Field emission in vacuum resonant tunneling heterostructures with high current densities.

We analyse the steady-state thermal regime of a one-dimensional triode resonant tunnelling structure. The high currents generated by resonant tunnelling produce a large amount of heat that could damage the structure. Establishing the conditions under which it can operate at optimum efficiency is therefore a problem of great relevance for applications. The tunnel current is found via eigenvalues of the Schrödinger equation in quantum wells. By calculating the current generated in the device and using the energy conservation law in the electrodes, the temperature reached is obtained for different types of electrodes and the importance of heat conduction and thermal radiation is analysed. In the cases discussed, conduction is dominant. When the electrode material is copper, the temperature reached is similar to that of the thermostat for a wide range of electrode lengths, whereas when the cathode material is diamond-graphite and the anode material is copper, the temperature increases significantly as a function of length. The results obtained allow the temperature to be controlled for optimum performance of the field-emitting triode structures.

Band Gap Opening in Borophene/GaN and Borophene/ZnO Van der Waals Heterostructures Using Axial Deformation: First-Principles Study.

One of the topical problems of materials science is the production of van der Waals heterostructures with the desired properties. Borophene is considered to be among the promising 2D materials for the design of van der Waals heterostructures and their application in electronic nanodevices. In this paper, we considered new atomic configurations of van der Waals heterostructures for a potential application in nano- and optoelectronics: (1) a configuration based on buckled triangular borophene and gallium nitride (GaN) 2D monolayers; and (2) a configuration based on buckled triangular borophene and zinc oxide (ZnO) 2D monolayers. The influence of mechanical deformations on the electronic structure of borophene/GaN and borophene/ZnO van der Waals heterostructures are studied using the first-principles calculations based on density functional theory (DFT) within a double zeta plus polarization (DZP) basis set. Four types of deformation are considered: uniaxial (along the Y axis)/biaxial (along the X and Y axes) stretching and uniaxial (along the Y axis)/biaxial (along the X and Y axes) compression. The main objective of this study is to identify the most effective types of deformation from the standpoint of tuning the electronic properties of the material, namely the possibility of opening the energy gap in the band structure. For each case of deformation, the band structure and density of the electronic states (DOS) are calculated. It is found that the borophene/GaN heterostructure is more sensitive to axial compression while the borophene/ZnO heterostructure is more sensitive to axial stretching. The energy gap appears in the band structure of borophene/GaN heterostructure at uniaxial compression by 14% (gap size of 0.028 eV) and at biaxial compression by 4% (gap size of 0.018 eV). The energy gap appears in the band structure of a borophene/ZnO heterostructure at uniaxial stretching by 10% (gap size 0.063 eV) and at biaxial compression by 6% (0.012 eV). It is predicted that similar heterostructures with an emerging energy gap can be used for various nano- and optoelectronic applications, including Schottky barrier photodetectors.

Radiative heat transfer between two carbon nanotubes.

We analyze the radiative heat transfer between two parallel and infinitely long carbon nanotubes (CNTs). The radiative heat exchange is due to the difference between the Poynting vectors generated by the fluctuating currents when the CNTs are at different temperatures. The radiated and absorbed Poynting vectors are expressed in terms of the correlations of the electromagnetic fields obtained from the Green's function and the fluctuation-dissipation theorem for the current density. The analysis takes into account the scattering of the fields by the nanotubes. We show that the radiative heat transfer depends not only on the distance between nanotubes, but also on their chiralities and thus on their semiconducting or metallic nature, which would allow the design of nanostructures for optimal radiative heat exchange.

Characterization of Silver Nanowire Layers in the Terahertz Frequency Range.

Thin layers of silver nanowires are commonly studied for transparent electronics. However, reports of their terahertz (THz) properties are scarce. Here, we present the electrical and optical properties of thin silver nanowire layers with increasing densities at THz frequencies. We demonstrate that the absorbance, transmittance and reflectance of the metal nanowire layers in the frequency range of 0.2 THz to 1.3 THz is non-monotonic and depends on the nanowire dimensions and filling factor. We also present and validate a theoretical approach describing well the experimental results and allowing the fitting of the THz response of the nanowire layers by a Drude-Smith model of conductivity. Our results pave the way toward the application of silver nanowires as a prospective material for transparent and conductive coatings, and printable antennas operating in the terahertz range-significant for future wireless communication devices.

Casimir forces exerted by epsilon-near-zero hyperbolic materials.

The Casimir force exerted on a gold dipolar nanoparticle by a finite-thickness slab of the natural hyperbolic material namely, the ortorhombic crystalline modification of boron nitride, is investigated. The main contribution to the force originates from the TM-polarized waves, for frequencies at which the parallel and perpendicular components of the dielectric tensor reach minimal values. These frequencies differ from those corresponding to the Lorentzian resonances for the permittivity components. We show that when the slab is made of an isotropic epsilon-near-zero absorbing material the force on the nanoparticle is larger than that induced by a hyperbolic material, for similar values of the characteristic parameters. This fact makes these materials optimal in the use of Casimir's forces for nanotechnology applications.

