Scrambling Is Necessary but Not Sufficient for Chaos.

We show that out-of-time-order correlators (OTOCs) constitute a probe for local-operator entanglement (LOE). There is strong evidence that a volumetric growth of LOE is a faithful dynamical indicator of quantum chaos, while OTOC decay corresponds to operator scrambling, often conflated with chaos. We show that rapid OTOC decay is a necessary but not sufficient condition for linear (chaotic) growth of the LOE entropy. We analytically support our results through wide classes of local-circuit models of many-body dynamics, including both integrable and nonintegrable dual-unitary circuits. We show sufficient conditions under which local dynamics leads to an equivalence of scrambling and chaos.

Memory in quantum dot blinking.

The photoluminescence intermittency (blinking) of quantum dots is interesting because it is an easily measured quantum process whose transition statistics cannot be explained by Fermi's golden rule. Commonly, the transition statistics are power-law distributed, implying that quantum dots possess at least trivial memories. By investigating the temporal correlations in the blinking data, we demonstrate with high statistical confidence that there is nontrivial memory between the on and off brightness duration data of blinking quantum dots. We define nontrivial memory to be statistical complexity greater than one. We show that this memory cannot be discovered using the transition distribution. We show by simulation that this memory does not arise from standard data manipulations. Finally, we conclude that at least three physical mechanisms can explain the measured nontrivial memory: (1) storage of state information in the chemical structure of a quantum dot; (2) the existence of more than two intensity levels in a quantum dot; and (3) the overlap in the intensity distributions of the quantum dot states, which arises from fundamental photon statistics.

Signatures of Quantum Chaos in an Out-of-Time-Order Tensor.

Motivated by the famous ink-drop experiment, where ink droplets are used to determine the chaoticity of a fluid, we propose an experimentally implementable method for measuring the scrambling capacity of quantum processes. Here, a system of interest interacts with a small quantum probe whose dynamical properties identify the chaoticity of the system. Specifically, we propose a fully quantum version of the out-of-time-order correlator-which we term the out-of-time-order tensor-whose correlations offer clear information theoretic meanings about the chaoticity of a process. We illustrate the utility of the out-of-time-order tensor as a signature of chaos using random unitary processes as well as in the quantum kicked rotor, where the chaoticity is tunable.

Inverse linear versus exponential scaling of work penalty in finite-time bit reset.

A bit reset is a basic operation in irreversible computing. This costs work and dissipates energy in the computer, creating a limit on speeds and energy efficiency of future irreversible computers. It was recently shown by Zhen et al. [Phys. Rev. Lett. 127, 190602 (2021)0031-900710.1103/PhysRevLett.127.190602] that for a finite-time reset protocol, the additional work on top of the quasistatic protocol can always be minimized by considering a two-level system, and then be lower bounded through a thermodynamical speed limit. An important question is to understand under what protocol parameters, including a bit reset error and maximum energy shift, this penalty decreases exponentially vs inverse linearly in the protocol time. Here we provide several analytical results to address this question, as well as numerical simulations of specific examples of protocols.

Universal Bound on Energy Cost of Bit Reset in Finite Time.

We consider how the energy cost of bit reset scales with the time duration of the protocol. Bit reset necessarily takes place in finite time, where there is an extra penalty on top of the quasistatic work cost derived by Landauer. This extra energy is dissipated as heat in the computer, inducing a fundamental limit on the speed of irreversible computers. We formulate a hardware-independent expression for this limit in the framework of stochastic processes. We derive a closed-form lower bound on the work penalty as a function of the time taken for the protocol and bit reset error. It holds for discrete as well as continuous systems, assuming only that the master equation respects detailed balance.

Bounding generalized relative entropies: Nonasymptotic quantum speed limits.

Information theory has become an increasingly important research field to better understand quantum mechanics. Noteworthy, it covers both foundational and applied perspectives, also offering a common technical language to study a variety of research areas. Remarkably, one of the key information-theoretic quantities is given by the relative entropy, which quantifies how difficult is to tell apart two probability distributions, or even two quantum states. Such a quantity rests at the core of fields like metrology, quantum thermodynamics, quantum communication, and quantum information. Given this broadness of applications, it is desirable to understand how this quantity changes under a quantum process. By considering a general unitary channel, we establish a bound on the generalized relative entropies (Rényi and Tsallis) between the output and the input of the channel. As an application of our bounds, we derive a family of quantum speed limits based on relative entropies. Possible connections between this family with thermodynamics, quantum coherence, asymmetry, and single-shot information theory are briefly discussed.

