Ultrasound-assisted preparation of PdCo bimetallic nanoparticles loaded on beta zeolite for efficient catalytic hydrogen production from dodecahydro-N-ethylcarbazole.

Research and development of high-performance catalysts is a key technology to realize hydrogen energy storage and transportation based on liquid organic hydrogen carriers. Co/beta was prepared using beta zeolite as a carrier via an electrostatic adsorption (ESA)-chemical reduction method, and it was used as the template and reducing agent to prepare bimetallic catalysts via an ultrasonic assisted galvanic replacement process (UGR). The fabricated PdCo/beta were characterized by TEM, XPS, FT-IR, XRD, H2-TPR, and H2-TPD. It was shown that the ultrafine PdCo nanoparticles (NPs) are evenly distributed on the surface of the beta zeolite. There is electron transfer between metal NPs and strong-metal-support-interaction (SMSI), which results in highly efficient catalytic dodecahydro-N-ethylcarbazole (12H-NEC) dehydrogenation performance of PdCo bimetallic catalysts. The dehydrogenation efficiency reached 100 % in 4 h at 180 °C and 95.3 % in 6 h at 160 °C. The TOF of 146.22 min-1 is 7 times that of Pd/beta. The apparent activation energy of the reaction is 66.6 kJ/mol, which is much lower than that of Pd/beta. Under the action of ultrasonic waves, the galvanic replacement reaction is accelerated, and the intermetal and metal-carrier interactions are enhanced, which improves the catalytic reaction performance.

Ionization state and dielectric constant in cold rarefied hydrocarbon plasmas of inertial confinement fusion.

A combined approach to study cold rarefied matter is introduced that includes a semianalytical method based on the free-energy minimization and ab initio calculations based on the finite-temperature density-functional theory. The approach is used to calculate the ionization state of hydrocarbon (CH) under the shock-release conditions in inertial confinement fusion. The dielectric constant of CH is calculated using the Kubo-Greenwood formulation and contribution from atomic polarizabilities is found to be as important as the free-electron contribution. Using the ionization state and dielectric constant, the electron density profile in the rarefaction wave of the shock-release plasma is obtained.

Nonlinear transmission of laser light through coronal plasma due to self-induced incoherence.

The success of direct laser-driven inertial confinement fusion (ICF) relies critically on the efficient coupling of laser light to plasma. At ignition scale, the absolute stimulated Raman scattering (SRS) instability can severely inhibit this coupling by redirecting and strongly depleting laser light. This article describes a new dynamic saturation regime of the absolute SRS instability near one-quarter of the critical density. The saturation occurs when spatiotemporal ion-acoustic fluctuations in the plasma density detune the instability resonance. The dynamic saturation mitigates the strong depletion of laser light and enhances its transmission through the instability region, explaining the coupling of laser light to ICF targets at higher plasma densities.

Anomalous Absorption by the Two-Plasmon Decay Instability.

Radiation-hydrodynamic simulations of directly driven fusion experiments at the Omega Laser Facility predict absorption accurately when targets are driven at low overlapped laser intensity. Discrepancies appear at increased intensity, however, with higher-than-expected laser absorption on target. Strong correlations with signatures of the two-plasmon decay (TPD) instability-including half-harmonic and hard-x-ray emission-indicate that TPD is responsible for this anomalous absorption. Scattered light data suggest that up to ≈30% of the laser power reaching quarter-critical density can be absorbed locally when the TPD threshold is exceeded. A scaling of absorption versus TPD threshold parameter was empirically determined and validated using the laser-plasma simulation environment code.

Plasma Density Measurements of the Inner Shell Release.

The material release on the side opposite to the laser drive of a CH shell was probed at conditions relevant to inertial confinement fusion. The release was found to expand further with a longer scale length than that predicted by radiation-hydrodynamic simulations. The simulations show that a relaxation of the back side of the shell consistent with measurements explains the experimentally observed reduction in inertial confinement fusion implosion performance-specifically, reduced areal density at peak compression.

Three-dimensional particle-in-cell modeling of parametric instabilities near the quarter-critical density in plasmas.

