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RATIONALE: Compounds like caffeine metabolites with more than one proton acceptor site can produce a mixture of isomeric protonated ions (protomers) in electrospray ionization and atmospheric pressure chemical ionization (APCI) ion sources. Discrimination between the protomers is of interest as the charge location influences ion structure and chemical and physical properties. METHODS: Protonation of caffeine in an APCI ion source was studied using ion mobility spectrometry. The hydronium ions, H3O+(H2O)n, are the main reactant ions in the APCI ion source. Different dopant gases including NO2, NH3, and CH3NH2 were used to produce new reactant ions NO+, NH4 +, and CH3NH3 +, respectively. Density functional theory was employed to explain the experimental results and calculate the energies of the ionization reactions. RESULTS: The ion mobility spectrum of caffeine showed three peaks. In the presence of NO2 dopant and NO+ reactant ion, caffeine was ionized via charge transfer and formation of M+ ion. As NH3 and CH3NH2 are stronger bases than H2O, the reactant ions NH4 + and CH3NH3 + selectively protonated the more basic site of caffeine, that is, the imidazole nitrogen. Using these dopants, we could attribute the first ion mobility peak to M+ ion, the second peak to the protonation of caffeine at the carbonyl oxygen atom, and the third peak to the protonation of the imidazole nitrogen atom. The calculated collisional cross-sections of M+ and the protomers of caffeine confirmed the peaks' assignment. CONCLUSIONS: The criterion for the selection of an appropriate dopant is that its proton affinity (PA) should be between those of the proton acceptor sites of the molecule studied.
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Electron attachment and corresponding dissociative electron attachment (DEA) to cobalt tricarbonyl nitrosyl (Co(CO)3NO) clusters have been studied by co-expansion with Ar gas into a high vacuum. A monochromatic electron beam was utilized to generate negative ions and the resulting reaction products were identified using mass spectrometry. The ion fragments corresponding to Co(CO)3NO monomers closely resemble results from earlier gas phase experiments and studies conducted on Co(CO)3NO in He nanodroplets. However, contrary to the gas phase or He nanodroplet ion yields, a resonance structure comprising several peaks at energies above â¼4 eV was observed both in the case of molecular clusters [Co(CO)3NO]n- (with n = 1, 2, 3) and clusters comprising DEA fragments. Additionally, the ion yields of numerous other clusters such as ions without nitrosyl ([Co(CO)4]-, [Co2(CO)5]-), clusters consisting of two fragments such as ([Co2(CO)NO]-, [Co2(CO)(NO)2]-, [Co2(CO)2NO]-, [Co2(CO)2(NO)2]-, [Co3(CO)(NO)3]-, [Co3(CO)8(NO)3]-, [Co3(CO)(NO)2]-, [Co3(CO)3(NO)2]-, and [Co3(CO)5(NO)2]-) were recorded. Moreover, NîO bond dissociation was confirmed with the [Co(CO)2N]-ion and with N- or O-retaining cluster ions, such as [Co2(CO)(NO)N]-, [Co2(CO)2(NO)N]-, [Co3(CO)2(NO)N]-, [Co3(CO)3(NO)N]- and [Co3(CO)(NO)2N]-, or [Co2(CO)2O]-, [Co2(CO)3O]-, [Co3(CO)3O]-, [Co3(CO)4O]-and [Co3(CO)2(NO)O]- respectively.
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Formic acid (FA) is introduced as a potent dopant for atmospheric pressure chemical ionization (APCI) for ion mobility spectrometry (IMS) and mass spectrometry (MS). The mechanism of chemical ionization with the FA dopant was studied in the negative polarity using a corona discharge (CD)-IMS-MS technique in air. Standard reactant ions of the negative polarity present in air are O2-·(CO2)n·(H2O)m (m = 0, 1 and n = 1, 2) clusters. Introduction of the FA dopant resulted in the production of HCOO-·FA reactant ions. The effect of the FA dopant on the APCI of different classes of compounds was investigated, including plant hormones, pesticides, acidic drugs, and explosives. FA dopant APCI resulted in deprotonation and/or adduct ion formation, [M - H]- and [M + HCOO]-, respectively. Supporting density functional theory (DFT) calculations showed that the ionization mechanism depended on the gas-phase acidity of the compounds. FA dopant APCI led to the improvement of detection sensitivity, suppression of fragmentation, and changes in the ion mobilities of the analyte ions for analytes with suitable molecular structures and gas acidity.