Controlling the Electronic Properties of a Nanoporous Carbon Surface by Modifying the Pores with Alkali Metal Atoms.

We investigate a process of controlling the electronic properties of a surface of nanoporous carbon glass-like thin films when the surface pores are filled with potassium atoms. The presence of impurities on the surface in the form of chemically adsorbed hydrogen and oxygen atoms, and also in the form of hydroxyl (OH) groups, is taken into account. It is found that even in the presence of impurities, the work function of a carbon nanoporous glass-like film can be reduced by several tenths of an electron volt when the nanopores are filled with potassium atoms. At the same time, almost all potassium atoms are ionized, losing one electron, which passes to the carbon framework of the film. This is due to the nanosizes of the pores in which the electron clouds of the potassium atom interact maximally with the electrons of the carbon framework. As a result, this leads to an improvement in the electrical conductivity and an increase in the electron density at the Fermi level. Thus, we conclude that an increase in the number of nanosized pores on the film surface makes it possible to effectively modify it, providing an effective control of the electronic structure and emission properties.

New 2D graphene hybrid composites as an effective base element of optical nanodevices.

For the first time, we estimated perspectives for using a new 2D carbon nanotube (CNT)-graphene hybrid nanocomposite as a base element of a new generation o optical nanodevices. The 2D CNT-graphene hybrid nanocomposite was modelled by two graphene monolayers between which single-walled CNTs with different diameters were regularly arranged at different distances from each other. Spectra of the real and imaginary parts of the diagonal elements of the surface conductivity tensor for four topological models of the hybrid nanocomposite have been obtained. The absorption coefficient for p-polarized and s-polarized radiation was calculated for different topological models of the hybrid nanocomposite. It was found that the characteristic peaks with high intensity appear in the UV region at wavelengths from 150 to 350 nm (related to graphene) and in the optical range from 380 to 740 nm irrespective of the diameter of the tubes and the distance between them. For waves corresponding to the most intense peaks, the absorption coefficient as a function of the angle of incidence was calculated. It was shown that the optical properties of the hybrid nanocomposite were approximately equal for both metallic and semiconductor nanotubes.

Lateral-drag propulsion forces induced by anisotropy.

We predict the existence of lateral drag forces near the flat surface of an absorbing slab made of an anisotropic material. The forces originate from the fluctuations of the electromagnetic field, when the anisotropy axis of the material forms a certain angle with the surface. In this situation, the spatial spectra of the fluctuating electromagnetic fields becomes asymmetric, different for positive and negative transverse wave vectors components. Differently from the case of van der Waals interactions in which the forward-backward symmetry is broken due to the particle movement, in our case the lateral motion results merely from the anisotropy of the slab. This new effect, of particular significance in hyperbolic materials, could be used for the manipulation of nanoparticles.

Photonic jets from Babinet's cuboid structures in the reflection mode.

In this Letter, we demonstrate applicability of Babinet's principle of complementary diffractive structures for the formation of near-field photonic jets in the reflection mode. Structures, complementary to dielectric cuboids, are characterized with additional geometric and electromagnetic parameters compared to initial cuboids and, for this reason, offer more opportunities for the design of photonic jets with required properties. Babinet's structures allow control of such parameters of photonic jets as the focus length, width, length, maximal field intensity, and ellipticity of jets.

Total absorption in asymmetric hyperbolic media.

Finite-thickness slabs of hyperbolic media with tilted optical axes exhibit asymmetry properties for waves propagating upward and downward with respect to slab interfaces. Under certain conditions, asymmetric hyperbolic media acquire extreme permittivity parameters and the difference between upward and downward propagating waves becomes very large. Furthermore, both waves can be perfectly matched with the free space; such a feature makes possible the development of optically ultra thin perfect absorbers. The proposed approach is unified and allows the use of different -negative materials. Of particular interest is the asymmetric hyperbolic medium, made of silicon nanowires, since it can be directly applicable to solar cell systems.

Photonic band gap structure containing metamaterial with negative permittivity and permeability.

We have considered theoretically the main properties of layered periodical structures [one-dimensional photonic band gap (PBG) structures] that include layers of so-called backward-wave material (BW), whose both permittivity and permeability are negative. Each period consists of one layer of a usual material and one layer of a BW medium. Eigenwaves in infinite photonic band-gap structures and reflective and transmitting properties of finite-length structures are considered. Our analysis has shown that the usage of the negative material makes it possible to dramatically widen the band gap of one-dimensional layered PBG structures.