Raman spectroscopic measurements and imaging on sub-newton Berkovich and spherical imprints in fused silica.

This paper lays out best practices for evaluating and optimizing a Raman spectroscopy setup to ensure the collection of reliable spectral data and/or Raman images on indented glasses. The Raman spectroscopic measurements and imaging were conducted on residual imprints created with Berkovich and spherical probes at forces in the sub-newton range in fused silica. The capability of a conventional optical instrument for mapping spectral variations in sub-newton imprints on glasses is evaluated by studying the influence of the optical configuration (choice of microscope objective) on the spatial resolution of the spectroscopy setup. The spatial resolution was quantitatively assessed in Z profile measurements and qualitatively evaluated by mapping changes in spectral features and correlated densification within the indented regions of fused silica specimens. The paper discusses the importance of appropriately matching the analysis volume of the Raman spectroscopic setup with the size of the indentation-induced densification zone by demonstrating the detrimental effects a mismatch may have on accurately capturing the magnitude of spectral changes and correlated densification.

Descriptive Analysis of Mental and Physical Wellness in Collegiate Dancers.

INTRODUCTION: Understanding the physical and mental health of collegiate dancers is important for developing appropriate screening protocols and treatment interventions. This study aims to provide descriptive data on the overall health, injury burden, and well-being of a group of collegiate dancers, including the interactions between injury, nutrition, and mental health, to provide insight for wellness screening and interventions in collegiate dance programs. METHODS: Members of the School of Dance at the University of Utah were sent an electronic general health survey. The survey included questions regarding medical history, family history, injuries, diet, sleep quality, symptoms of depression and anxiety, and history of eating disorders. RESULTS: Of the 231 dancers who received the survey, 198 responded (response rate = 85.7%). Fifty 2% of respondents had an active injury. Symptoms of depression and anxiety were common (35.4%), and 37.4% of the dancers were interested in receiving mental health support. Symptoms of depression and anxiety had a significant association with both a history of injury and active injuries (P = .033 and .039, respectively). History of eating disorder was also significantly associated with active injuries (P = .005). The most commonly injured body area was ankle or foot (n = 144, 72.7%), followed by lower leg or shin (n = 76, 38.4%), and knee (n = 61, 30.8%). Over a quarter of the dancers (n = 54, 27.3%) reported having trouble sleeping, and 9.1% reported having a history of eating disorder. CONCLUSIONS: This study highlights the important interplay between mental health, sleep, nutrition, and injury. These results show that in a group of collegiate dancers, active injuries and mental health concerns are common, and that there are statistically significant associations between injury, nutrition, and mental health. These data provide insight into factors that affect dancer wellness and help inform future screening and intervention protocols for dance programs.

Stress Measurements in Alumina by Optical Fluorescence: Revisited.

Stress measurements in single-crystal and polycrystalline alumina are revisited using a recently developed optical fluorescence energy shift method. The method simultaneously utilizes the R1 and R2 Cr-related ruby line shifts in alumina to determine two components of the stress tensor in crystallographic coordinates, independent of the intended or assumed stress state. Measurements from a range of experimental conditions, including high-pressure, shock, quasi-static, and bulk polycrystals containing thermal expansion anisotropy effects, are analyzed. In many cases, the new analysis suggests stress states and stress magnitudes significantly different from those inferred previously, particularly for shock experiments. An implication is that atomistic models relating stress state to fluorescence shift require significant refinement for use in materials-based residual stress distribution analyses. Conversely, the earliest measurements of fluorescence in polycrystalline alumina are shown to be consistent with recent detailed measurements of stress equilibrium and dispersion.

Review: Coefficients for Stress, Temperature, and Composition Effects in Fluorescence Measurements of Alumina.