The nonlinear regime of laser-plasma interactions including both two-plasmon decay (TPD) and stimulated Raman scattering (SRS) instabilities has been studied in three-dimensional (3D) particle-in-cell simulations with parameters relevant to the inertial confinement fusion (ICF) experiments. SRS and TPD develop in the same region in plasmas, and the generation of fast electrons can be described accurately with only the full model including both SRS and TPD. The growth of instabilities in the linear stage is found to be in good agreement with analytical theories. In the saturation stage the low-frequency density perturbations driven by the daughter waves of the SRS side scattering can saturate the TPD and consequently inhibit the fast-electron generation. The fast-electron flux in 3D modeling is up to an order of magnitude smaller than previously reported in 2D TPD simulations, bringing it close to the results of ICF experiments.

Tripled yield in direct-drive laser fusion through statistical modelling.

Focusing laser light onto a very small target can produce the conditions for laboratory-scale nuclear fusion of hydrogen isotopes. The lack of accurate predictive models, which are essential for the design of high-performance laser-fusion experiments, is a major obstacle to achieving thermonuclear ignition. Here we report a statistical approach that was used to design and quantitatively predict the results of implosions of solid deuterium-tritium targets carried out with the 30-kilojoule OMEGA laser system, leading to tripling of the fusion yield to its highest value so far for direct-drive laser fusion. When scaled to the laser energies of the National Ignition Facility (1.9 megajoules), these targets are predicted to produce a fusion energy output of about 500 kilojoules-several times larger than the fusion yields currently achieved at that facility. This approach could guide the exploration of the vast parameter space of thermonuclear ignition conditions and enhance our understanding of laser-fusion physics.

Experimental platform for investigations of high-intensity laser plasma interactions in the magnetic field of a pulsed power generator.

An experimental platform for the studying of high-intensity laser plasma interactions in strong magnetic fields has been developed based on the 1 MA Zebra pulsed power generator coupled with the 50-TW Leopard laser. The Zebra generator produces 100-300 T longitudinal and transverse magnetic fields with different types of loads. The Leopard laser creates plasma at an intensity of 1019 W/cm2 in the magnetic field of coil loads. Focusing and targeting systems are integrated in the vacuum chamber of the pulsed power generator and protected from the plasma debris and strong mechanical shock. The first experiments with plasma at laser intensity >2 × 1018 W/cm2 demonstrated collimation of the laser produced plasma in the axial magnetic field strength >100 T.

The meio- to macrozoobenthos ratio in a lake benthic community: Dynamic aspect.

Multiyear data (2002-2015) on the biomasses of meio- and macrozoobenthic communities have been studied at different depths of a small lake in northern Karelia. A trend towards anti-phase changes in meio- and macrobenthic biomasses was observed and, as a consequence, the ratio between these components varied significantly in different years. Thus, inter-annual dynamics should be taken into account in analysis of hydrobiological data.

Multiple beam two-plasmon decay: linear threshold to nonlinear saturation in three dimensions.

The linear stability of multiple coherent laser beams with respect to two-plasmon-decay instability in an inhomogeneous plasma in three dimensions has been determined. Cooperation between beams leads to absolute instability of long-wavelength decays, while shorter-wavelength shared waves are shown to saturate convectively. The multibeam, in its absolutely unstable form, has the lowest threshold for most cases considered. Nonlinear calculations using a three-dimensional extended Zakharov model show that Langmuir turbulence created by the absolute instability modifies the convective saturation of the shorter-wavelength modes, which are seen to dominate at late times.

Experimental validation of the two-plasmon-decay common-wave process.

The energy in hot electrons produced by the two plasmon decay instability, in planar targets, is measured to be the same when driven by one or two laser beams and significantly reduced with four for a constant overlapped intensity on the OMEGA EP. This is caused by multiple beams sharing the same common electron-plasma wave. A model, consistent with the experimental results, predicts that multiple laser beams can only drive a resonant common two plasmon decay electron-plasma wave in the region of wave numbers bisecting the beams. In this region, the gain is proportional to the overlapped laser beam intensity.

Generating energetic electrons through staged acceleration in the two-plasmon-decay instability in inertial confinement fusion.