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Methyl salicylate (MeSA) is a plant-signaling molecule that plays an essential role in the regulation of plant responses to biotic and abiotic pathogens. In this work, solid phase microextraction (SPME) and a multicapillary column (MCC) are coupled to ion mobility spectrometry (IMS) to detect MeSA in tomato leaves. The SPME-MCC-IMS method provides two-dimensional (2D) separation by both MCC and IMS, based on the retention and drift times. The effect of the IMS polarity on the separation efficiency of MCCs was also investigated. In the positive polarity, ionization of MeSA resulted in [MeSA + H]+ formation while, in the negative, deprotonated ions, [MeSA - H]-, and the O2- adduct ion, [MeSA + O2]-, were formed. In the real sample analysis, the negative polarity operation resulted in the suppression of many matrix molecules and thus in the reduction of interferences. Four different SPME fibers were used for head space analysis, and four MCC columns were investigated. In the negative polarity, complete separation was achieved for all of the MCCs columns. The limits of detection (LODs) of 0.1 µg mL-1 and linear range of 0.25-12 µg mL-1 were obtained for the measurement of MeSA in a standard solution (H2O/CH3OH, 50:50) by the SPME-IMS method with a 5 min extraction time using an SPME with a PDMS fiber, in the negative mode of IMS. The MeSA contents of fresh tomato leaves were determined as 1.5-9.8 µg g-1, 24-96 h after inoculation by tomato mosaic ringspot virus (ToRSV).
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Solanum lycopersicum , Microextração em Fase Sólida , Microextração em Fase Sólida/métodos , Espectrometria de Mobilidade Iônica , Íons/química , Folhas de PlantaRESUMO
Negative polarity atmospheric pressure chemical ionization of selected chlorinated hydrocarbons (tetrachloromethane CCl4 and hexachloroethane C2Cl6, dichloromethane CH2Cl2, trichloromethane CHCl3, 1,1,1,2-tetrachloroethane 1,1,1,2-C2H2Cl4, 1,1,2,2-tetrachloroethane 1,1,2,2,-C2H2Cl4 1,1,2-trichloroethane 1,1,2-C2H3Cl3, and 1,1,2-trichloroethane 1,1,2-C2HCl3) was studied using ion mobility spectrometry (IMS) and IMS combined with time-of-flight mass spectrometer (IMS-TOF MS) techniques, in the dry air and at two different drift gas temperatures (323 and 373 K). The ionization was performed using the O2-CO2(H2O)0,1 reactant ions (RIs), and the dominant ionization reaction was the dissociative electron transfer. The ionization resulted in the appearance of Cl- ions for all substances and [O2H..Cl]- ions, which were absent in the case of perchlorinated substances. The quantum-chemical calculations at the density functional theory level of theory using the ωB97X-D/aug-cc-pVTZ method were performed to calculate the thermochemical data (heats of formations, electron affinities, reaction enthalpies) for RIs, neutral substances, neutral fragments, and the anionic fragments. The calculations supported the experimental observations regarding the endothermicity of the Cl- channel for all substances and the exothermicity of the [O2H..Cl]- channel for the tetrachloro- and trichloroethanes.
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Hidrocarbonetos Clorados , Espectrometria de Mobilidade Iônica , Pressão Atmosférica , Íons/química , Espectrometria de Massas/métodosRESUMO
Ion mobility spectrometry (IMS) equipped with a corona discharge (CD) ion source was used for measurement of three auxin plant hormones including indole-3-acetic acid (IAA), indole-3-propionic acid (IPA), and indole-3-butyric acid (IBA). The measurements were performed in both positive and negative polarities of the CD ion source. Dopant gases NH3, CCl4, and CHBr3 were used to modify the ionization mechanism. A time-of-flight mass spectrometer (TOFMS) orthogonal to the IMS cell was used for identification of the product ions. Density functional theory was used to rationalize formation of the ions, theoretically. The mixtures of the auxins were analyzed by CD-IMS. The separation performance depended on the ion polarity and the dopants. In the positive polarity without dopants, auxins were ionized via protonation and three distinguished peaks were observed. Application of NH3 dopant resulted in two ionization channels, protonation, and NH4+ attachment leading to peak overlapping. In the negative polarity, two ionization reactions were operative, via deprotonation and O2- attachment. The separation of the monomer peaks was not achieved while the peaks of anionic dimers [2 M-H]- were separated well. The best LOD (4 ng) was obtained in negative polarity with CCl4 dopant. Methylation (esterification) of IAA improved LODs by about one order.
