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We studied the structural, chemical, and magnetic properties of Ti/Au/Co/Ni layered systems subjected to plasma oxidation. The process results in the formation of NiO at the expense of metallic Ni, as clearly evidenced by X-ray photoelectron spectroscopy, while not affecting the surface roughness and grain size of the Co/Ni bilayers. Since the decrease of the thickness of the Ni layer and the formation of NiO increase the perpendicular magnetic anisotropy, oxidation may be locally applied for magnetic patterning. Using this approach, we created 2D heterostructures characterized by different combinations of magnetic properties in areas modified by plasma oxidation and in the regions protected from oxidation. As plasma oxidation is an easy to use, low cost, and commonly utilized technique in industrial applications, it may constitute an improvement over other magnetic patterning methods.
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Recent results showed that the ferrimagnetic compensation point and other characteristic features of Tb/Co ferrimagnetic multilayers can be tailored by He+ ion bombardment. With appropriate choices of the He+ ion dose, we prepared two types of lattices composed of squares with either Tb or Co domination. The magnetization reversal of the first lattice is similar to that seen in ferromagnetic heterostructures consisting of areas with different switching fields. However, in the second lattice, the creation of domains without accompanying domain walls is possible. These domain patterns are particularly stable because they simultaneously lower the demagnetizing energy and the energy associated with the presence of domain walls (exchange and anisotropy). For both lattices, studies of magnetization reversal show that this process takes place by the propagation of the domain walls. If they are not present at the onset, the reversal starts from the nucleation of reversed domains and it is followed by domain wall propagation. The magnetization reversal process does not depend significantly on the relative sign of the effective magnetization in areas separated by domain walls.
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We show that it is possible to engineer magnetic multidomain configurations without domain walls in a prototypical rare-earth-transition-metal ferrimagnet using keV He^{+} ion bombardment. We additionally show that these patterns display a particularly stable magnetic configuration due to a deep minimum in the energy of the system caused by flux closure and a corresponding reduction of the magnetostatic energy without an increase in energy by exchange and anisotropy terms across the walls. This occurs because light-ion bombardment affects an element's relative contribution to the properties of the ferrimagnet differently. Therefore, it is possible to control the relative contribution from each magnetic subsystem. The selection of material and the use of light-ion bombardment allow us to engineer domain patterns in continuous magnetic films, which open a way to fabricate them in a much smaller scale than currently possible. Our Letter emphasizes that the right criterion to determine the presence or absence of a domain wall is whether there is a rotation of the spin for each sublattice and that changes of the direction of effective magnetization alone do not constitute an appropriate criterion.
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Reduced graphene oxide-magnetite hybrid aerogels attract great interest thanks to their potential applications, e.g., as magnetic actuators. However, the tendency of magnetite particles to migrate within the matrix and, ultimately, escape from the aerogel structure, remains a technological challenge. In this article we show that coating magnetite particles with polydopamine anchors them on graphene oxide defects, immobilizing the particles in the matrix and, at the same time, improving the aerogel structure. Polydopamine coating does not affect the magnetic properties of magnetite particles, making the fabricated materials promising for industrial applications.
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New interesting aspects of the spectroscopic properties, magnetism, and method of synthesis of gadolinium orthovanadates doped with Eu(3+) ions are discussed. Gd(1-x)Eu(x)VO4 (x = 0, 0.05, 0.2) bifunctional luminescent materials with complex magnetic properties were synthesized by a microwave-assisted hydrothermal method. Products were formed in situ without previous precipitation. The crystal structures and morphologies of the obtained nanomaterials were analyzed by X-ray diffraction and transmission and scanning electron microscopy. Crystallographic data were analyzed using Rietveld refinement. The products obtained were nanocrystalline with average grain sizes of 70-80 nm. The qualitative and quantitative elemental composition as well as mapping of the nanocrystals was proved using energy-dispersive X-ray spectroscopy. The spectroscopic properties of red-emitting nanophosphors were characterized by their excitation and emission spectra and luminescence decays. Magnetic measurements were performed by means of vibrating sample magnetometry. GdVO4 and Gd0.8Eu0.2VO4 exhibited paramagnetic behavior with a weak influence of antiferromagnetic couplings between rare-earth ions. In the substituted sample, an additional magnetic contribution connected with the population of low-lying excited states of europium was observed.
Assuntos
Európio/química , Gadolínio/química , Nanopartículas Metálicas , Vanadatos/síntese química , Fenômenos Magnéticos , Microscopia Eletrônica de Varredura , Temperatura , Difração de Raios XRESUMO
Graded anisotropy magnetic materials possess a coercive field changing laterally with position. A simple fabrication procedure to produce such an anisotropy gradient in a polycrystalline Au/Co layer system without lateral thickness variation and with perpendicular magnetic anisotropy, prototypical for a large variety of thin film systems, is shown. The procedure uses light-ion bombardment without the use of a mask. Magnetization reversal in this polycrystalline layer system takes place by unidirectional movement of a single domain wall only in regions with larger anisotropies and anisotropy gradients. In this anisotropy/anisotropy gradient regime, the domain wall is oriented perpendicular to the coercive field gradient, and it can be positioned along the gradient by an appropriate magnetic field pulse. For smaller anisotropies/anisotropy gradients, the natural anisotropy fluctuations of the polycrystalline layer system induce magnetization reversal dominated by domain nucleation. PACS: 75.30.Gw; 75.70.Cn; 75.60.Ch.