Effects of Limiting the Number of Different Cross-Sections Used in Statically Loaded Truss Sizing and Shape Optimization.

This research aims to show the effects of adding cardinality constraints to limit the number of different cross-sections used in simultaneous sizing and shape optimization of truss structures. The optimal solutions for sizing and shape optimized trusses result in a generally high, and impractical, number of different cross-sections being used. This paper presents the influence of constraining the number of different cross-sections used on the optimal results to bring the scientific results closer to the applicable results. The savings achieved using the cardinality constraint are expected to manifest in more than just the minimization of weight but in all the other aspects of truss construction, such as labor, assembly time, total weld length, surface area to be treated, transport, logistics, and so on. It is expected that the optimal weight of the structures would be greater than when not using this constraint; however, it would still be below conventionally sized structures and have the added benefits derived from the simplicity and elegance of the solution. The results of standard test examples for each different cardinality constraint value are shown and compared to the same examples using only a single cross-section on all bars and the overall optimal solution, which does not have the cardinality constraint. An additional comparison is made with results of just the sizing optimization from previously published research where authors first used the same cardinality constraint.

Influence of TiN Coating on the Drawing Force and Friction Coefficient in the Deep Drawing Process of AlMg4.5Mn0.7 Thin Sheets.

The influence of various process parameters on the deep drawing process is a current research topic in sheet metal forming technology. Starting from the application of the previously constructed original testing device, an original tribological model was developed based on the process of sheet metal strip sliding between flat contact surfaces under variable pressures. A complex experiment was executed using an Al alloy sheet, tool contact surfaces of different roughness, two types of lubricants and variable contact pressures. The procedure included analytically pre-defined contact pressure functions based on which, for each of the mentioned conditions, the dependencies of the drawing forces and friction coefficients were obtained. The pressure in function P1 constantly decreased from a high initial value until the minimum, while in function P3 the pressure increased until the minimum value at the halfway point of the stroke, after which it increased up to the initial value. On the other hand, the pressure in function P2 constantly increased from the initial minimum value until the maximum value, while in function P4 the pressure increased until reaching the maximum value at the halfway point of the stroke, after which it decreased to the minimum value. This enabled the determination of the influence of tribological factors on the process parameters of intensity of traction (deformation force) and coefficient of friction. The pressure functions starting with decreasing trends produced higher values for the traction forces and the friction coefficient. In addition, it was established that the roughness of the contact surfaces of the tool, especially those with titanium nitride coating, has a significant influence on the process parameters. For surfaces of lower roughness (polished), a tendency of the Al thin sheet to form a glued-on layer was noticed. This was especially prominent for lubrication with MoS2-based grease under conditions of high contact pressure (functions P1 and P4 at the beginning of the contact).

Analysis of Filler Metals Influence on Quality of Hard-Faced Surfaces of Gears Based on Tests in Experimental and Operating Conditions.

Hard-facing as a type of the coating depositing is increasingly used today. Physical-chemical-metallurgical characteristics of contact layers in tribo-mechanical systems depend on the operating conditions and the conditions under which the work surfaces were created. That is the reason the influence of the processing procedures and regime, used in the contact surfaces formation, on development of the wear process of contact elements, is being considered ever more. To determine the influence of the hard-facing technology on characteristics of the gears' working surfaces, the experimental investigations were performed on samples hard-faced on the steel for cementation, by varying the filler metals (FM) and the hard-facing regimes. The samples tested were hard-faced by five "hard" and three "soft" filler metals. Experimental investigations included measuring the hard-faced layers' hardness and determination of their microstructure, as well as the wear resistance in the laboratory conditions, on tribometer and on a specially designed device for tests in the real operating conditions of gears. The wear intensity was monitored by the wear trace's width in the laboratory conditions and by the share of the teeth surfaces affected by the destructive pitting in the operating conditions. The results obtained were compared to results of the base metal (BM) tests, which provided the certain conclusions on which filler metal and which welding procedure are the optimal ones for regeneration of the worn teeth surfaces.

