Nanobubbles produced by nanopores to probe gas-liquid mass transfer characteristics.

HYPOTHESIS: This study tested the hypothesis of how the nanopore size of membranes and how the surface charge of nanobubbles responds to its pinch-off from the nanopore. This study also tested the hypothesis that nanobubbles that remain in solution after production may increase the dissolved oxygen content in water. EXPERIMENTS: The effect of membrane pore size, hydrodynamic conditions (gas and liquid flow rates), and physicochemical parameters (pH and temperature) on volumetric mass transfer coefficient (kLa) for oxygen nanobubbles formed by the nanopore diffusion technique was investigated. This study experimentally determined the kLa by carefully removing the dissolved oxygen by nitrogen purging from nanobubble suspension to examine the sole contribution of nanobubble dissolution in water to the reaeration. RESULTS: Scaling estimates indicate that the nanobubble pinch-off radius and nanopore radius have a power-law correlation and that nanobubble size declines with the nanopore size. This is in line with our experimental results. The surface charge of nanobubbles delays its pinch-off at the gas-liquid interface. Nanobubbles offered 3-4 times higher kLa than microbubbles. Standard oxygen transfer efficiency in water was found to be 78%, significantly higher than that in microbubbles. However, dissolving stable nanobubbles in water does not considerably increase dissolved oxygen levels.

Electrochemically reactive colloidal nanobubbles by water splitting.

HYPOTHESIS: The existing literature reports have conflicting views on reactive oxygen species (ROS) generation by bulk nanobubbles. Consequently, we propose the hypothesis that (i) ROS may be generated during the process of nanobubble generation through water splitting, and (ii) bulk nanobubbles possess electrochemical reactivity, which could potentially lead to continuous ROS generation even after the cessation of nanobubble production. EXPERIMENTS: A comprehensive set of experiments was conducted to generate nanobubbles in pure water using the water-splitting method. The primary aims of this study are as follows: (i) nanobubble generation by electrolysis and its characterization; (ii) to provide conclusive evidence that the nano-entities are indeed nanobubbles; (iii) to quantify the production of reactive oxygen species during the process of nanobubble generation and (iv) to establish evidence for the presence of electrochemically reactive nanobubbles. The findings of our experiment suggest that bulk nanobubbles possess the ability to generate reactive oxygen species (ROS) during the process of nanobubble nucleation. Additionally, our results indicate that bulk nanobubbles are electrochemically reactive after the cessation of nanobubble production. The electron spin spectroscopy (ESR) response and degradation of the dye compound over time confirm the electrochemical reactivity of bulk nanobubbles.

Understanding the Role of Surface Charge on Nanobubble Capillary Bridging during Particle-Particle Interaction.

The interactions between particles due to long-range hydrophobic forces have been extensively investigated. The hydrophobic force is likely a capillary force that arises from the formation of capillary bridges due to the merging of nanobubbles. In this study, we aim to investigate the impact of the nanobubble surface charge on the capillary bridge and, subsequently, the interaction between particles. The surface charge of the nanobubbles was altered in the presence of various surfactants (cationic, anionic, and nonionic) and salts (mono-, di-, and trivalent). The particle-particle interaction was quantified by measuring the aggregate size of the hydrophobized glass particles. Both experimental and theoretical findings confirm that the interaction between particles was enhanced when the surface potential of the nanobubble was around the neutral regime. This is probably because, when the surface potential was close to neutral, the interaction between two surface-deposited nanobubbles dominated over electrostatic repulsion, which was more conducive to the formation of the nanobubble capillary bridge. The estimation of the constrained Gibbs potential also showed the capillary bridge to be more stable when surface charge density along the bridge gas-liquid interface was minimal.

Do Nanobubbles Exist in Pure Alcohol?

The existence of nanobubbles in pure water has been extensively debated in recent years, and it is speculated that nanobubbles may be ion-stabilized. However, nanobubbles in the alcohol-water mixture and pure alcohols are still controversial due to the lack of ions present in the alcohol system. This work tested the hypothesis that stable nanobubbles exist in pure alcohol. The ultrasound and oscillatory pressure fields are used to generate nanobubbles in pure alcohol. The size distribution, concentration, diameter, and scattering intensity of the nanobubbles were measured by nanoparticle tracking analysis. The light scattering method measures the zeta potential. The Mie scattering theory and electromagnetic wave simulation are utilized to estimate the refractive index (RI) of nanobubbles from the experimentally measured scattering light intensity. The average RI of the nanobubbles in pure alcohols produced by ultrasound and oscillating pressure fields was estimated to be 1.17 ± 0.03. Degassing the nanobubble sample reduces its concentration and increases its size. The average zeta potential of the nanobubbles in pure alcohol was measured to be -5 ± 0.9 mV. The mechanical stability model, which depends on force balance around a single nanobubble, also predicts the presence of nanobubbles in pure alcohol. The nanobubbles in higher-order alcohols were found to be marginally colloidally stable. In summary, both experimental and theoretical results suggest the existence of nanobubbles in pure alcohol.

