Competitive algae biodiesel depends on advances in mass algae cultivation.

The aim of this review was to study why, despite large investments in research and development, algae biodiesel is still not price competitive with fossil fuels. Microalgal production was confirmed to be a critical cost item (84 up to 93 %) for biodiesel regardless of the production technology. Techno-economic assessment revealed the main cost drivers during mass cultivation. It is argued that a breakthrough in the cultivation efficiency of microalgae is identified as a necessary condition for achieving price-competitive microalgal biodiesel. The key bottlenecks were identified as follows: (1) light and O2 concentration management; (2) overnight respiratory loss of oil. It is concluded that most of the research on microalgae biodiesel yields economically over-optimistic presumptions because it has been based on laboratory scale experiments with a low level of interdisciplinary overlap.

Silica Nanoparticles from Coir Pith Synthesized by Acidic Sol-Gel Method Improve Germination Economics.

Lignin is a natural biopolymer. A vibrant and rapid process in the synthesis of silica nanoparticles by consuming the lignin as a soft template was carefully studied. The extracted biopolymer from coir pith was employed as capping and stabilizing agents to fabricate the silica nanoparticles (nSi). The synthesized silica nanoparticles (nSi) were characterized by ultraviolet-visible (UV-Vis) spectrophotometry, X-ray diffraction analysis (XRD), Scanning Electron Microscope (SEM), Energy-Dispersive X-ray Analysis (EDAX), Dynamic Light Scattering (DLS) and Fourier-Transform Infrared Spectroscopy (FTIR). All the results obtained jointly and independently verified the formation of silica nanoparticles. In addition, EDAX analysis confirmed the high purity of the nSi composed only of Si and O, with no other impurities. XRD spectroscopy showed the characteristic diffraction peaks for nSi and confirmed the formation of an amorphous nature. The average size of nSi obtained is 18 nm. The surface charge and stability of nSi were analyzed by using the dynamic light scattering (DLS) and thus revealed that the nSi samples have a negative charge (-20.3 mV). In addition, the seed germination and the shoot and root formation on Vigna unguiculata were investigated by using the nSi. The results revealed that the application of nSi enhanced the germination in V. unguiculata. However, further research studies must be performed in order to determine the toxic effect of biogenic nSi before mass production and use of agricultural applications.

Techno-economic analysis reveals the untapped potential of wood biochar.

The United Nations estimates the rate of deforestation over 10 million hectares per year, with additional infested wood available due to drought, bark beetle calamity and other damage vectors. Processing the hard-to-reach infested wood into biochar via mobile pyrolysis units seems to be a good option for fire prevention. However, since most biochar is currently produced mainly from biological waste, there is not enough experience with wood biochar on a large scale. Review of current knowledge, followed by techno-economic assessment reveals that following the chemical composition of the feedstock, wood biochar outperforms other types of biochar in terms of high porosity. Therefore, wood biochar shows excellent results in increasing the amount of plant-available water content in soil and appears to be an excellent tool for recycling nutrients (especially into plant-available forms of phosphorus and nitrogen). The overall positive effects of biochar application change from abiotic to biotic over time because as it decays, many of its physical properties disappear, but it can boost soil microbial communities on which soil fertility depends. As global climate change creates a wide range of factors that damage forest cover, wood biochar consequently represents untapped potential in the field of soil, nutrient, and energy management.

Recovering phosphorous from biogas fermentation residues indicates promising economic results.

The economics of producing energy-valuable gases by fermenting phytomass is deteriorated by the costs associated with waste management of highly diluted (typically 95% water) fermentation residues (FR). Previously, no better solution was known than to plough FR into the arable land and claim that it is an irrigation with soil improving and fertilizing effect. However, farmers soon realized that FR organic matter is of little agronomic value and nutrients are at agronomically insignificant levels. As FR watering has proved economically irrational in many countries the practice of separating water from the FR and using the solid fraction for energy purposes (such as charcoal) has dominated. However, most nutrients are lost in this way. For the first time it is proposed to activate the charred FR via calcium chloride (whose price is insignificant as it would be used for fertilization purposes anyway) and using the resulting sorbent to capture phosphorus (P) out of the FR's liquid fraction. It is reported for the first time that the activated char is capable of capturing 37.5 ± 4.7 kg P t-1 whereas the P availability for plant nutrition outperforms FR as well as struvite. In addition, the char demonstrates the potential to improve soil characteristics and the metabolism of soil biota. The cost breakdown and subsequent market analysis indicates that the novel fertilizer shows signs of competitiveness.

