Robust charge carrier by Fe3O4 in Fe3O4/WO3 core-shell photocatalyst loaded on UiO-66(Ti) for urea photo-oxidation.

In this study, a facile four-step hydrothermal method was utilized to deposit a core-shell structure on UiO-66(Zr/Ti) nanoflake (NFs) as a visible-light-driven photocatalyst. The core was magnetic Fe3O4 which served as a charge carrier coated with WO3 shell. The as-prepared photocatalyst was characterized by XRD, VSM, BET, FTIR, FE-SEM, UV-Vis-DRS, and PL techniques which proved successful deposition of Fe3O4@WO3 core/shell particle on UiO-66(Zr/Ti)-NFs. The obtained photocatalyst was subsequently applied for urea photo-oxidation. This magnetically recoverable photocatalyst exhibited superior activity due to its desirable band alignment, high stability, and generation of the photo-induced charge carriers, as well as providing a high surface area with low mass transfer resistance. Fe3O4 core acted as charge-carrier to transport the photogenerated charges of UiO-66(Zr/Ti)-NFs (electron-donor) to WO3 charge-collectors for effective photoconversion. The central composite design was applied to design the experiments matrix in which flow rate, pH, irradiation time, catalyst mass, and initial urea concentration were considered as operational factors. The optimized condition was found by defining the desirability function. 90% degradation percentage was achieved at 550 mL/min solution flowrate, pH = 7, 120 min irradiation time, 0.22 g UiO-66(Zr)-NFs-Fe3O4@WO3, and 40 mg/L of the initial concentration of urea with the desirability value of 0.89. Such a superior photocatalytic activity of UiO-66-Fe3O4@WO3 can be ascribed to the reclamation of Fe3O4 as a low bandgap carrier, which accelerated the conveyance of electrons and followed surpassing charge separation. Our present findings open a new strategy to produce a wide range of core-shell heterogeneous catalysts to be applied in photoreactors scale-up.

UiO-66(Ti)-Fe3O4-WO3 photocatalyst for efficient ammonia degradation from wastewater into continuous flow-loop thin film slurry flat-plate photoreactor.

This work presents the characterization of novel synthesized UiO-66(Ti)-Fe3O4-WO3 magnetic photocatalyst and investigates their photocatalytic activity for the photodegradation of ammonia in a designed continuous flow-loop thin-film slurry flat-plate photoreactor (TFSR). Excellent ammonia degradation efficiency was achieved in the presence of the synthesized catalyst at ambient conditions using no more reactive oxidant species. Several independent variables involving catalyst mass, flowrate, pH, irradiation time and initial ammonia concentration as well as corresponding experiments were analyzed and design using the central composite design (CCD). The influence and significance of each parameter and their binary interactions were then evaluated by applying the analysis of variance. The ammonia degradation efficiency of 91.80 % with the desirability of 0.903 were obtained at optimum values of operational parameters including 550 mL/min,10, 0.125 g/L, 60 min and 30 mg/L for solution flowrate, pH, catalyst mass, irradiation time and initial ammonia concentration, respectively. Furthermore, the liquid phase products of ammonia degradation such as nitrate and nitrite ions were completely removed, and purified water was produced using the combination of reverse osmosis process and mixed resins beds. The photocatalyst mechanism study revealed that [Formula: see text] was the predominant reactive oxygen species in the ammonia photodegradation.

Chemical pretreatment of formaldehyde-containing effluents.

Lime was found in this study to be an efficient reagent to lower the concentration of formaldehyde in highly concentrated effluents down to and below the limits suitable for biological treatment systems. The results show that the reactions leading to formaldehyde elimination can be divided in two steps. In the first step, the reaction is relatively slow. More than two-thirds of the original formaldehyde disappears in the second step in a period as short as one-third of the first step. Such trend is followed in a temperature range of up to 92 degrees C. Economical considerations suggest maintaining the conditions of the process around the ambient temperature with no heat requirement. It was noticed that the efficiencies of formaldehyde removal better than 99% could be achievable even around room temperature. However, these efficiencies would result in quite a shorter period of time if the temperature was raised. The mathematical representation for the rate of formaldehyde removal was found to appear with an exponential behavior. It will be seen that the rate of formaldehyde removal is strongly dependent on temperature. The present survey proves that the formaldehyde-containing effluents can be treated in a pretreatment step by lime to maintain the formaldehyde concentration in a range that is safe for biological treatment systems.