On Nanobubble Dynamics under an Oscillating Pressure Field during Salting-out Effects and Its DLVO Potential.

We have investigated the origin, stability, and nanobubble dynamics under an oscillating pressure field followed by the salting-out effects. The higher solubility ratio (salting-out parameter) of the dissolved gases and pure solvent nucleates nanobubbles during the salting-out effect, and the oscillating pressure field enhances the nanobubble density further as solubility varies linearly with gas pressure by Henry's law. A novel method for refractive index estimation is developed to differentiate nanobubbles and nanoparticles based on the scattering intensity of light. The electromagnetic wave equations have been numerically solved and compared with the Mie scattering theory. The scattering cross-section of the nanobubbles was estimated to be smaller than the nanoparticles. The DLVO potentials of the nanobubbles predict the stable colloidal system. The zeta potential of nanobubbles varied by generating nanobubbles in different salt solutions, and it is characterized by particle tracking, dynamic light scattering, and cryo-TEM. The size of nanobubbles in salt solutions was reported to be higher than that in pure water. The novel mechanical stability model is proposed by considering both ionic cloud and electrostatic pressure at the charged interface. The ionic cloud pressure is derived by electric flux balance, and it is found to be twice the electrostatic pressure. The mechanical stability model for a single nanobubble predicts the existence of stable nanobubbles in the stability map.

Augmenting the Leidenfrost Temperature of Droplets via Nanobubble Dispersion.

Droplets may rebound/levitate when deposited over a hot substrate (beyond a critical temperature) due to the formation of a stable vapor microcushion between the droplet and the substrate. This is known as the Leidenfrost phenomenon. In this article, we experimentally allow droplets to impact the hot surface with a certain velocity, and the temperature at which droplets show the onset of rebound with minimal spraying is known as the dynamic Leidenfrost temperature (TDL). Here we propose and validate a novel paradigm of augmenting the TDL by employing droplets with stable nanobubbles dispersed in the fluid. In this first-of-its-kind report, we show that the TDL can be delayed significantly by the aid of nanobubble-dispersed droplets. We explore the influence of the impact Weber number (We), the Ohnesorge number (Oh), and the role of nanobubble concentration on the TDL. At a fixed impact velocity, the TDL was noted to increase with the increase in nanobubble concentration and decrease with an increase in impact velocity for a particular nanobubble concentration. Finally, we elucidated the overall boiling behaviors of nanobubble-dispersed fluid droplets with the substrate temperature in the range of 150-400 °C against varied impact We through a detailed phase map. These findings may be useful for further exploration of the use of nanobubble-dispersed fluids in high heat flux and high-temperature-related problems and devices.

Ion transport and current rectification in a charged conical nanopore filled with viscoelastic fluids.

The ionic current rectification (ICR) is a non-linear current-voltage response upon switching the polarity of the potential across nanopore which is similar to the I-V response in the semiconductor diode. The ICR phenomenon finds several potential applications in micro/nano-fluidics (e.g., Bio-sensors and Lab-on-Chip applications). From a biological application viewpoint, most biological fluids (e.g., blood, saliva, mucus, etc.) exhibit non-Newtonian visco-elastic behavior; their rheological properties differ from Newtonian fluids. Therefore, the resultant flow-field should show an additional dependence on the rheological material properties of viscoelastic fluids such as fluid relaxation time [Formula: see text] and fluid extensibility [Formula: see text]. Despite numerous potential applications, the comprehensive investigation of the viscoelastic behavior of the fluid on ionic concentration profile and ICR phenomena has not been attempted. ICR phenomena occur when the length scale and Debye layer thickness approaches to the same order. Therefore, this work extensively investigates the effect of visco-elasticity on the flow and ionic mass transfer along with the ICR phenomena in a single conical nanopore. The Poisson-Nernst-Planck (P-N-P) model coupled with momentum equations have been solved for a wide range of conditions such as, Deborah number, [Formula: see text], Debye length parameter, [Formula: see text], fluid extensibility parameter, [Formula: see text], applied electric potential, [Formula: see text], and surface charge density [Formula: see text] and [Formula: see text]. Limited results for Newtonian fluid ([Formula: see text], and [Formula: see text]) have also been shown in order to demonstrate the effectiveness of non-Newtonian fluid behaviour over the Newtonian fluid behaviour. Four distinct novel characteristics of electro-osmotic flow (EOF) in a conical nanopore have been investigated here, namely (1) detailed structure of flow field and velocity distribution in viscoelastic fluids (2) influence of Deborah number and fluid extensibility parameter on ionic current rectification (ICR) (3) volumetric flow rate calculation as a function of Deborah number and fluid extensibility parameter (4) effect of viscoelastic parameters on concentration distribution of ions in the nanopore. At high applied voltage, both the extensibility parameter and Deborah number facilitate the ICR phenomena. In addition, the ICR phenomena are observed to be more pronounced at low values of [Formula: see text] than the high values of [Formula: see text]. This effect is due to the overlapping of the electric double layer at low values of [Formula: see text].

