. These results clearly demonstrate a new and alternative strategy to address the stability issue of perovskite materials, which is the major roadblock for high-performance optoelectronics.

Wafer Scale Phase-Engineered 1T- and 2H-MoSe2 /Mo Core-Shell 3D-Hierarchical Nanostructures toward Efficient Electrocatalytic Hydrogen Evolution Reaction.

The necessity for new sources for greener and cleaner energy production to replace the existing ones has been increasingly growing in recent years. Of those new sources, the hydrogen evolution reaction has a large potential. In this work, for the first time, MoSe2 /Mo core-shell 3D-hierarchical nanostructures are created, which are derived from the Mo 3D-hierarchical nanostructures through a low-temperature plasma-assisted selenization process with controlled shapes grown by a glancing angle deposition system.

Honeycomb-like Porous Carbon-Cobalt Oxide Nanocomposite for High-Performance Enzymeless Glucose Sensor and Supercapacitor Applications.

Herein, we report the preparation of Pongam seed shells-derived activated carbon and cobalt oxide (∼2-10 nm) nanocomposite (PSAC/Co3O4) by using a general and facile synthesis strategy. The as-synthesized PSAC/Co3O4 samples were characterized by a variety of physicochemical techniques. The PSAC/Co3O4-modified electrode is employed in two different applications such as high performance nonenzymatic glucose sensor and supercapacitor. Remarkably, the fabricated glucose sensor is exhibited an ultrahigh sensitivity of 34.2 mA mM(-1) cm(-2) with a very low detection limit (21 nM) and long-term durability. The PSAC/Co3O4 modified stainless steel electrode possesses an appreciable specific capacitance and remarkable long-term cycling stability. The obtained results suggest the as-synthesized PSAC/Co3O4 is more suitable for the nonenzymatic glucose sensor and supercapacitor applications outperforming the related carbon based modified electrodes, rendering practical industrial applications.