Wastewater in the food industry: Treatment technologies and reuse potential.

Water is the most extensively used raw material in the food and beverage industry. This industrial sector has a negative impact on the environment and economy as a result of rising water demand and wastewater production. With the increasing scarcity of drinking water, the reuse of wastewater streams has become an important economic and ecological concern. Therefore, the optimisation of water consumption and wastewater reuse in the food industry is essential. On the other hand, several countries limit the reuse of wastewater because of legal curtailment, public health and safety concerns. This represents a major challenge for both industries and administrations due to the technical complexity and financial costs involved. The present review aims at addressing the key issues related to water consumption, wastewater generation, treatment and successful implementation cases of water reuse in the food and beverage industry. Moreover, the various case studies of already employed technologies for the food industry wastewater treatment and reuse have been analysed for their performance. Also, this review reveals future research on the application of other innovative technologies such as ultraviolet irradiation and micro electrolysis. However, the successful implementation of reuse strategies is associated with the holistic evaluation of local factors such as governmental incentives, social acceptance and legislation harmonisation related to the cost, risks, and environmental performance.

Removal of Cu(II), Pb(II) and Cr(VI) ions from aqueous solution using amidoximated non-woven polyethylene-g-acrylonitrile fabric.

Pre-irradiation method was applied to graft acrylonitrile (AN) onto non-woven polyethylene film. Graft yield reached 130% at 70 kGy radiation dose, 60% monomer concentration and 4 h reaction time when H2SO4 was used as an additive. The modification of AN grafted films with hydroxyl amine hydrochloride was done for the preparation of amidoxime adsorbent. The constructed adsorbent was characterized using FTIR, DMA and SEM. The amidoxime adsorbent was used for adsorption of Cu(II), Pb(II) and Cr(VI). Adsorption capacity was investigated under different conditions: contact time, pH and initial metal ion concentration. The optimum condition for maximum adsorption was found to be contact time 72 h and initial metal concentration 500 ppm for all the metal ions studied and pH 5.2 for Cu(II), 5.4 for Pb(II), 1.5 for Cr(VI). Kinetic adsorption data was elucidated using pseudo-first-order and pseudo-second-order equations. The equilibrium experimental data of metal adsorption matched Langmuir isotherm model. From the Langmuir equation, the monolayer saturation adsorption capacity (highest adsorption capacity) of the adsorbent was found to be 74.62 mg/g for Cu(II), 107 mg/g for Pb(II) and 156.25 mg/g for Cr(VI). The thermodynamics of metal adsorption was also investigated. Furthermore, desorption and reuse of the adsorbent film was studied. The results suggest that the adsorbent can be effective for adsorption of Cu(II), Pb(II) and Cr(VI).