RESUMO
The five unimolecular HX and DX (X = F, Cl) elimination pathways of CD2ClCHFCl* were examined using a chemical activation technique; the molecules were generated with 92 kcal mol-1 of vibrational energy in a room-temperature bath gas by a combination of CD2Cl and CHFCl radicals. The total unimolecular rate constant was 9.7 × 107 s-1, and branching fractions for each channel were 0.52 (2,1-DCl), 0.29 (1,1-HCl), 0.10 (2,1-DF), 0.07 (1,1-HF), and 0.02 (1,2-HCl). Comparison of the individual experimental rate constants to calculated statistical rate constants gave threshold energies for each process as 63, 72, 66, 73, and 70 kcal mol-1, listed in the same order as the branching fractions. The 1,1-HCl and 1,1-HF reactions gave carbenes, CD2Cl(F)C: and CD2Cl(Cl)C:, respectively, as products, which have hydrogen-bonded complexes with HCl or HF in the exit channel of the potential energy surface. These carbenes have energy in excess of the threshold energy for D atom migration to give CDClâCDF and CDClâCDCl, and the subsequent cis-trans isomerization rates of the dihaloethenes can provide information about energy disposal by the 1,1-HX elimination reactions. Electronic structure calculations provide information for transition states of CD2ClCHFCl and hydrogen-bonded complexes of carbenes with HF and HCl. In addition, D atom migration in both free carbenes and in complexes formed by the carbene hydrogen bonding to HCl or HF is explored.
RESUMO
Chemically activated C2D5CHCl2 molecules were generated with 88 kcal mol-1 of vibrational energy by the recombination of C2D5 and CHCl2 radicals in a room temperature bath gas. The competing 2,1-DCl and 1,1-HCl unimolecular reactions were identified by the observation of the CD3CDâCHCl and CD3CDâCDCl products. The initial CD3CD2C-Cl carbene product from 1,1-HCl elimination rearranges to CD3CDâCDCl under the conditions of the experiments. The experimental rate constants were 2.7 × 107 and 0.47 × 107 s-1 for 2,1-DCl and 1,1-HCl elimination reactions, respectively, which corresponds to branching fractions of 0.84 and 0.16. The experimental rate constants were compared to calculated statistical rate constants to assign threshold energies of 54 and ≈66 kcal mol-1 for the 1,2-DCl and 1,1-HCl reactions, respectively. The statistical rate constants were obtained from models developed from electronic-structure calculations for the molecule and its transition states. The rate constant (5.3 × 107 s-1) for the unimolecular decomposition of CHCl2CHCl2 molecules formed with 82 kcal mol-1 of vibrational energy by the recombination of CHCl2 radicals also is reported. On the basis of the magnitude of the calculated rate constant, 1,1-HCl elimination must contribute less than 15% to the reaction; 1,2-HCl elimination is the major reaction and the threshold energy is 59 kcal mol-1. Calculations also were done to analyze previously published rate constants for chemically activated CD2ClCHCl2 molecules with 86 kcal mol-1 of energy to obtain a better overall description of the nature of the 1,1-HCl pathway for 1,1-dichloroalkanes. The interplay of the threshold energies for the 2,1-HCl and 1,1-HCl reactions and the available energy determines the product branching fractions for individual molecules. The unusual nature of the transition state for 1,1-HCl elimination is discussed.
RESUMO
Vibrationally excited CD3CHFCl molecules with 96 kcal mol(-1) of energy were generated by the recombination of CD3 and CHFCl radicals in a room-temperature bath gas. The four competing unimolecular decomposition reactions, namely, 1,1-HCl and 1,2-DCl elimination and 1,1-HF and 1,2-DF elimination, were observed, and the individual rate constants were measured. The product branching fractions are 0.60, 0.27, 0.09, and 0.04 for 1,2-DCl, 1,1-HCl, 1,2-DF, and 1,1-HF elimination, respectively. Electronic structure calculations were used to define models of the four transition states. The statistical rate constants calculated from these models were compared to the experimental rate constants. The assigned threshold energies with ±2 kcal mol(-1) uncertainty are 60, 72, 65, and 74 kcal mol(-1) for the 1,2-DCl, 1,1-HCl, 1,2-DF, and 1,1-HF reactions, respectively. The loose structure of the 1,1-HX transition states, which is exemplified by the order of magnitude larger pre-exponential factor relative to the 1,2-HX elimination reactions, compensates for the high threshold energy; thus, the 1,1-HX elimination reaction rates can compete with the 1,2-HX elimination reactions for high levels of vibrational excitation in CD3CHFCl. The 1,1-HCl and 1,1-HF reactions are observed via the CD2âCDF and CD2âCDCl products formed from isomerization of the CD3CF and CD3CCl carbenes. These D-atom migration reactions are discussed, and the possibility of tunneling is evaluated. The transition states developed from the 1,1-HCl and 1,1-HF reactions of CD3CHFCl are compared to models for the HCl and HF elimination reactions of CHF2Cl, CHFCl2, and CH2FCl.
