RESUMO
In this work, a portable-Raman device (excitation wavelength 1064nm) was employed for the first time for continuously monitoring the complex molecular dynamics of terpenoid resins (dammar, mastic, colophony, sandarac and shellac), which occur during their ageing under artificial light exposure. The instrumentation was equipped with a pyroelectric sensor allowing for temperature control of the sample's irradiated surface while the acquisition of spectra occurs by setting fixed maximum temperature and total radiant exposure. Resins were dropped into special pits over a dedicated rotating wheel moved by a USB motor. The rotation allowed samples sliding between the positions designated for the acquisition of the Raman spectra and that for artificial ageing. Samples were exposed to artificial light for 45-days and almost 400 spectra for each resin sample were collected. The exposure to artificial light led to significant changes allowing the characterization of the alteration process. The automated acquisition of a large number of spectra overtime during light-exposure has given the possibility to distinguish fast dynamics, mainly associated to solvent evaporation, from those slower due to resins photo-degradation processes.
RESUMO
The present work focuses on the potential of 3D digital microscopy for assessing micro-morphological features during laser cleaning treatments of artworks. This application requires preliminary optimization studies aimed at defining operative irradiation parameters and practicable degree of cleaning, as well as in situ diagnostic assessments during the restoration work. To this goal, we developed and tested a dedicated 3D digital microscope by implementing the "shape-from-focus" technique. The significant potential of this instrument, which provides textural and chromatic information, was proven for the phenomenological characterization of black crust removal from stones, earthy concretion from bronzes and dark varnish from easel paintings. Comparative measurements using 3D digital microscopy and contact microprofilometry were performed after laser cleaning tests of prepared samples, genuine archaeological bronze artefacts and a stone sculptural element from Florence's Dome. The results achieved demonstrate the effectiveness and reliability of the novel approach and the advantages it provides with respect to alternative techniques, which will allow the methods to be used in the wider restoration community.
RESUMO
We report the development of a novel portable and low-cost laser induced plasma spectroscopy (LIPS) system and describe the application method for quantitative characterisation of quaternary copper alloy artefacts. The device was carefully calibrated and phenomenologically characterised using a set of reference samples. The reliability of the quantitative measurement of the depth profile and bulk compositions was assessed through crossed comparisons with traditional analytical techniques. Finally, the LIPS system was applied to investigate a museum figurine of unknown origin composed of several pieces, which is representative of a typical authentication problem.
RESUMO
A miniaturized probe comprising a circular array of optical fibers coupled to a graded-index microlens has been designed for analyzing colloidal solutions by photon correlation spectroscopy (PCS). The system's suitability for PCS measurements was validated by experimental testing performed in bulk solutions and small drops of monodisperse and bimodal test colloidal solutions.
RESUMO
A fiber-optic sensor designed to operate inside high-power electric plants is presented. The probe is based on a fiber-optic proximity sensor that detects the light intensity modulation induced by an elastic transducer. The nonlinear response of the optical head is exploited in an original manner to obtain the simultaneous and ndependent measurement of temperature and vibration at 100 Hz. The particular working principle provides an intrinsically lead-insensitive response.
RESUMO
A multimode optical fiber thermometer is described, which makes use of a single fiber for light guiding and a thermochromic solution as a differential absorption temperature transducer. The probe has a novel design and utilizes graded-index microlenses to achieve high coupling efficiency between fiber and transducer. Technical data of the electrooptic unit, along with the working principle of the probe are presented, and calibration tests of the thermometer are given.
RESUMO
A novel fiber optic vibration sensor is presented, based on the motion detection of an elastic cantilever by means of the optical triangulation technique. The sensor was designed to work at a fixed frequency of 100 Hz for applications in high power electrical plants where insulation and EM immunity requirements make fiber optic sensing the most suitable choice. The working linear range reaches a peak amplitude of 0.25 mm; resolution is 0.1 microm; accuracy is better than +/-3%; and sensitivity is 10 mV/microm. Design details and experimental results are reported.