Does salting-out effect nucleate nanobubbles in water: Spontaneous nucleation?

The solubility of gases in aqueous salt solution decreases with the salt concentration, often termed the "salting-out effect." The dissolution of salt in water is followed by dissociation of salt and further solvation of ions with water molecules. The solvation weakens the affinity of gaseous molecules, and thus it releases the excess dissolved gas. Now it is interesting to know that what happens to the excess gas released during salting-out? Since it is imperative to note that the transfer of the dissolved gas in the bulk liquid may often occur in the form of nanobubbles. In this work, we have answered this question by investigating the nano-entities nucleation during the salting-out effect. The solubility of gases in aqueous salt solution decreases with the salt concentration, and it is often termed as the "salting-out effects." The dissolution of salt in water undergoes dissociation of salt and further solvation of ions with water molecules. The solvation weakens the affinity of gaseous molecules, and thus it releases the excess dissolved gas. Now it is interesting to know that what happens to the excess gas released during salting-out? While it is also imperative to note that the gas transfer in the bulk liquid often occurs in the form of bubbles. With this hypothesis, we have experimentally investigated that whether the salting-out effect nucleates nanobubble or not. What is the strong scientific evidence to prove that they are nanobubbles? Does the salting-out parameter affect the number density? The answers to such questions are essential for the fundamental understanding of the origin and driving force for nanobubble generation. We have provided three distinct proofs for the nano-entities to be the nanobubbles, namely, (1) by freezing and thawing experiments, (2) by destroying the nanobubbles under ultrasound field, and (3) we also proposed a novel method for refractive index estimation of nanobubbles to differentiate them from nano drops and nanoparticles. The refractive index (RI) of nanobubbles was estimated to be 1.012 for mono- and di-valent salts and 1.305 for trivalent salt. The value of RI closer to 1 provides strong evidence of gas-filled nanobubbles. Both positive and negative charged nanobubbles nucleate during the salting-out effect depending upon the valency of salt. The nanobubbles during the salting-out effect are stable only for up to three days. This shorter stability could plausibly be due to reduced colloidal stability at a low surface charge.

Novel strategies to enhance hydrodynamic cavitation in a circular venturi using RANS numerical simulations.

Hydrodynamic cavitation is a popular advanced oxidation technique and it has received wide range of applications from waste water treatment to the nanoparticles synthesis in recent years. The enhancement of the intensity of the hydrodynamic cavitation is always been an emerging field of research. Within this framework, we have proposed and investigated three distinct strategies to enhance the intensity of cavitation in a circular venturi, namely, (1) by introducing the surface roughness on the wall (2) single or multiple circular hurdles in the diverging section (3) By modifying the diverging section from planer to the trumpet shape. RANS (Reynolds Averaged Navier-Stokes) based numerical simulations are carried out the over wide range of conditions: 2≤PR≤6 (pressure ratio), 6.2∘≤ß≤10∘ (half divergent angle), 15∘≤α≤20∘ (half convergent angle), and 1≤l/d≤3 (throat length). An extensive numerical and experimental validation with the literature have been presented to ensure the reliability and accuracy of present work. Detailed results on velocity fields, local and average volume fraction, pressure loss coefficients, cavitation number, discharge coefficient and pressure distribution are reported as function of dimensionless parameters. Five designs of various combinations of surface roughness, circular hurdles, and trumpet diverging section have been compared. The effect of surface roughness on trumpet diverging wall has been observed to be more pronounced than the other designs. Trumpet diverging wall with surface roughness is found to be optimum for the practical applications.