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Espectrometria de Mobilidade Iônica , Reguladores de Crescimento de Plantas , Ácidos Indolacéticos , Íons/química , Espectrometria de Massas/métodosRESUMO
An atmospheric Pressure Field Effect (APFE) ionisation source for drift tube ion mobility spectrometry has been developed for operation in positive and negative polarities. The formation of negative and positive ions in synthetic air was studied and compared with the Atmospheric Pressure Corona Discharge (APCD) ionisation source. The APFE ionisation source is of point-to-plane geometry with a 10 µm Pt point electrode, a stainless steel plate electrode and ultra-high resistance (20 GΩ) current limiters. In the case of negative polarity, the ionisation source was able to generate Reactant Ions (RIs) O2-(H2O)n and O2-CO2(H2O)n, and in the case of positive polarity, stable production of H+(H2O)n RI was achieved in two different gas flow regimes of the IMS. RIs formed in the APFE in both polarities have made it a reliable chemical ionisation source at atmospheric pressure. The identification of the ions generated in the APFE was performed using an Ion Mobility Spectrometer coupled with an orthogonal acceleration Time of Flight Mass Spectrometer (IMS-oa-TOF-MS). The chemical ionisation of molecules was demonstrated for the APFE ionisation source in positive (2,6-di-tert-butyl-pyridine) and negative (tetrachloromethane) polarities.
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Pressão Atmosférica , Espectrometria de Mobilidade Iônica , Íons , Espectrometria de Massas/métodosRESUMO
The excitation of nitromethane (CH3 NO2 ), which is an important propellant and prototypic molecule for large class of explosives, has been investigated by electron impact and subsequent emission of photons in the UV-VIS spectral region between 300â nm and 670â nm. Emission spectrum of nitromethane was recorded at an electron energy of 50â eV. New dissociative excitation channels were observed through the appearance of different CH, CN, NH, OH and NO bands, and the Balmer series of atomic hydrogen. In addition, relative emission cross sections were recorded for the transitions of selected fragments. The emission spectrum was captured with significantly higher resolution in comparison to previous studies.
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In this study, we have demonstrated a separation of positional isomers of some derivatives of alkoxyphenylcarbamic acid. These compounds belong to drugs with local anesthetics activity. The low volatility compounds were analysed by a Thin Layer Chromatography (TLC) and Ion Mobility Spectrometry (IMS) using diode laser desorption for sample introduction to IMS. This combined approach allowed the identification of compounds. Also, we have carried out IMS studies of all compounds and determined their ion mobilities The ion mobilities were increasing with the geometry change from position ortho to para of alkoxy chain, which is in agreement with their different collision cross section (CCS).
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Cromatografia em Camada Fina/métodos , Espectrometria de Mobilidade Iônica/métodos , Fenilcarbamatos/análise , Fenilcarbamatos/química , IsomerismoRESUMO
An online coupling of microchip isotachophoresis (µITP) with ion mobility spectrometry (IMS) using thermal evaporation interface is reported for the first time. This combination integrates preconcentration power of the µITP followed by unambiguous identification of trace compounds in complex samples by IMS. Short-chain carboxylic acids, chosen as model analytes, were first separated by the µITP in a discontinuous electrolyte system at pH 5-6, and subsequently evaporated at 130 °C during their transfer to the IMS analyzer. Various parameters, affecting the transfer of the separated sample components through the evaporation system, were optimized to minimize dispersion and loss of the analytes as well as to improve sensitivity. The following analytical attributes were obtained for carboxylic acids in the standard solutions: 0.1-0.3 mg L-1 detection limits, 0.4-0.9 mg L-1 quantitation limits, linear calibration range from the quantitation limit to 75 mg L-1, 0.2-0.3% RSD of the IMS response and 98-102% accuracy. The analytical potential of the developed µITP-IMS combination was demonstrated on the analysis of various food, pharmaceutical and biological samples, in which the studied acids are naturally present. These include: apple vinegar, wine, fish sauce, saliva and ear drops. In the real samples, 0.3-0.6% RSD of the IMS response and 93-109% accuracy were obtained.
