RESUMO
Trityl chloride (TrCl) was efficiently used as a neutral catalyst for the multicomponent cyclization reaction of an aldehyde with dimedone and 6-amino-1,3-dimethyluracil for the preparation of pyrimido[4,5-b] quinolines in chloroform under reflux condition.
RESUMO
A nano TiO2/porous carbon nanocomposite (TiO2/PCN) was designed by the pyrolysis of peanut shells as bio waste with nano titanium dioxide. In the presented nanocomposite, titanium dioxide is properly placed in the positions and pores of the porous carbon, so that it acts as an optimal catalyst in the nanocomposite structure. The structure of TiO2/PCN was studied by various analyses such as Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray Spectroscopy (EDX), scanning electron microscopy (SEM), SEM coupled EDX (SEM mapping), transmission electron microscopy (TEM), X-ray fluorescence (XRF) and BET. TiO2/PCN was successfully tested as a nano catalyst for the preparation of some 4H-pyrimido[2,1-b]benzimidazoles in high yields (90-97%) and short reaction times (45-80 min).
RESUMO
DABCO was used as a basic and inexpensive catalyst for the synthesis of some new benzyloxy pyrimido[4,5-b]quinoline derivatives and 1,2,3- triazole-fused pyrimido[4,5-b]quinolines by the one-pot multi-component reaction of various benzyloxy benzaldehydes or benzylic -1,2,3-triazol-4-yl-methoxy benzaldehydes with dimedone and 6-amino-1,3-dimethyluracil at 90 °C under the solvent-free condition.
RESUMO
[This retracts the article DOI: 10.1039/C5RA02718G.].
RESUMO
Nano-[Fe3O4@SiO2/N-propyl-1-(thiophen-2-yl)ethanimine][ZnCl2] as a nano magnetite Schiff base complex was designed and fully characterized by various analyses such as Fourier transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential thermal gravimetric analysis (DTA), vibrating sample magnetometry (VSM), scanning electron microscopy (SEM), and transmission electron micrographs (TEM). The presented nano magnetite Schiff base complex was used as a heterogeneous catalyst for the synthesis of pyrimido[4,5-b]quinolones by the reaction of aryl aldehyde, dimedone and 6-amino-1,3-dimethyluracil in EtOH : H2O (7 : 3) as a solvent at 60 °C.
RESUMO
Water was magnetized via an external magnetic field and employed, for the first time, as a solvent in green preparation of 3,4-dihydropyrimidin-2(1H)-ones by the one-pot three-component condensation reaction using boric acid as a catalyst. Shorter reaction times, higher yields, and cleaner reaction profiles were some advantages of using magnetic water.
RESUMO
[This retracts the article DOI: 10.1039/D1RA03769B.].