RESUMO
The structural flexibility at three substitution sites in LaFeAsO enabled investigation of the relation between superconductivity and structural parameters over a wide range of crystal compositions. Substitutions of Nd for La, Sb or P for As, and F or H for O were performed. All these substitutions modify the local structural parameters, while the F/H-substitution also changes band filling. It was found that the superconducting transition temperature [Formula: see text] is strongly affected by the pnictogen height [Formula: see text] from the Fe-plane that controls the electron correlation strength and the size of the [Formula: see text] hole Fermi surface (FS). With increasing [Formula: see text], weak coupling BCS superconductivity switches to the strong coupling non-BCS one where electron correlations and the [Formula: see text] hole FS may be important.
RESUMO
We performed temperature- and doping-dependent high-resolution Raman spectroscopy experiments on YBa_{2}Cu_{3}O_{7-δ} to study B_{1g} phonons. The temperature dependence of the real part of the phonon self-energy shows a distinct kink at T=T_{B1g} above T_{c} due to softening, in addition to the one due to the onset of the superconductivity. T_{B1g} is clearly different from the pseudogap temperature with a maximum in the underdoped region and resembles charge density wave onset temperature, T_{CDW}. We attribute the B_{1g}-phonon softening to an energy gap on the Fermi surface induced by a charge density wave order, which is consistent with the results of a recent electronic Raman scattering study. Our work demonstrates a way to investigate Fermi surface instabilities above T_{c} via phonon Raman studies.
RESUMO
The superconductivity precursor phenomena in high temperature cuprate superconductors is studied by direct measurements of the superconducting condensate with the use of the c-axis optical conductivity of YBa2(Cu1-xZnx)3Oy for several doping levels (p) as well as for several Zn concentrations. Both the real and imaginary parts of the optical conductivity clearly show that the superconducting carriers persist up to the high temperatures Tp that is higher than the critical temperature Tc but lower than the pseudogap temperature T*. Tp increases with reducing doping level like T*, but decreases with Zn substitution unlike T*.