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Espectrometria de Mobilidade Iônica/métodos , Isotacoforese/métodos , Líquidos Corporais/química , Análise de Alimentos , Preparações Farmacêuticas/análiseRESUMO
In this paper, the rate coefficients (k) and activation energies (Ea) for SiCl4, SiHCl3, and Si(CH3)2(CH2Cl)Cl molecules in the gas phase were measured using the pulsed Townsend technique. The experiment was performed in the temperature range of 298-378 K, and carbon dioxide was used as a buffer gas. The obtained k depended on temperature in accordance with the Arrhenius equation. From the fit to the experimental data points with function described by the Arrhenius equation, the activation energies (Ea) were determined. The obtained k values at 298 K are equal to (5.18 ± 0.22) × 10-10 cm3·s-1, (3.98 ± 1.8) × 10-9 cm3·s-1 and (8.46 ± 0.23) × 10-11 cm3·s-1 and Ea values were equal to 0.25 ± 0.01 eV, 0.20 ± 0.01 eV, and 0.27 ± 0.01 eV for SiHCl3, SiCl4, and Si(CH3)2(CH2Cl)Cl, respectively. The linear relation between rate coefficients and activation energies for chlorosilanes was demonstrated. The DFT/B3LYP level coupled with the 6-31G(d) basis sets method was used for calculations of the geometry change associated with negative ion formation for simple chlorosilanes. The relationship between these changes and the polarizability of the attaching center (αcentre) was found. Additionally, the calculated adiabatic electron affinities (AEA) are related to the αcentre.
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RATIONALE: Phthalates are widely used in consumer products in the chemical industries. Due to their abundance in the milieu, their potentially harmful effect on the environment, human and animal health there is a need for sensitive and fast methods for their detection. METHODS: Positive polarity Corona Discharge Atmospheric Pressure Chemical Ionization (CD-APCI) in the air was applied for ionization of phthalates. The ionization method for the phthalates was studied by atmospheric pressure Ion Mobility Spectrometry (IMS) and hybrid IMS/orthogonal acceleration Time-of-Flight Mass spectrometry (IMS-oaTOF-MS). RESULTS: CD-APCI IMS and MS spectra of selected phthalates (dimethyl phthalate, diethyl phthalate, diethyl isophthalate, diethyl terephthalate, dipropyl phthalate, diisopropyl phthalate, dibutyl phthalate, diisobutyl phthalate, and dibutyl terephthalate) were recorded. In the case of the ortho- and "iso"-isomers exclusively the protonated molecular ions [M + H]+ were detected. In the case of the para- and meta-isomers and regioisomers, APCI resulted in the appearance of hydrated protonated molecular ions [M + H]+ ·(H2 O)0,1,2 . The ion mobilities, collision cross-sections of these ions in air, as well as the limits of detection (LODs) for the phthalate vapors, were determined. In the case of isomeric phthalates, we have demonstrated the potential of the IMS technique for their separation. CONCLUSIONS: The results show that CD-APCI in combination with IMS and IMS-oaTOF-MS is a suitable method for the fast and sensitive detection of phthalates with the potential to separate some isomers.
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A rapid and simple method is proposed for detection of elemental mercury (Hg) vapor by ion mobility spectrometry (IMS). Negative corona discharge (CD) as the ionization source and chloroform as the dopant gas were used to produce Cl- reactant ion. A mass spectrum of the product ions confirmed that the mechanism of ionization is based on Cl- anion attachment to Hg and formation of HgCl- ion. It was found that the optimum drift gas temperature for Hg detection was about 160 °C and the drift gas flow rate should be minimized and just sufficient to clear contaminants and carry-over from the drift cell. The drift time of the HgCl- peak relative to that of the Cl- peak at 160 °C is 1.52 ms corresponding to the reduced mobility of 1.90 cm2/Vs. Because many volatile organic compounds (VOCs) such as alcohols, amines, aldehydes, ketones, and alkanes are not ionized in the negative mode of CD-IMS, these compounds do not interfere with the detection of Hg. Mercaptans peaks also did not show any interference with the Hg signal. Hence, the method is highly selective for detection of Hg in natural gas containing sulfur compounds. The detection limit of Hg obtained by the proposed method was 0.07 mg/m3. The method was successfully verified in determination of the mercury vapor content of a fluorescent lamp, as a real sample.