Weldability Assessment of Various Steels by Hard-Facing.

Two aspects of various steels' weldability are considered in this article. The theoretical part presents general concepts related to steel's weldability and the application of the most important methods for its determination. In the experimental section, results of the hard-facing application to several samples are presented, and consist of hardness measurements in the different zones of the welded samples, with the evaluation of those zones' microstructures. The tested materials included two carbon steels and two alloyed steels, with hard-facing layers deposited by various filler metals. Experimental results were compared to results obtained by calculations; using both, authors were able to conclude which combination of filler metal, welding procedure and, if necessary, heat treatment, would achieve the optimal improvement of weldability in welding/hard-facing of each of the tested base metals.

Exploitation Characteristics of Teeth Flanks of Gears Regenerated by Three Hard-Facing Procedures.

Numerous phenomena that occur during the process of machine parts' regeneration have a significant impact on the loss of their working ability. Therefore, the properties of the working surfaces of the teeth flanks of repaired gears were analyzed in this research. The hereditary properties of the gear teeth are expressed by the interdependence of their geometric and physical-mechanical-metallurgical parameters created during the technological operations of regeneration of worn teeth by welding/hard-facing. The hard-facing was executed with three filler metal types, namely: combination Inox 18/8/6 + EDur 600, Castolin 2 and UTP 670. The tested properties included geometrical accuracy, microstructure and microhardness. Evaluation of the executed regeneration procedures was done by comparing the mentioned parameters of the regenerated gears and the new ones. The tested gears were not withdrawn from production due to damage, but they were newly manufactured and intentionally damaged gears, made of the same materials, subjected to the same manufacturing process. In this way, all influences except for the considered filler metal type were eliminated. Based on results of the conducted experiments, it was possible to establish the influence of the filler metal type on the surface characteristics of the regenerated gears' teeth flanks.

Analysis of the Welding Type and Filler Metal Influence on Performance of a Regenerated Gear.

This paper presents the results of voluminous experimental investigations conducted to analyze the influence of the welding procedure on the performance of regenerated gears. Cylindrical spur gears were tested, both newly manufactured and regenerated, in two fundamentally different ways: by hard facing (surfacing) with the "hard" filler metal (DUR 600-IG) and with the "soft" filler metal (EVB2CrMo) with subsequent cementation and quenching. The regeneration procedures were defined and executed, while, subsequently, the microstructure and microhardness of the hard-faced layers were established and measured, followed by checking the durability of the hard-faced teeth flanks. Finally, techno-economic analysis was performed to establish the rationality of the conducted regenerations, i.e., the costs of regenerated and newly manufactured teeth were compared. Based on the results of the conducted investigations, it was possible to establish the influence of the welding type on the performance characteristics (primarily the service life) of the regenerated gears. For individual reparatory hard facing, the procedure with the "hard" filler metal exhibited better characteristics, while for batch reparation of numerous damaged gears, the reparation with the "soft" filler metal, followed by cementation and heat treatment, might be more convenient.

Spot-Weld Service Life Estimate Based on Application of the Interfacial Crack Concept.

In the automotive industry, spot-welding is the most common method of joining components. Thus, determining the service life of spot-welds is of great importance in designing assemblies or structures. It is well-known that lately there has been a trend in the industry toward reducing the fuel consumption and harmful gasses emissions, as well as the weight of structures with the application of the lightweight materials, like aluminum alloys. In this paper, research is presented on the behavior of a spot-weld between the plates made of the two dissimilar materials-aluminum alloy and steel. In addition, the influence of the plates' thickness and the weld nugget's diameter on welds' service life is presented. In this analysis, a concept of the interface crack between the two linear elastic materials was applied. Obtained results show that the plates' thickness and the nugget's size, as well as the working load, impose significant influences on the service life of a spot-weld between the two dissimilar materials.

Analysis of Selected Properties of Welded Joints of the HSLA Steels.