The numerical coefficients linearly relating the effects of stress (including pressure), temperature, and composition to shifts in the energies of the Cr-related fluorescence in alumina (Al2O3) are reviewed. The primary focus is the shift of the R1 and R2 "ruby" fluorescence lines under conditions typical for stress determination in polycrystalline Al2O3. No significant experimental difference in the R1 and R2 responses is observed for hydrostatic stress (or pressure) conditions (average shift coefficient of about 7.6 cm-1/GPa), changes in temperature (about 0.140 cm-1/K), or variations in composition (about 120 cm-1/mass fraction of Cr). There are significant differences in the R1 and R2 responses for nonhydrostatic stress conditions. In particular, for uniaxial stress along the a and c directions in the Al2O3 crystal, the R1 piezospectroscopic tensor coefficients (about 3.0 cm-1/GPa and 1.6 GPa cm-1/GPa, respectively) differ considerably, whereas the R2 coefficients (about 2.6 cm-1/GPa and 2.3 GPa cm-1/GPa, respectively) do not. Measurements of the piezospectroscopic tensor coefficients are shown to have interlaboratory relative consistency of about 4 % extending over 30 years, and are consistent with the scalar high-pressure measurements. Measurements of the temperature coefficients are shown to have interlaboratory relative consistency less than 1 % extending over 60 years. Fluorescence-based measurements of stress in polycrystalline Al2O3, although requiring temperature adjustment, are shown to have a relative uncertainty of about 2.5 %.

Determination of Residual Stress Distributions in Polycrystalline Alumina using Fluorescence Microscopy.

Maps of residual stress distributions arising from anisotropic thermal expansion effects in a polycrystalline alumina are generated using fluorescence microscopy. The shifts of both the R1 and R2 ruby fluorescence lines of Cr in alumina are used to create maps with sub-µm resolution of either the local mean and shear stresses or local crystallographic a- and c-stresses in the material, with approximately ± 1 MPa stress resolution. The use of single crystal control materials and explicit correction for temperature and composition effects on line shifts enabled determination of the absolute values and distributions of values of stresses. Temperature correction is shown to be critical in absolute stress determination. Experimental determinations of average stress parameters in the mapped structure are consistent with assumed equilibrium conditions and with integrated large-area measurements. Average crystallographic stresses of order hundreds of MPa are determined with characteristic distribution widths of tens of MPa. The stress distributions reflect contributions from individual clusters of stress in the structure; the cluster size is somewhat larger than the grain size. An example application of the use of stress maps is shown in the calculation of stress-intensity factors for fracture in the residual stress field.

Quantitative Mapping of Stress Heterogeneity in Polycrystalline Alumina using Hyperspectral Fluorescence Microscopy.

The microstructurally-induced heterogeneous stress fields arising in a series of Cr-doped polycrystalline alumina materials are mapped with sub-micrometer sub-grain size resolution using fluorescence microscopy. Analysis of the hyperspectral data sets generated during imaging enabled both the amplitude and position of the characteristic Cr R1 fluorescence peak to be determined at every pixel in an image. The peak amplitude information was used to segment the images into individual grains and grain boundary regions. The peak position information, in conjunction with measurements on single-crystal controls, was used to quantify overall stress distributions in the materials and provide stress scales for maps. The combined information enabled spatial variations in the stress fields in crystallographic axes to be mapped and compared directly with microstructural features such as grains and grain boundaries. The mean c-axis stresses in these materials were approximately 200 MPa with stress distribution widths of about 70 MPa, both increasing with average grain size. Greatest variations in stress were observed at grain junctions; no trend in the stress for individual grains with grain size was observed.

In situ observations of Berkovich indentation induced phase transitions in crystalline silicon films.

The pressure induced phase transitions of crystalline Si films were studied in situ under a Berkovich probe using a Raman spectroscopy-enhanced instrumented indentation technique. The observations suggested strain and time as important parameters in the nucleation and growth of high-pressure phases and, in contrast to earlier reports, indicate that pressure release is not a precondition for transformation to high pressure phases.

Coherent stokes scattering from gold nanorods: critical dimensions and multicolor near-resonant plasmon excitation.

In this study, we detail the coherent Stokes scattering from gold nanorods in ensemble and single particle measurements. An increase of more than an order of magnitude was observed in the surface plasmon resonance enhancement of coherent Stokes scattering by gold nanorods for small changes in nanorod dimensions. The impact of this dimensional change is, in general, smaller when probed by single color linear and non-linear techniques. We find that the size sensitivity and associated wavelength dependence of the enhanced coherent Stokes scattering from individual gold nanorods is consistent with predictions based on local surface plasmon resonances found from exact solutions obtained using boundary element methods.

Comparison of the sensitivity and image contrast in spontaneous Raman and coherent Stokes Raman scattering microscopy of geometry-controlled samples.