Equilibration on average in quantum processes with finite temporal resolution.

We characterize the conditions under which a multitime quantum process with a finite temporal resolution can be approximately described by an equilibrium one. By providing a generalization of the notion of equilibration on average, where a system remains closed to a fixed equilibrium for most times, to one which can be operationally assessed at multiple times, we place an upper-bound on a new observable distinguishability measure comparing a multitime process with a finite temporal resolution against a fixed equilibrium one. While the same conditions on single-time equilibration, such as a large occupation of energy levels in the initial state remain necessary, we obtain genuine multitime contributions depending on the temporal resolution of the process and the amount of disturbance of the observer's operations on it.

Completely Positive Divisibility Does Not Mean Markovianity.

In the classical domain, it is well known that divisibility does not imply that a stochastic process is Markovian. However, for quantum processes, divisibility is often considered to be synonymous with Markovianity. We show that completely positive divisible quantum processes can still involve non-Markovian temporal correlations, that we then fully classify using the recently developed process tensor formalism, which generalizes the theory of stochastic processes to the quantum domain.

Quantum Markov Order.

We formally extend the notion of Markov order to open quantum processes by accounting for the instruments used to probe the system of interest at different times. Our description recovers the classical property in the appropriate limit: when the stochastic process is classical and the instruments are noninvasive, i.e., restricted to orthogonal, projective measurements. We then prove that there do not exist non-Markovian quantum processes that have finite Markov order with respect to all possible instruments; the same process exhibits distinct memory effects when probed by different instruments. This naturally leads to a relaxed definition of quantum Markov order with respect to specified instrument sequences. The memory effects captured by different choices of instruments vary dramatically, providing a rich landscape for future exploration.

Masking Quantum Information is Impossible.

Classical information encoded in composite quantum states can be completely hidden from the reduced subsystems and may be found only in the correlations. Can the same be true for quantum information? If quantum information is hidden from subsystems and spread over quantum correlation, we call it masking of quantum information. We show that while this may still be true for some restricted sets of nonorthogonal quantum states, it is not possible for arbitrary quantum states. This result suggests that quantum qubit commitment-a stronger version of the quantum bit commitment-is not possible in general. Our findings may have potential applications in secret sharing and future quantum communication protocols.

Emergence of a fluctuation relation for heat in nonequilibrium Landauer processes.

In a generalized framework for the Landauer erasure protocol, we study bounds on the heat dissipated in typical nonequilibrium quantum processes. In contrast to thermodynamic processes, quantum fluctuations are not suppressed in the nonequilibrium regime and cannot be ignored, making such processes difficult to understand and treat. Here we derive an emergent fluctuation relation that virtually guarantees the average heat produced to be dissipated into the reservoir either when the system or reservoir is large (or both) or when the temperature is high. The implication of our result is that for nonequilibrium processes, heat fluctuations away from its average value are suppressed independently of the underlying dynamics exponentially quickly in the dimension of the larger subsystem and linearly in the inverse temperature. We achieve these results by generalizing a concentration of measure relation for subsystem states to the case where the global state is mixed.

Tightening Quantum Speed Limits for Almost All States.

Conventional quantum speed limits perform poorly for mixed quantum states: They are generally not tight and often significantly underestimate the fastest possible evolution speed. To remedy this, for unitary driving, we derive two quantum speed limits that outperform the traditional bounds for almost all quantum states. Moreover, our bounds are significantly simpler to compute as well as experimentally more accessible. Our bounds have a clear geometric interpretation; they arise from the evaluation of the angle between generalized Bloch vectors.

Operational Markov Condition for Quantum Processes.

We derive a necessary and sufficient condition for a quantum process to be Markovian which coincides with the classical one in the relevant limit. Our condition unifies all previously known definitions for quantum Markov processes by accounting for all potentially detectable memory effects. We then derive a family of measures of non-Markovianity with clear operational interpretations, such as the size of the memory required to simulate a process or the experimental falsifiability of a Markovian hypothesis.

Enhancing the Charging Power of Quantum Batteries.