A new hot-electron generation mechanism in two-plasmon-decay instabilities is described based on a series of 2D, long-term (~10 ps) particle-in-cell and fluid simulations under parameters relevant to inertial confinement fusion. The simulations show that significant laser absorption and hot-electron generation occur in the nonlinear stage. The hot electrons are stage accelerated from the low-density region to the high-density region. New modes with small phase velocities develop in the low-density region in the nonlinear stage and form the first stage for electron acceleration. Electron-ion collisions are shown to significantly reduce the efficiency of this acceleration mechanism.

Growth and saturation of convective modes of the two-plasmon decay instability in inertial confinement fusion.

Particle-in-cell (PIC) and fluid simulations of two-plasmon decay (TPD) instability under conditions relevant to inertial confinement fusion show the importance of convective modes. Growing at the lower density region, the convective modes can cause pump depletion and are energetically dominant in the nonlinear stage. The PIC simulations show that TPD saturates due to ion density fluctuations, which can turn off TPD by raising the instability threshold through mode coupling.

Optimizing electron-positron pair production on kilojoule-class high-intensity lasers for the purpose of pair-plasma creation.

Expressions for the yield of electron-positron pairs, their energy spectra, and production rates have been obtained in the interaction of multi-kJ pulses of high-intensity laser light interacting with solid targets. The Bethe-Heitler conversion of hard x-ray bremsstrahlung [D. A. Gryaznykh, Y. Z. Kandiev, and V. A. Lykov, JETP Lett. 67, 257 (1998); K. Nakashima and H. Takabe, Phys. Plasmas 9, 1505 (2002)] is shown to dominate over direct production (trident process) [E. P. Liang, S. C. Wilks, and M. Tabak, Phys. Rev. Lett. 81, 4887 (1998)]. The yields and production rates have been optimized as a function of incident laser intensity by the choice of target material and dimensions, indicating that up to 5 x 10 (11) pairs can be produced on the OMEGA EP laser system [L. J. Waxer, Opt. Photonics News 16, 30 (2005)]. The corresponding production rates are high enough to make possible the creation of a pair plasma.

Multibeam effects on fast-electron generation from two-plasmon-decay instability.

Experiments with multiple laser beams have been carried out in both spherical and planar geometry to study two-plasmon-decay instability, the predominant source of suprathermal electrons in direct-drive inertial confinement fusion experiments. These electrons are observed using the hard x rays generated through electron-target interactions. The experiments show for the first time that the total overlapped intensity governs the scaling of the suprathermal-electron generation regardless of the number of overlapped beams, in contrast to conventional theories that are based on the single-beam approximation.

Classification of PDZ domains.

A diverse family of PDZ domains has been identified, but the rules that govern their ligand specificity are not clear. Here we propose a novel classification of PDZ domains based on the nature of amino acids in the two critical positions in the PDZ domain fold. Using these principles, we classified PDZ domains present in the SMART database. Using yeast two-hybrid, in vitro pull-down and plasmon surface resonance assays, we demonstrated that in agreement with their position in the proposed classification the Mint1-1, hINADL-5, and PAR6 PDZ domains display similar dual ligand specificity. The proposed classification helps to organize PDZ domain containing proteins.

Nonlinear propagation of a randomized laser beam through an expanding plasma.

We present simulations of the interaction of a random phase plate laser beam with an underdense, expanding plasma for conditions typical of recent LULI experiments. We use a new code that describes the paraxial propagation of the laser, accounting for the nonlinear evolution of the plasma in an isothermal fluid description with weakly collisional electrons. The transmitted light, in excellent agreement with experiment, is shown to be strongly redshifted as a result of self-phase modulation due to self-focusing.

Blood cells and hormonal and immunological parameters of humans in northeast Russia.

In this study the hormone and immune system parameters as well as the number of erythrocytes and hemoglobin concentration in people adapting to the northeast of Russia have been investigated. It was shown that in newcomers to the north, depending on their duration of adaptation, a specific regional norm of response in functional indices is formed which differs from parameters of the European part of the country. The number and character of correlations proved to reflect the process of functional alterations. From the structure of the correlation played the degree of human adaptation to natural and climatic extremes can be assessed.