Novel sorbent shows promising financial results on P recovery from sludge water.

For several decades, researchers have been struggling to obtain minimum phosphorus (P) capture costs to meet the parameters for discharging wastewater into the watercourse. Findings from ongoing practices suggest that the Modified University of Cape Town process is currently the cheapest P capture method in the USA, whereas struvite precipitation seems to be the most cost effective method in the rest of the developed world. P sorption via biochars is becoming widespread in developing countries because this technique allows for the turning of voluminous biowaste into fertilizer with soil improving properties. Nevertheless, the reliability of this technology fluctuates throughout the year according to biowaste characteristics. For the first time, it has been proposed to use broken cellulose casings, which are readily available in increasing quantities worldwide. The sorbent obtained was subsequently activated by calcium chloride (CaCl2), whose cost is irrelevant as it would be used for agronomical purposes anyway. Pilot scale experiments show that this novel sorbent is capable of capturing 31.8 kg P t-1 from sludge water that contains 52.5 mg of extractable P L-1. More importantly, it was reported that the novel sorbent captures P, mostly in calcium phosphates (CaP) forms (191.5 g CaP t-1), which are the most valuable for plant nutrition. Enough evidence was obtained to claim that the ongoing technological race to meet the P discharge standards at the lowest cost possible should also reflect the agronomic value of P to plant nutrition to increase its competitiveness.

Biochar reduces nitrate level in red beet.

Impacts of red beet consumption both on human and animal health are subject of intense research. In particular, products that are not heat-processed contain plethora of bioactive compounds that hold promise against numerous degenerative and aging-associated diseases. However, high level of nitrates (typically more than 2 g NO3- kg-1) whose health effects are perceived with reasoned objections counterbalance these benefits. Following the above, from a certain level, the increased consumption of red beet has contrary impacts, creating a limiting factor not only from the economic point of view but also in terms of beneficial compounds intake. Reduction of NO3- levels (- 35%) has been achieved by soil amendment via increased doses of biochar. The data obtained indicates that the mechanism can be explained as follows. The soil improvement reduces soil density, increases soil temperature, improves water retention, and other prerequisites for increased activity of soil microorganisms. Accelerated metabolism of soil biota turned more nitrogen from fertilizers into organic forms. Hence, less mineral nitrogen is left for red beet intake.

Polemics on Ethical Aspects in the Compost Business.

This paper focuses on compost use in overpasses and underpasses for wild animals over roads and other similar linear structures. In this context, good quality of compost may result in faster and more resistant vegetation cover during the year. Inter alia, this can be interpreted also as reduction of damage and saving lives. There are millions of tones of plant residue produced every day worldwide. These represent prospective business for manufacturers of compost additives called "accelerators". The opinions of the sale representatives' with regards to other alternatives of biowaste utilization and their own products were reviewed. The robust analyzes of several "accelerated" composts revealed that the quality was generally low. Only two accelerated composts were somewhat similar in quality to the blank sample that was produced according to the traditional procedure. Overlaps between the interests of decision makers on future soil fertility were weighed against the preferences on short-term profit. Possible causes that allowed the boom of these underperforming products and the possible consequences are also discussed. Conclusions regarding the ethical concerns on how to run businesses with products whose profitability depends on weaknesses in the legal system and customer unawareness are to follow.

Managerial preferences in relation to financial indicators regarding the mitigation of global change.

Biochar is a soil-improving substrate made from phytomass pyrolysis. In Southeast Asia, its application decreases due to the long-term growth of biochar cost and thus caused further prolongation of the payback period. In the Euro-American civilization the biochar application is already almost forgotten once it has been much earlier recognized that the crop yields can be increased much faster with higher doses of nutrients and other agrochemicals. The payback period can be expected in decades. Such a long-time investment into soil fertility raises also many ethical questions. The final decision combines issues of social responsibility, risk and other financial indicators as well as personal preferences and more. The attitudes of Western and Central European decision makers in the agriculture business segment were analyzed on the basis of electronic questionnaire survey and a subsequent interview through their local unions. According to the data, most of them did not know about the possibilities of a more environmentally friendly approach to soil enhancement based on the addition of a fertilizer in the form of biochar. Among others, the collected data also shows that the decision makers from Western Europe have a much different ethical approach to the land and financial indicators than the Central Europeans.

Economically oriented process optimization in waste management.