We experimentally compare the performance and image contrast of spontaneous Raman and coherent Stokes Raman scattering microscopy. We demonstrate the differences between these techniques on a series of geometry-controlled samples that range in complexity from a point (array of tips) to one-dimensional (line grating) and, lastly, two-dimensional (checkereboard) microstructure. Through the use of this sample series, a comparison of the focal volume, achievable signal-to-noise, and resulting image contrast is made. The results demonstrate the efficiency and spatial resolution attainable in coherent Raman microscopy relative to spontaneous Raman microscopy. Additionally, we detail potential complications in the interpretation of coherent Raman images of sample fine structure, where contrast is no longer based solely on oscillator concentration but can be influenced by sample microstructure.

Fourier transform spectrometry with a near-infrared supercontinuum source.

Optical fiber based supercontinuum light sources combine the brightness of lasers with the broad bandwidth of incandescent lamps and thus are promising candidates for sources in spectroscopic applications requiring high brightness and broad bandwidth. Herein, near-infrared (IR) Fourier transform (FT) spectrometry with a supercontinuum (SC) light source is investigated. The efficient, collimated propagation of broad bandwidth SC light through an 18 m path length multipass cell is demonstrated. A normalized spectral difference is calculated for the SC spectrum on consecutive FT mirror scans and is found to vary by less than 0.5%, indicating excellent spectral stability. The rms noise on zero absorbance lines is obtained as a function of the number of mirror scans at 0.125, 2, and 16 cm(-1) resolution for both the SC and conventional tungsten lamp source. The SC source has approximately a factor of ten times more noise than the lamp under comparable conditions for each resolution and data acquisition time. This clearly indicates that spectral acquisition with the SC source is not detector noise limited. NIR-FT spectra of methane and methyl salicylate, acquired with both the SC and lamp source, are reported. These spectra illustrate the advantage the SC source has over the incandescent source in that it can efficiently traverse long path lengths, thus providing a sensitivity advantage. The spectra also demonstrate the disadvantage of the SC source with respect to the lamp in the increased level of amplitude noise. Prospects for the future use of SC sources in absorption spectroscopy, including possible noise mitigation strategies, are briefly discussed.

Modulus and chemical mapping of multilayer coatings.

Thermoplastic olefins (TPOs) are polymeric materials utilized for interior and exterior automotive parts. These materials are often painted to protect and enhance their appearance. TPO materials possess a low surface energy because of the aliphatic backbone, and adhesion promoters (APs), such as chlorinated polyolefins, are used to increase paint adhesion and improve paint performance. The impact of the AP structure and processing conditions on the mechanical properties and degree of interpenetration was investigated on cross sectioned coatings. The AP structure was varied by the chlorine content and molecular weight for the same TPO and polyester acrylic, melamine-cured paint system. Two different processing conditions were investigated. Mechanical properties were measured using depth-sensing indentation. Long-range diffusion of coating components across each interface was verified with confocal Raman microscopy. The AP interfaces, AP/base coat and AP/TPO, were chemically and mechanically sharp at the 1 mum lateral resolution of both techniques. Depth-sensing indentation measured a modulus gradient across the top coating cross section. The free air surface of the top coat had a higher modulus than the interior. Processing conditions and polishing to prepare the cross section for measurements were found to affect only the control AP.

Near-field infrared imaging and spectroscopy of a thin film polystyrene/poly(ethyl acrylate) blend.

The application of broadband, near-field infrared microscopy to the characterization of the mesoscale structure of a thin film polymer blend is described. Key features of this instrument, which couples the nanoscale spatial resolution of scanning probe microscopy with the chemical specificity of vibrational spectroscopy, include broad tunability and bandwidth, parallel spectral detection for high image acquisition rates, and infrared-transparent aperture probes. Nearfield spectral transmission images of a thin film of polystyrene/poly(ethyl acrylate) acquired in the C-H stretching region are reported. An assessment of the relative importance of transmission image contrast mechanisms is a significant aim of this work. Analysis of the near-field infrared spectra indicates that the image contrast in the C-H stretching region is largely due to near-field coupling and/or scattering effects. Identification and differentiation of the operative contrast mechanisms on the basis of their relative dependence on wavelength is discussed. Analysis of the contrast attributed to absorption is consistent with the chemical morphology of this sample derived from previous chemical modification/atomic force microscopy studies.