Can collective quantum effects make a difference in a meaningful thermodynamic operation? Focusing on energy storage and batteries, we demonstrate that quantum mechanics can lead to an enhancement in the amount of work deposited per unit time, i.e., the charging power, when N batteries are charged collectively. We first derive analytic upper bounds for the collective quantum advantage in charging power for two choices of constraints on the charging Hamiltonian. We then demonstrate that even in the absence of quantum entanglement this advantage can be extensive. For our main result, we provide an upper bound to the achievable quantum advantage when the interaction order is restricted; i.e., at most k batteries are interacting. This constitutes a fundamental limit on the advantage offered by quantum technologies over their classical counterparts.

Quantum thermodynamics of general quantum processes.

Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to arbitrary quantum states. We formulate an operational thermodynamics suitable for application to an open quantum system undergoing quantum evolution under a general quantum process by which we mean a completely positive and trace-preserving map. We derive an operational first law of thermodynamics for such processes and show consistency with the second law. We show that heat, from the first law, is positive when the input state of the map majorizes the output state. Moreover, the change in entropy is also positive for the same majorization condition. This makes a strong connection between the two operational laws of thermodynamics.

Nonequilibrium quantum Landauer principle.

Using the operational framework of completely positive, trace preserving operations and thermodynamic fluctuation relations, we derive a lower bound for the heat exchange in a Landauer erasure process on a quantum system. Our bound comes from a nonphenomenological derivation of the Landauer principle which holds for generic nonequilibrium dynamics. Furthermore, the bound depends on the nonunitality of dynamics, giving it a physical significance that differs from other derivations. We apply our framework to the model of a spin-1/2 system coupled to an interacting spin chain at finite temperature.

Measuring the heat exchange of a quantum process.

Very recently, interferometric methods have been proposed to measure the full statistics of work performed on a driven quantum system [Dorner et al., Phys. Rev. Lett. 110, 230601 (2013) and Mazzola et al., Phys. Rev. Lett. 110, 230602 (2013)]. The advantage of such schemes is that they replace the necessity to make projective measurements by performing phase estimation on an appropriately coupled ancilla qubit. These proposals are one possible route to the tangible experimental exploration of quantum thermodynamics, a subject which is the center of much current attention due to the current control of mesoscopic quantum systems. In this Rapid Communication we demonstrate that a modification of the phase estimation protocols can be used in order to measure the heat distribution of a quantum process. In addition, we demonstrate how our scheme maybe implemented using ion trap technology. Our scheme should pave the way for experimental explorations of the Landauer principle and hence the intricate energy to information conversion in mesoscopic quantum systems.

Classical to quantum in large-number limit.

We construct a quantumness witness following the work of Alicki & van Ryn (AvR). We reformulate the AvR test by defining it for quantum states rather than for observables. This allows us to identify the necessary quantities and resources to detect quantumness for any given system. The first quantity turns out to be the purity of the system. When applying the witness to a system with even moderate mixedness, the protocol is unable to reveal any quantumness. We then show that having many copies of the system leads the witness to reveal quantumness. This seems contrary to the Bohr correspondence, which asserts that, in the large-number limit, quantum systems become classical, whereas the witness shows quantumness when several non-quantum systems, as determined by the witness, are considered together. However, the resources required to detect the quantumness increase dramatically with the number of systems. We apply the quantumness witness for systems that are highly mixed but in the large-number limit that resembles nuclear magnetic resonance (NMR) systems. We make several conclusions about detecting quantumness in NMR-like systems.

Operational approach to open dynamics and quantifying initial correlations.

A central aim of physics is to describe the dynamics of physical systems. Schrödinger's equation does this for isolated quantum systems. Describing the time evolution of a quantum system that interacts with its environment, in its most general form, has proved to be difficult because the dynamics is dependent on the state of the environment and the correlations with it. For discrete processes, such as quantum gates or chemical reactions, quantum process tomography provides the complete description of the dynamics, provided that the initial states of the system and the environment are independent of each other. However, many physical systems are correlated with the environment at the beginning of the experiment. Here, we give a prescription of quantum process tomography that yields the complete description of the dynamics of the system even when the initial correlations are present. Surprisingly, our method also gives quantitative expressions for the initial correlation.

Unified view of quantum and classical correlations.

We discuss the problem of the separation of total correlations in a given quantum state into entanglement, dissonance, and classical correlations using the concept of relative entropy as a distance measure of correlations. This allows us to put all correlations on an equal footing. Entanglement and dissonance, whose definition is introduced here, jointly belong to what is known as quantum discord. Our methods are completely applicable for multipartite systems of arbitrary dimensions. We investigate additivity relations between different correlations and show that dissonance may be present in pure multipartite states.