Electrophoretic propulsion of matchstick-shaped magnetodielectric particles in the presence of external magnetic fields in a nematic liquid crystal.

Synthesis of micro- and nanoparticles of pre-designed shape and surface properties is an integral part of soft and synthetic active matter. We report synthesis of matchstick-shaped (MS) magnetodielectric particles and demonstrate their potential as active agents with field-controllable trajectories in a nematic liquid crystal (NLC). The MS particles with homeotropic anchoring in NLCs align either parallel or perpendicular to the director depending on the dipolar or quadrupolar director distortions. When subjected to transverse electric and magnetic fields, the particles experience electric and magnetic torques trying to align them in the respective field directions. At equilibrium, the long axis is tilted at an angle with respect to the director. The change in orientation alters the surrounding elastic distortion, which results in unbalanced electroosmotic flows. These flows provide the necessary impetus for propelling the particles in various directions with different velocities depending on their orientations.

Rheology and microstructure of thermoresponsive composite gels of hematite pseudocubes and Pluronic F127.

Stimuli-responsive materials or smart materials are designed materials whose properties can be changed significantly by applying external stimuli, such as stress, electric or magnetic fields, light, temperature, and pH. We report the linear and nonlinear rheological properties of thermoresponsive composite gels based on submicron-sized hematite pseudocube-shaped particles and a triblock copolymer Pluronic F127 (PF127). These novel composites form hard gels at an elevated temperature of 37 °C. For certain concentrations (<20 w/v. %) of hematite pseudocubes in 17.5 w/v. % of PF127, the gel strength is enhanced and the brittleness of the gels decreases. Higher concentrations (>20 w/v. %) of hematite pseudocubes in PF127 result in weaker and fragile gels. We develop an extensive rheological fingerprint using linear and nonlinear rheological studies. Adsorption of PF127 copolymer molecules on the hematite cube surfaces would further assist the formation of particle clusters along with magnetic interactions to be held effectively in the PF127 micellar network at elevated temperatures. The microscopic structure of these composite gels is visualized through a confocal microscope. Our experiments show that addition of hematite cubes up to 20 w/v. % does not change the rapid thermal gelation of PF127 solutions; hence, the hematite-PF127 composite, which transforms into a hard gel near human body temperature of 37 °C, could be suitable for use in smart drug delivery systems.