Design of a new low cost natural phosphate doped by nickel oxide nanoparticles for capacitive adsorption of reactive red 141 azo dye.

Nickel oxide doped natural phosphate (NP/NiO) nanoparticles were thermally synthesized for effective adsorption of Reactive Red 141 (RR141) as toxic dye model, characterization methods such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy combined with energy dispersive X-ray analysis(SEM-EDAX)and have been employed to identify the adsorbent. Surface area and pore size volume were determined by the Brunauer, Emmett and Teller (BET) method. Environmental factors such as pH, time of contact, initial RR141 concentration, the dose of adsorbent and solution temperature have been all put to the test to evaluate optimum adsorption activity. Thermal processing NP/NiO at 1% NiO doping percentage was effectual for exhibiting best adsorption behavior at an annealing temperature of 600 °C. Furthermore, batch experiments revealed significant adsorption activity reaching 96%. The maximal adsorption capacity was found to be 38.91 mg of RR 141 per 0.1 g of the adsorbent in only 40min of contact, at an initial colorant concentration of 20 mg L-1, pH 6 at ambient temperature and a volume of 100 ml. Langmuir isotherm model was more adequate to describe the adsorption process than the Freundlich model. The rate mechanism of the adsorption process was determined from the intraparticle diffusion model, Boyd plot revealed that the adsorption of the dye on the NP/NiO was mainly governed by film diffusion. Moreover, the dye adsorption was spontaneous and exothermic. The mechanism of adsorption may involve chemical adsorption through hydrogen bonding mechanism and electrostatic interactions between the dye molecules and the adsorbent. Thermal regeneration was feasible only for three cycles, the adsorbent also showed great potential for real textile wastewater treatment.

Dielectric and electric properties as a tool to investigate the coagulation mechanism during sludge treatment.

The analysis of the complex permittivity, electrical complex modulus and the hopping conductivity have been employed in order to investigate the impacts of calcium oxide during sludge treatment in textile such as coagulation process. In this context, impedance measurement was performed on five samples, including raw sludge and four compositions containing different amounts of calcium oxide: 2%, 3%, 4% and 5% (w/w). The dielectric spectra of each composition were described by the summation of a power law and a Cole-Cole relaxation model. The relaxation time and the magnitude of the dielectric relaxation obtained from the analysis of dielectric properties showed an increase up to 3% of these parameters with the addition of calcium oxide. Above this critical value, both parameters showed a very small change, suggesting that the aggregation became more stable. In addition, the evolution of the hopping conductivity reached a minimum value at this critical amount (3%). This evolution was well described by a double power law, which allowed us to estimate the optimal amount of the calcium oxide to achieve coagulation process. The analysis of the dielectric properties was found useful in monitoring aggregation processes that occur during the coagulation mechanism in textile sludge.

Rheological and electrical properties used to investigate the coagulation process during sludge treatment.

Analyses of rheological properties and electrical conductivity (σdc) at direct current have been employed in order to investigate the effects of calcium oxide on the coagulation process during sludge treatment in the textile industry. In this context, rheological and electrical measurements were performed on five samples - one that contained raw sludge and the other four that were prepared from the raw sludge and different amounts of calcium oxide: 2, 3, 4, 5% (w/w). Rheological behavior of these samples was analyzed using the Herschel-Bulkley modified model. The influence of calcium oxide content on the rheological parameters such as infinite viscosity, the yield stress, the consistency coefficient, and the consistency index, are presented and discussed. The impact of the calcium oxide content on pH and conductivity were also examined. Similar behaviors have been seen in the evolution of conductivity and infinite viscosity as a function of the calcium oxide content. These latter characteristics were modeled by an equation using two power laws. This equation was able to fit very well the evolution of electrical conductivity and also the viscosity versus the percentage of calcium oxide to predict the optimal amount of calcium oxide (3%) to achieve the coagulation step during sludge treatment.

Ibuprofen analysis in blood samples by palladium particles-impregnated sodium montmorillonite electrodes: Validation using high performance liquid chromatography.

The electrochemical detection of ibuprofen has been studied on Palladium-Montmorillonite (Mt) modified carbon paste electrode using differential pulse voltammetry. The optimization of the modifier preparation and the instrumental parameters was investigated. The results indicate that ibuprofen oxidation was favored in the presence of Pd-PdO particles. The quantitative determination of ibuprofen was statistically analyzed and validated using HPLC method. The detection and quantification limits, specificity and precision were found to be acceptable. Finally, the developed method was successfully applied for ibuprofen determination in human blood samples.