Electro-architected porous platinum on metallic multijunction nanolayers to optimize their optical properties for infrared sensor application.

Tailoring the physicochemical properties of the metallic multijunction nanolayers is a prerequisite for the development of microelectronics. From this perspective, a desired lower reflectance of infrared radiation was achieved by an electrochemical deposition of porous platinum in nonaqueous media on silver mirror supported nickel-chrome and nickel-titanium metallic films with incremental decreasing thicknesses from 80-10 nm. The electro-assembled architectures were examined by means of scanning electron microscopy and Fourier transform infrared spectroscopy and it was observed that the layer and sublayer thicknesses and resistivities have a substantial effect upon the porous platinum morphology and its optical properties. It is here reported that the augmentation of the metallic layer electrical conductivity determines the electroformation of more compact platinum nanolayers. Moreover, the platinum black coating of metallic nanolayers causes a considerable decrease of the reflectance in the region from 1000-8000 cm-1.

Hierarchically-Designed 3D Flower-Like Composite Nanostructures as an Ultrastable, Reproducible, and Sensitive SERS Substrate.

Surface-enhanced Raman spectroscopy (SERS) is an attractive tool in the analytical sciences due to its high specificity and sensitivity. Because SERS-active substrates are only available as two-dimensional arrays, the fabrication of three-dimensional (3D) nanostructures allows for an increased number of hot spots in the focus volume, thus further amplifying the SERS signal. Although a great number of fabrication strategies for powerful SERS substrates exist, the generation of 3D nanostructures with high complexity and periodicity is still challenging. For this purpose, we report an easy fabrication technique for 3D nanostructures following a bottom-up preparation protocol. Enzymatically generated silver nanoparticles (EGNPs) are prepared, and the growth of hierarchically-designed 3D flower-like silica-silver composite nanostructures is induced by applying plasma-enhanced atomic layer deposition (PE-ALD) on the EGNPs. The morphology of these nanocomposites can be varied by changes in the PE-ALD cycle number, and a flower height of up to 10 µm is found. Moreover, the metallized (e.g., silver or gold) 3D nanostructures resulting from 135 PE-ALD cycles of silica creation provide highly reproducible SERS signals across the hydrophobic surface. Within this contribution, the morphological studies, optical properties, as well as the SERS response of these metallized silica-silver composite nanostructures applying vitamin B2 as a model analyte are introduced.

Proof of concept of fiber dispersed Raman spectroscopy using superconducting nanowire single-photon detectors.

Due to its high molecular specificity, Raman spectroscopy is a well-established analytical tool. Usually the inelastically scattered Raman light is spectrally dispersed by a spectrometer. Here, we present an alternative method, using an optical fiber as dispersive element. As the group velocity within the fiber is wavelength-dependent, different Raman bands arrive at different times at the detector. In combination with time-correlated single-photon counting, Raman spectra can be measured in the time domain. As detector we implemented a Superconducting Nanowire Single-Photon Detector (SNSPD), which possesses a timing accuracy of about 20 ps. Within this contribution we show first results of Raman spectra measured in the time domain using gradient index fibers of varying length.

Implementation of a quantum metamaterial using superconducting qubits.

The key issue for the implementation of a metamaterial is to demonstrate the existence of collective modes corresponding to coherent oscillations of the meta-atoms. Atoms of natural materials interact with electromagnetic fields as quantum two-level systems. Artificial quantum two-level systems can be made, for example, using superconducting nonlinear resonators cooled down to their ground state. Here we perform an experiment in which 20 of these quantum meta-atoms, so-called flux qubits, are embedded into a microwave resonator. We observe the dispersive shift of the resonator frequency imposed by the qubit metamaterial and the collective resonant coupling of eight qubits. The realized prototype represents a mesoscopic limit of naturally occurring spin ensembles and as such we demonstrate the AC-Zeeman shift of a resonant qubit ensemble. The studied system constitutes the implementation of a basic quantum metamaterial in the sense that many artificial atoms are coupled collectively to the quantized mode of a photon field.

Orthogonal sequencing multiplexer for superconducting nanowire single-photon detectors with RSFQ electronics readout circuit.

We propose an efficient multiplexing technique for superconducting nanowire single-photon detectors based on an orthogonal detector bias switching method enabling the extraction of the average count rate of a set of detectors by one readout line. We implemented a system prototype where the SNSPDs are connected to an integrated cryogenic readout and a pulse merger system based on rapid single flux quantum (RSFQ) electronics. We discuss the general scalability of this concept, analyze the environmental requirements which define the resolvability and the accuracy and demonstrate the feasibility of this approach with experimental results for a SNSPD array with four pixels.

Design, realization, and characteristics of a transition edge bolometer for sub-millimeter wave astronomy.

The large array bolometer camera is scheduled to succeed its semiconducting predecessor at the Atacama pathfinder experiment. It shall be an array of 300 transition edge sensors operated at a temperature of about 0.25 K, provided by a (3)He evaporation cooler and a pulse tube refrigerator. The instrument will be read out by a superconducting quantum interference device time domain multiplexer. The design and realization of a suitable detector for this instrument is described. Based on sensitivity demands derived from the background limit, the thermal and electrical designs for a spider-web bolometer are deduced. The theoretical predictions are compared to experimental results. The pixel design yields a background-limited performance for background loads corresponding to blackbody sources between 77 K and 300 K and a partially effective anti-aliasing filter for the intended multiplexed readout.

Characteristics and performance of an intensity-modulated optically pumped magnetometer in comparison to the classical M(x) magnetometer.

We compare the performance of two methods for the synchronization of the atomic spins in optically pumped magnetometers: intensity modulation of the pump light and the classical M(x) method using B(1) field modulation. Both techniques use the same set-up and measure the resulting features of the light after passing a micro-fabricated Cs cell. The intensity-modulated pumping shows several advantages: better noise-limited magnetic field sensitivity, misalignment between pumping and spin synchronization is excluded, and magnetometer arrays without any cross-talk can be easily set up.

Superconducting single-photon counting system for optical experiments requiring time-resolution in the picosecond range.

We have developed a cryogenic measurement system for single-photon counting, which can be used in optical experiments requiring high time resolution in the picosecond range. The system utilizes niobium nitride superconducting nanowire single-photon detectors which are integrated in a time-correlated single-photon counting (TCSPC) setup. In this work, we describe details of the mechanical design, the electrical setup, and the cryogenic optical components. The performance of the complete system in TCSPC mode is tentatively benchmarked using 140 fs long laser pulses at a repetition frequency of 75 MHz. Due to the high temporal stability of these pulses, the measured time resolution of 35 ps (FWHM) is limited by the timing jitter of the measurement system. The result was cross-checked in a Coherent Anti-stokes Raman Scattering (CARS) setup, where scattered pulses from a ß-barium borate crystal have been detected with the same time resolution.

Light-shift suppression in a miniaturized Mx optically pumped Cs magnetometer array with enhanced resonance signal using off-resonant laser pumping.

The performance of an optically pumped Mx magnetometer with miniaturized Cs cell at earth's magnetic field strength (50 µT) is investigated. Operation using detuned high intensity laser light is shown to be superior to the conventional resonant operation in terms of the projected shot-noise-limited ( 50 fT/√Hz) and the actual noise-limited sensitivity using a noise compensation method. The Zeeman light shift effect, emerging due to the off-resonant circularly polarized laser radiation and leading to a strong orientational dependence of the measurement, is suppressed by averaging two identical magnetometer configurations pumped with oppositely circularly polarized light. A residual heading error within the range of 14 nT, limited by the present experimental characterization setup, was achieved.