Wearables and their applications for the rehabilitation of elderly people.

Globally, there has been a change in the population pyramid with an accelerated aging process. This increase requires a greater challenge to maintain autonomy and independence. Currently, there are technologies developed with a focus on health. This is given by the development of wearables and their areas of applications. As a general context, this technology is characterized by the research field in energy generation, the development of external devices for human control and monitoring, clothing, smart textiles, and electronics. The latter are classified into three areas of application: monitoring and safety; fabrics, perception, and physical activity; and rehabilitation. A literature review is conducted to identify the state-of-the-art in these fields within the last years. The progress in monitoring systems and intelligent textiles is evidenced, being able to highlight remote feedback, materials, and wearability both at a commercial and user level. A discussion is included to address the main challenges and future trends in the application of wearables in elderly people.

Photoactivated release of cargo from the cavity of polyelectrolyte capsules to the cytosol of cells.

Polyelectrolyte capsules with metal nanoparticles in their walls and fluorescently labeled polymers as cargo inside their cavity were prepared. Capsules were ingested by living cells with no uncontrolled release of the cargo upon the incorporation process. Photoinduced heating of the metal nanoparticles in the capsule walls lead to rupture of the capsule walls, and the polymeric cargo was released to the whole cytosol. Viability tests demonstrate that opening of capsules at moderate light intensities does not impair the cellular metabolism, whereas capsule opening at high light intensities ultimately leads to cell death.

Gold nanoparticles quench fluorescence by phase induced radiative rate suppression.

The fluorescence quantum yield of Cy5 molecules attached to gold nanoparticles via ssDNA spacers is measured for Cy5-nanoparticle distances between 2 and 16 nm. Different numbers of ssDNA per nanoparticle allow to fine-tune the distance. The change of the radiative and nonradiative molecular decay rates with distance is determined using time-resolved photoluminescence spectroscopy. Remarkably, the distance dependent quantum efficiency is almost exclusively governed by the radiative rate.