A Holistic Approach to Assessment of Population Exposure to Radiation: Challenges and Initiatives of a Regulatory Authority.

A regulatory authority for radiation safety should continuously evaluate and improve the national safety framework, in line with current requirements and standards. In this context, the Greek Atomic Energy Commission initiated a series of concerted actions. The radiation dose to the population due to public and medical exposures was assessed. The assessment of dose due to public exposure was based on measurements of radon concentrations in dwellings, radionuclide concentrations in environmental samples, and air dose rates; the assessment of dose due to medical exposure was based on dose measurements for typical examinations or procedures and data on their frequency. The mean effective dose to a member of the population was found to be 4.5 mSv (1.8 mSv and 2.7 mSv from medical and public exposures, respectively). Regarding occupational exposure, aircrew dose assessment, eye lens monitoring, and the national dose registry were significantly improved. With respect to artificial tanning (sun beds), the ultraviolet radiation produced was assessed and the practices followed were observed. Results demonstrated exceedance of the 0.3 W m erythema effective irradiance limit set in European Union standards by 63.5% of the sun beds measured, along with general noncompliance with standards. An overarching activity was the upgrade of the Greek Atomic Energy Commission information system in order to collect and disseminate radiation data electronically, launch a networking strategy for interaction with stakeholders, and facilitate the process of regulatory control. In response to the above findings, regulatory actions have been initiated.

DETERMINATION OF THE INTERNAL EXPOSURE OF GREEK CITIZENS RETURNING FROM JAPAN IMMEDIATELY AFTER THE FUKUSHIMA ACCIDENT.

Following the nuclear accident at the Fukushima Daiichi Nuclear Power Plant on 11 March 2011, during the period 17 March to 25 October 2011, a total of 22 Greek citizens were measured after their return to Greece. Artificial radionuclides were detected in 5 of the 22 measured individuals by whole body counter measurements conducted 10 and 11 d after the commencement of the accident. Of the 5 contaminated individuals, 3 were adults and 2 children, aged 9 and 5 y, who stayed for a single day in Tokyo. Dose calculations were performed assuming that the sole exposure pathway was through inhalation that occurred on 14 March, according to the information provided by them, using the detected artificial radionuclides in the spectra ((134)Cs, (137)Cs, (131)I). The estimated total committed effective doses calculated were found to be in the range of 9-280 µSv.

Knowledge and general consideration about Pap test screening among women from Finland and Greece.

It seems that lack of regular Pap smear screening is a risk factor for cervical cancer. Since women started having Pap smears the number of deaths from cervical cancer has dropped dramatically. The purpose of this study was to investigate the knowledge of women about the essential and basic parameters related to the Pap test in the general population of two European countries: Finland and Greece. The same percentages (> 50%) of women in Athens and Helsinki had good knowledge of the Pap test. Comparing country populations, greater numbers of Finnish women had a better level of Pap test knowledge. Additionally, older women in Finland were more educated and informed about the usage of Pap testing due to the good health service information in this country.

Photochemical treatment of 2-chlorophenol aqueous solutions using ultraviolet radiation, hydrogen peroxide and photo-Fenton reaction.

In the present work, the photochemical oxidation of 2-chlorophenol aqueous solutions in a batch recycle photochemical reactor using ultraviolet irradiation and hydrogen peroxide was studied. Specifically, the effect of hydrogen peroxide initial concentration (0-10316 mg L(-1)) and 2-chlorophenol initial concentration (150-3000 mg L(-1)) was examined. The process was attended via total organic carbon (TOC), 2-chlorophenol, chloride ion, acetic acid, formic acid and pH measurements. The conversion of 2-chlorophenol observed was always much higher than the corresponding total organic carbon removal, whereas the increase in hydrogen peroxide amount in the solution led to higher values of 2-chlorophenol conversion and total organic carbon removal. Finally, the photo-Fenton reaction was applied to the oxidation of 2-chlorophenol, leading to a higher degree of mineralization of the parent compound.

Photochemical degradation of 1,3-dichloro-2-propanol aqueous solutions.

The photochemical oxidation of 1,3-dichloro-2-propanol (1,3-DCP) was studied by following the target compound degradation, the total carbon removal rate by a total organic carbon (TOC) analyzer and by identifying the oxidation products by gas chromatography-mass spectrometry (GC-MS). The reaction was performed in a batch recycle reactor, at room temperature, using UV radiation provided by a low pressure 12W Hg lamp and H(2)O(2) as oxidant. Chloride ions, formic, acetic and chloroacetic acid were measured by ion chromatography. Apart from the chloride ions and the organic acids, the presence of 1,3-dichloro-2-propanone and chloroacetyl chloride was also detected and a possible pathway is proposed for the degradation of the parent compound. Complete degradation of 1,3-dichloro-2-propanol was achieved and the TOC removal reached as much as 80% at the end of the reaction time. The effect of the initial concentration of hydrogen peroxide was investigated and it was established that higher concentrations of H(2)O(2) slow down the reaction rate. Finally, the effect of the initial concentration of 1,3-DCP was investigated.

Photocatalytical degradation of 1,3-dichloro-2-propanol aqueous solutions by using an immobilized TiO2 photoreactor.

The photocatalytic oxidation of 1,3-dichloro-2-propanol (1,3-DCP) was studied by following the target compound degradation, the total organic carbon removal rate and by identifying the oxidation products. The reaction was performed in a batch recycle reactor, at room temperature, using UV radiation, H2O2 as oxidant, and immobilized TiO2 as catalyst. 1,3-Dichloro-2-propanone, chloroacetyl-chloride, chloroacetic acid, formic and acetic acid were detected as reaction intermediates and a possible pathway for the oxidation of 1,3-dichloro-2-propanol is proposed. The effect of the oxidative agent's initial concentration was investigated and it was established that higher concentrations of H2O2 slow down the reaction rate. The investigation of the effect of the 1,3-DCP initial concentration showed no influence on the degradation process. The carbon and chloride ion mass balance calculations confirmed the fact that chlorinated intermediates are formed and that they degrade with a lower rate than 1,3-DCP.

Photo-fenton assisted reaction of dimethoate in aqueous solutions.

The photo-Fenton reaction of an organophosphorus insecticide, dimethoate (O,O-dimethyl methylcarbamoylmethyl phosphorodithioate), was studied by following the identification and determination of the decomposition products and the total carbon removal rate. The reactions were performed in a batch recycle reactor, at room temperature, using UV radiation, H2O2 as oxidant, and FeCl3 x 6H2O as catalyst. The oxidation results were determined with a total organic carbon (TOC) analyzer and ion chromatography. The presence of reaction products was identified by gas chromatography-mass spectrometry (GC-MS). Apart from the sulfate, phosphate, and ammonium ions, the presence of dimethyl phosphite, N-methyl-acetamide, and formic acid was also detected. Excess of H2O2 concentration did not influence the reaction rate. The expression for the total carbon removal was assessed and the TOC removal rate constants were calculated.