A brief report on the development of novel apparatus is presented. It was verified in a commercial scale that a new concept of anaerobic fermentation followed by continuous pyrolysis is technically and economically feasible to manage previously enzymatically hydrolyzed waste haylage in huge volumes. The design of the concept is thoroughly described, documented in figures, and biochemically analyzed in detail. Assessment of the concept shows that subsequent pyrolysis of the anaerobically fermented residue allows among biogas to produce also high-quality biochar. This significantly improves the overall economy. In addition, it may be assumed that this applied research is consistent with previous theoretical assumptions stating that any kind of aerobic or anaerobic fermentation increases the microporosity of the biochar obtained.

Use of pressure manifestations following the water plasma expansion for phytomass disintegration.

A prototype capable of generating underwater high-voltage discharges (3.5 kV) coupled with water plasma expansion was constructed. The level of phytomass disintegration caused by transmission of the pressure shockwaves (50-60 MPa) followed by this expansion was analyzed using gas adsorption techniques. The dynamics of the external surface area and the micropore volume on multiple pretreatment stages of maize silage and sunflower seeds was approximated with robust analytical techniques. The multiple increases on the reaction surface were manifest in up to a 15% increase in cumulative methane production, which was itself manifest in the overall acceleration of the anaerobic fermentation process. Disintegration of the sunflower seeds allowed up to 45% higher oil yields using the same operating pressure.

Commercial-scale utilization of greenhouse residues.

Development of techniques utilizing waste without any additional energy or rare catalysts is a starting point for becoming sustainable. In the present work, the complex utilization of greenhouse residues was studied on a commercial scale. Only the energy produced by the process (8%) was used to run the technology, thanks to multilevel heat recuperation and high methane yields (over 340 m(3) volatile solid t(-1) ). Manifestations of labile carbon in relation to available nitrogen, methane yields, and the formation of inhibitors were investigated in detail. The results sweep away many false beliefs about the ratios of carbon to nitrogen and highlight the role of the availability of carbon in phytomass utilization.

Prospects in straw disintegration for biogas production.

The pretreatment methods for enhancing biogas production from oat straw under study include hot maceration, steam explosion, and pressure shockwaves. The micropore area (9, 55, and 64 m(2) g(-1)) inhibitor formations (0, 15, and 0 mL L(-1)) as well as the overall methane yields (67, 179, and 255 CH4 VS t(-1)) were robustly analyzed. It was confirmed that the operating conditions of the steam explosion must be precisely tailored to the substrate. Furthermore, it was beneficial to prepend the hot maceration before the steam explosion and the pressure shockwaves. The second alternative may give increased methane yields (246 in comparison to 273 CH4 VS t(-1)); however, the application of pressure shockwaves still faces limitations for deployment on a commercial scale.

Two-fraction anaerobic fermentation of grass waste.

BACKGROUND: Waste from public green areas represents large quantities of grassy phytomass. The grass is usually utilised by composting, combustion or anaerobic fermentation. However, the classical composts are time-demanding, the quality of accelerated composts is low, combustion is under increasing criticism and conventional anaerobic fermentation requires high investment. RESULTS: A new method of two-fraction anaerobic fermentation of grass waste consisting from a hot maceration, up-flow anaerobic sludge blanket reactor, steam explosion, horizontally stirred batch anaerobic fermentors and a charcoal kiln, all run on waste heat from a co-generation unit was investigated on a commercial scale. CONCLUSION: The results shows that due to faster energy utilisation the two-fraction technology requires smaller fermentors and hence the technology is approximately one-third less costly than conventional systems, with 4 years shorter payback time. Additionally, huge amounts of charcoal are produced. However, the process control and optimisation is more demanding.

The use of underwater high-voltage discharges to improve the efficiency of Jatropha curcas L. biodiesel production.

Underwater high-voltage discharges (3.5 kV) resulting in 4.9 kJ shock waves (50-60 MPa) were studied at the laboratory scale as a Jatropha curcas L. seed disintegration method. Grinding and macerating in an excess of methanol (3.5:1) was advantageous because methanol acts both as a liquid carrier for the pressure shock waves and as a solvent that increases the efficiency of oil extraction while remaining usable for esterification. The influence of the number of shock waves and the intensity of methanol maceration on the heat values of the pressed cake are stated in detail. Soxhlet extraction demonstrated that a greater than 94% oil extraction was achieved. The increased disintegration of vacuoles rich in oil was documented by surface area analysis, mineralization kinetics analysis, and electron microscopy. The working volumes were small, and the proportion of energy inadequate compared to the yields released; however, much can be improved by upgrading the process.