This paper presents research of the impact toughness and hardness distribution in specific zones of a 'single V'butt multiple-pass welded joints of the high-strength low-alloyed steels. Obtained values of the impact toughness are analyzed in correlation with a microstructure in specific zones of the welded joint, together with the micro hardness distribution found in the related zones. Based on the carried out analysis and results obtained in experiments, the applied technology of welding was evaluated. The original conclusions on influence of the selected welding procedure manual metal arc (MMA) for the root passes and metal active gas (MAG) for the filling and covering passes) on impact toughness of the high-strength low-alloyed steels are drawn. The paper also presents discussion on the valid standards and recommendations related to welding of those steels, from the aspect of applications in design of steel welded constructions.

Monitoring the toxic effects of Pb, Cd and Cu on hematological parameters of Wistar rats and potential protective role of lipoic acid and glutathione.

Heavy metal pollution is a serious environmental and health problem. The negative effects of heavy metals that can enter human body can be reduced by the addition of some supplements. In this study, the effects of lead (Pb), cadmium (Cd) and copper (Cu) on the hematological parameters in Wistar rats in the absence and presence of lipoic acid and glutathione were analyzed. Pb, Cd and Cu intoxication significantly affected the hematological parameters of treated animals. The main effects in the case of Pb and Cd intoxication were decreased values of erythrocytes, hemoglobin and hematocrit (up to 30% and 20% for these two metals, respectively) compared with the control group. Cu intoxication caused decrease in hematocrit, thrombocytes, mean cell volume values (c.a. 15%) and slight decrease in the erythrocyte number, while the value of hemoglobin increased (c.a. 7%). The treatment with lipoic acid and glutathione reduced the toxic effects of these metals in all cases.

Protective effects of glutathione and lipoic acid against cadmium-induced oxidative stress in rat's kidney.

Cadmium is a widespread, toxic industrial pollutant. The proximal tubule of the mammalian kidney is a major target of Cd-induced toxicity. We analyzed the effects of cadmium exposure on the model system of experimental animals, the thiobarbituric acid (TBA)-reactive substance (TBARS) level, and the activity of xanthine oxidase (XO) and catalase in kidney of rats, with and without glutathione and lipoic acid (LA). The experimental animals were classified into six groups, regarding cadmium, glutathione, and LA intake. The concentration of TBARSs in the homogenate was determined by spectrophotometric method according to Nabavi et al. The specific activity of XO was determined spectrophotometrically by the method of Aygul et al. Catalase activity in tissues was determined by spectrophotometric method according to Nabavi et al. The increased level of TBARS and the increased activity of XO in kidney tissue in cadmium poisoning are statistically significant compared to control (p < 0.001). Glutathione and LA applied along with cadmium lowered TBARS concentration and reduced XO activity (p < 0.001). Catalase activity in the kidney tissue was increased in the group, which was administered cadmium (p < 0.001). In conclusion, glutathione and LA, as physiological antioxidants applied with cadmium, have reduced the level of lipid peroxide and the activity of XO, and can be used as protectors in conditions of cadmium poisoning.

The release of zinc, copper, lead, and cadmium from the mineral tissue of teeth under the influence of soft drinks and sour-tasting food.

This study was carried out with the aim of identifying the effects of consuming sour-tasting food and refreshing drinks on the bone tissue of teeth among teenagers. The cumulative effect of a year-long exposure of teeth to the erosive effects of a model system of acidic media (citric acid, lactic acid, acetic acid, apple vinegar, lemonade, the soft drink Sprite, mineral water) was studied. The effects were registered based on the amount of released biometal ions, of zinc and copper, and toxic lead, during a period of 24 hr at room temperature, using the potentiometric stripping analysis. In the given time span, amounts ranging from 75 to 750 ppm of zinc, from 0.1 to 1.0 ppm of copper, and up to 1.5 ppm of lead were released from the dental matrix, while the release of cadmium was below the level of detection. The changes to the mineral structure of the bone tissue were monitored by the Fourier's transformation infrared spectroscopy and scanning electron microscopy technique. These studies have shown that under the influence of an acidic medium significant erosion to the tooth enamel ensues and that the eroded surfaces had a radius of 1-5 µm.