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Técnicas de Química Analítica/métodos , Clorofórmio/química , Gases/análise , Espectrometria de Mobilidade Iônica , Mercúrio/análise , Álcoois , Técnicas de Química Analítica/instrumentação , Gases/química , Íons/química , Gás Natural/análise , Compostos de Enxofre/química , Temperatura , Compostos Orgânicos Voláteis/análiseRESUMO
Phthalates are widely industrially used and their toxicity is of serious environmental and public health concern. Chemical ionization (CI) analytical techniques offer the potential to detect and monitor traces of phthalate vapours in air or sample headspace in real time. Promising techniques include selected ion flow tube mass spectrometry (SIFT-MS), proton transfer reaction mass spectrometry (PTR-MS) and ion mobility spectrometry (IMS). To facilitate such analyses, reactions of H3O+, O2+ and NO+ reagent ions with phthalate molecules need to be understood. Thus, the ion chemistry of dimethyl phthalate isomers (dimethyl phthalate, DMP - ortho; dimethyl isophthalate, DMIP - meta; dimethyl terephthalate, DMTP - para), diethyl phthalate (DEP), dipropyl phthalate (DPP) and dibutyl phthalate (DBP) was studied by SIFT-MS. Reactions of H3O+, O2+ and NO+ with these phthalate molecules M were found to produce the characteristic primary ion products MH+, M+ and MNO+, respectively. In addition, a dissociation process forming the (M-OR)+ fragment was observed. For phthalates with longer alkyl chains, mainly DPP and DBP, a secondary dissociation channel triggered by the McLafferty rearrangement was also observed. However, this is dominant only for the more energetic O2+ reactions with phthalates, additionally resulting in a recognisable formation of the protonated phthalate anhydride. For the NO+ reagent ions, the McLafferty rearrangement makes only a minor contribution and for H3O+, it was not observed. Experiments on the effect of water vapour on this ion chemistry have shown that protonated DMIP and DMTP efficiently associate with H2O forming the DMIP·H+H2O, DMIP·H+(H2O)2 and DMTP·H+H2O cluster ions, whilst the protonated ortho DMP isomer as well as other ortho phthalates DEP, DPP and DBP does not associate with H2O. The results indicate that the degree of hydration can be used to identify specific phthalate isomers in CI.
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We present the design, construction, and first spectra of a step-scan Michelson Fourier-transform spectrometer for optical emission spectroscopy in the UV-VIS spectral range. The mirror motion mechanism is based on a long-travel piezo-based linear translation stage with built-in position feedback. The step-scan arrangement allows for signal integration, making the instrument suitable for measurements of less intensive radiation sources and for the photon-counting technique. The spectrometer consists of two coupled Michelson interferometers, one for the spectrometer itself and the other to provide positional reference for the mirror stepping mechanism using interference fringes of a stabilized 635 nm laser diode. Using interpolation of the laser interferogram and taking advantage of the translation stage precision in linear-piezo mode, the mechanism is capable of performing 79 nm steps, which puts the Nyquist wavelength at â¼320 nm. The spectrometer was tested by measuring the spectra of HgAr cold-cathode fluorescent lamp and electron-induced fluorescence of ambient air. Two different detectors were used, an amplified photodiode detector and a photomultiplier tube module in photon counting mode. The highest achieved experimental spectral resolving power was â¼4000 using 1 mm of total mirror travel and the highest achieved noise-free dynamic range was 103. Test results show that the instrument is suitable for use with moderate-to-low intensity signal sources such as small gas discharges and spectroscopic measurements at astronomical telescopes.
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An Ion Mobility Spectrometry (IMS) apparatus has been used to detect the ß-methyl-γ-octalactone (Whisky Lactone - WL) standard in the air and as well WL vapours originating from the oak wood samples. The IMS was equipped with Atmospheric Pressure Chemical Ionisation (APCI) ion source based on a Corona Discharge (CD) and was operated in the positive polarity. The IMS spectrum of WL exhibits two peaks, a monomer with reduced ion mobility value K0 = 1.39 cm2V-1s-1 and dimer K0 = 1.09 cm2V-1s-1. Using Ion Mobility orthogonal acceleration Time of Flight mass spectrometer (IMS-oaTOF MS) these peaks were identified as protonated monomer M.H+.(H2O)0,1 and dimer M2.H+ ions respectively. The limit of detection study resulted in LOD for WL of 50 ppbv. Detection of WL from oak wood samples of different "Quality Level" (QL) categories (categories 1 to 10), indicated strong correlation between the QL category number and the response of the IMS.
