1.
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 7): m863-4, 2012 Jul 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22807714
RESUMO
In the title compound, cis-[PtCl2(NH3)2]·C3H7NO, the metal complex mol-ecules are stacked parallel to the b axis, forming close Ptâ¯Pt inter-actions of 3.4071â (7) and 3.5534â (8)â Å and weak N-Hâ¯Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N-Hâ¯O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethyl-formamide mol-ecules. The crystal was found to be a split crystal and was analyzed using two domains related by a rotation of ca 4.4° about the reciprocal axis (-0.351 1.000 0.742) and refined to give a minor component fraction of 0.084â (6).