Synthesis, physicochemical and spectroscopic characterization of copper(II)-polysaccharide pullulan complexes by UV-vis, ATR-FTIR, and EPR.

Bioactive copper(II) complexes with polysaccharides, like pullulan and dextran, are important in both veterinary and human medicine for the treatment of hypochromic microcitary anemia and hypocupremia. In aqueous alkaline solutions, Cu(II) ion forms complexes with the exopolysaccharide pullulan and its reduced low-molecular derivative. The metal content and the solution composition depend on pH, temperature, and time of the reaction. The complexing process begins in a weak alkali solution (pH >7) and involves OH groups of pullulan monomer (glucopyranose) units. Complexes of Cu(II) ion with reduced low-molecular pullulan (RLMP, M(w) 6000 g mol(-1)) were synthesized in water solutions, at the boiling temperature and at different pH values ranging from 7.5 to 12. The Cu(II) complex formation with RLMP was analyzed by UV-vis spectrophotometry and other physicochemical methods. Spectroscopic characterizations (ATR-FTIR, FT-IRIS, and EPR) and spectra-structure correlation of Cu(II)-RLMP complexes were also carried out.

Copper release from dental prosthetic crowns, dental materials, and human teeth into acetic acid.

This article examines the dilution of the ion of copper from human teeth and dental prosthetic crowns in 4% CH(3)COOH during a period of 24 hr at room temperature. The content of the diluted copper in an acetate extract, as well as the overall content of this metal in the samples, was determined by means of a potentiometric stripping analysis. The comparative measurements were carried out using the furnace atomic absorption spectrophotometry technique, which is recommended by the International Standards (ISO 6872:2008; ISO 24234:2004) as a method for quality control of dental-prosthetic material (dental ceramic, metal restorative materials, dental amalgams) in the process of checking for heavy metals. During a 24-hr period in 4% CH(3)COOH at a temperature of 25 degrees C, approximately 72% of the overall copper was released from the tooth. The percentage of the released copper from baby teeth is higher, ranging from 88 to 92%, which is probably a consequence of the bone tissue being in development, its infirmity, and inadequate stability. On these conditions, approximately 72% of the overall copper was released from the dental-ceramic prosthetic crowns.

Potentiometric stripping analysis of zinc and copper in human teeth and dental materials.

Potentiometric stripping analysis (PSA) with oxygen as the oxidant has been used to determine soluble zinc and copper levels in exfoliated human teeth (all of which required extraction for orthodontic reasons) and commercial dental materials. The soluble zinc and copper contents of teeth were slightly below the zinc and copper contents in whole teeth reported by other researchers, except in the case of tooth with removed amalgam filling. Soluble zinc and copper concentrations of the dental materials and metal ceramic crowns were 0.50-6.30, and of 2.00-4.30 microg/g, respectively. The results of this work suggest that PSA may be a good method for zinc and copper leaching studies during the investigation of dental prosthetic materials' biocompatibility. Corrosive action of acidic media as evidenced by SEM micrographs caused the leaching of metal ions from teeth.

Spectroscopic and potentiometric studies on derivatized natural humic acid.

Isolated soil humic acid (HA) and commercial Aldrich HA were derivatized by esterification with methanol-thionyl and acetylation with acetic anhidride, in order to obtain derivatives with selectively blocked carboxyl and phenol groups, respectively. Results obtained by FT-IR spectroscopy and potentiometry show that the methanol-thionyl procedure is a selective, specific and efficient route for blocking carboxyl groups. The good correlation between results obtained by direct potentiometry after HA esterification and by classical calcium-acetate and baryta exchange methods suggests that esterification followed by direct acid-base potentiometric titration can be used as a method for the estimation of carboxyl and phenol group contents. Phenol groups can not be specifically identified by the acetylation method, due to the low selectivity of the acetylation method. The average values of apparent and intrinsic pK of underivatized and derivatized HAs confirm decrease in ionizable groups content due to derivatization and their values are related to the different chemical structures of the acids.