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In this work we have studied the ionisation mechanism of Atmospheric Pressure Chemical Ionisation (ACPI) for three isomers of dimethyl phthalate (dimethyl phthalate - DMP (ortho- isomer), dimethyl isophthalate - DMIP (meta) and dimethyl terephthalate - DMTP (para)) using Ion Mobility Spectrometry (IMS) and IMS combined with an orthogonal acceleration Time of Flight Mass Spectrometer (oa-TOF MS). The molecules were chemically ionised using reactant ions H+·(H2O)n (n = 3 and 4). The positive IMS and IMS-oaTOF mass spectra of the isomers showed significant differences in the ion mobilities and in the ion composition. The IMS - oaTOF spectra consisted of clusters of ions M·H+·(H2O)n with different degrees of hydration (n = 0, 1, 2, 3) for different isomers. In the case of the DMP isomer, we have observed almost exclusive formation of M·H+ by proton transfer ionisation, while in the case of DMIP and DMTP, hydrated ions M·H+·(H2O)n (n = 1, 2, 3) and M·H+·(H2O)n (n = 0, 1, 2) respectively were detected, formed via adduct formation reactions. This behaviour was elucidated by differences in ionisation processes. In order to elucidate the ionisation processes we have carried out DFT calculations of the structures and energies of the neutral and protonated and hydrated isomers (for different conformers) and their corresponding proton affinities (PA) and hydration energies.
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Protonation, hydration, and cluster formation of ammonia, formaldehyde, formic acid, acetone, butanone, 2-ocatanone, 2-nonanone, acetophenone, ethanol, pyridine, and its derivatives were studied by IMS-TOFMS technique equipped with a corona discharge ion source. It was found that tendency of the protonated molecules, MH+, to participate in hydration or cluster formation depends on the basicity of M. The molecules with higher basicity were hydrated less than those with lower basicity. The mass spectra of the low basic molecules such as formaldehyde exhibited larger clusters of MnH+(H2O)n, while for compounds with high basicity such as pyridine, only MH+ and MH+M peaks were observed. The results of DFT calculations show that enthalpies of hydrations and cluster formation decrease as basicities of the molecules increases. Using comparison of mass spectra of formic acid, formaldehyde, and ethanol, effect of structure on the cluster formation was also investigated. Formation of symmetric (MH+M) and asymmetric proton-bound dimers (MH+N) was studied by ion mobility and mass spectrometry techniques. Both theoretical and experimental results show that asymmetric dimers are formed more easily between molecules (M and N) with comparable basicity. As the basicity difference between M and N increases, the enthalpy of MH+N formation decreases.
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Ionization of 2-nonanone, cyclopentanone, acetophenone, pyridine, and di- tert-butylpyridine (DTBP) in a corona discharge (CD) atmospheric pressure chemical ionization (APCI) ion source was studied using ion mobility (IMS) and time-of-flight mass spectrometry (TOF-MS). The IMS and MS spectra were recorded in the absence and presence of ammonia dopant. Without NH3 dopant, the reactant ion (RI) was H+(H2O) n, n = 3,4, and the MH+(H2O) x clusters were produced as product ions. Modeling of hydration shows that the amount of hydration ( x) depends on basicity of M, temperature and water concentration of drift tube. In the presence of ammonia (NH4+(H2O) n as RI) two kinds of product ions, MH+(H2O) x and MNH4+(H2O) x, were produced, depending on the basicity of M. With NH4+(H2O) n as RI, the product ions of pyridine and DTBP with higher basicity were MH+(H2O) x while cyclopentanone, 2-nonanone, and acetophenone with lower basicity produce MNH4+(H2O) x. To interpret the formation of product ions, the interaction energies of M-H+, H+-NH3, and H+-OH2 in the M-H+-NH3 and M-H+-OH2 and M-H+-M complexes were computed by B3LYP/6-311++G(d,p) method. It was found that for a molecule M with high basicity, the M-H+ interaction is strong leading in weakening of the H+-NH3, and H+-OH2 interactions in the M-H+-NH3 and M-H+-OH2 complexes.
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Experimental investigation of electron ionization (EI) of and electron attachment (EA) onto dicyclohexyl phthalate (DCHP) was carried out using a crossed electron and molecular beam technique. Formation of positive and negative ions by EI and EA with the corresponding dissociation processes was studied and discussed. Due to a low ion yield of the parent positive ion, we were not able to estimate the ionization energy of DCHP. However, we estimated the appearance energies for the protonated phthalate anhydride (m/z 149) to be 10.5 eV and other significant ionic fragments of m/z 249 [DCHP-(R-2H)]+, m/z 167 [DCHP-(2R-3H)]+, and m/z 83 [C6H11]+. The reaction mechanisms of the dissociative ionization process were discussed. In the case of negative ions, we estimated the relative cross sections for a transient negative ion (TNI) and for several detected ions. At low electron energies (close to 0 eV), the TNI of DCHP molecules was the dominant ion, with products of dissociative EA dominating in broad resonances at 7.5 and 8.5 eV.