The role of algae in regulating the fate of microplastics: A review for processes, mechanisms, and influencing factors.

As an important emerging pollutant, the fate of microplastics (MPs) in ecosystems is of growing global concern. In addition to hydrodynamics and animals, algae can also affect the transport of MPs in aquatic environments, which could potentially remove MPs from the water column. Although researchers have conducted many studies on the sink of MPs regulated by algae in both marine and freshwater environments, there is still a lack of comprehensive understanding coupled with the increasingly scattered study contents and findings. This review aims to provide a systematic discussion of the processes, mechanisms, and influencing factors, which are coupled with the sink of MPs changes by algae. The main processes identified include retention, flocculation, deposition, and degradation. The retention of MPs is achieved by adhesion of MPs to algae or embedment/encrustation of MPs within the epibiont matrix of algae, thereby preventing MPs from migrating with water currents. The extracellular polymeric substances (EPS) and enzymes produced by algal metabolic activities can lead not only to the formation of aggregates containing MPs but also to the biodegradation of MPs. The processes that algae alter the fate of MPs in aquatic environments are very complex and can be influenced by various factors such as algal attributes, microplastic characteristics and environmental conditions. This review provides insights into recent advances in the fate of aquatic MPs and highlights the need for further research on MPs-algae interactions, potentially shortening the knowledge gap in the sink of MPs in aquatic ecosystems.

Microplastic pollution in urban stormwater inlet sediments influenced by land use type of runoff drainage area.

Since the urban stormwater inlet (USI) acts as a link in the migration of microplastics (MPs) in stormwater, sufficient information on MPs in USI sediments is very important for understanding urban diffuse microplastic pollution. In this study, the abundance and characteristics of MPs in the USI sediments of Ma'anshan City, China, were analyzed based on urban land use type. MPs were prevalent in the USI sediments, with the average abundances of 536.77 ± 313.92 items·kg-1 for commercial areas, 505.64 ± 400.82 items·kg-1 for campuses, 694.71 ± 219.95 items·kg-1 for industrial areas, 526.41 ± 152.34 items·kg-1 for residential areas, and 1107.75 ± 422.10 items·kg-1 for main roads, indicating a high microplastic pollution in the USI sediments from main roads. The microplastic polymers were mainly polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), and polystyrene (PS), accounting for 46.75 %-100.00 %, with PP MPs being the most abundant. Fiber MPs had the highest proportion in USI sediments from both campuses (35.30 %) and industrial areas (38.19 %), while film MPs were the most abundant for both commercial areas (39.91 %) and residential areas (35.65 %). The average proportions of fiber (27.29 %), fragment (29.18 %), and film (28.68 %) were almost equal for main roads, unlike other land use types. Except for campuses, transparent MPs were the most common for all land use types, with average proportions of 29.60 %-42.70 %. The proportions of MPs with sizes of <1000 µm were 72.54 % for commercial areas, 77.11 % for campuses, 76.05 % for industrial areas, 70.76 % for residential areas, and 74.29 % for main roads, respectively, with a consistent result with previous study that the MPs of <1000 µm are the predominant in the environment. This study enriches the knowledge of microplastic pollution in USI sediments and will benefit the mitigation of diffuse microplastic pollution.

Impacts of the steel industry on sediment pollution by heavy metals in urban water system.

The impact of the steel industry on sediment heavy metal (HM) pollution in urban aquatic environments was investigated in a major iron ore-producing area (Ma'anshan) in China. The concentrations of Cd, Cr, Cu, Ni, Pb, and Zn were 9.68 ± 3.56, 170.31 ± 82.40, 90.62 ± 19.54, 30.61 ± 6.72, 125.43 ± 63.60, and 1276.59 ± 701.90 mg/kg in the steel industry intruded upon sediments and 4.63 ± 1.41, 87.60 ± 10.96, 52.67 ± 19.99, 37.49 ± 6.17, 35.84 ± 11.41, and 189.02 ± 95.57 mg/kg in the control area, respectively. Comparing with the local soil background (0.08 mg/kg for Cd, 62.6 mg/kg for Cr, 19.3 mg/kg for Cu, 28.1 mg/kg for Ni, 26.0 mg/kg for Pb, and 58.0 mg/kg for Zn), significantly higher levels of Cd, Cr, Cu, Pb, and Zn were detected in the steel industry affected sediments. The enrichment factor and principal component analysis indicated that the heavy metals (HMs), except for Ni, were primarily derived from anthropogenic inputs, particularly from steel industrial activities. Multiple risk assessment models suggested that the sediments affected by industrial activities showed significant toxic effects for Cd, Cr, Pb, and Zn, with Cd being the main contributor to sediment toxicity. However, the alkaline nature of the sediments (pH = 7.85 ± 0.57) and the high proportion of residual fraction Cd (61.09% ± 26.64%) may help to reduce the toxic risks in the sediments. Effective measures to eliminate tinuous thethe continous input of Cd and Zn via surface runoff are crucial.

Microplastics and microorganisms in sediments from stormwater drain system.

Research has already confirmed the occurrence of microplastics (MPs) in sediments of stormwater drain system (SDS). However, the microplastic pollution remains to be elucidated well in sediments, especially the spatio-temporal distribution and the impacts of MPs on microorganisms. In this study, the averaged abundance of MPs in SDS sediments was 479 ± 688 items·kg-1 for spring, 257 ± 93 items·kg-1 for summer, 306 ± 227 items·kg-1 for autumn and 652 ± 413 items·kg-1 for winter. As expected, the abundance of MPs was the lowest in summer due to runoff scouring, while the highest in winter attributed to infrequent low-intensity rainfall. The major polymers of MPs were polyethylene terephthalate and polypropylene plastics, occupying 76 % to 98 % of the total number. Fiber MPs were the most regardless of season (41 % to 58 %). MPs with size of 250-1000 µm accounted for over 50 %, which is in accordance with the previous study that MPs of <1000 µm were the major. High-throughput sequencing of analysis shows that MPs provided an ecological niche for bacterial communities different from that of SDS sediments. Actinomycetes and bacteria with chemoheterotrophic genes tended to be enriched on the surfaces of MPs. In addition, Acidobacteria and bacteria with nitrification genes would not like to present in microplastisphere. A strong positive correlation (R from 0.74 to 0.83, P < 0.01) was found between the abundance of MPs in sediments and the abundance of functional genes for denitrification and nitrogen respiration of microorganisms on the surfaces of MPs. It indicates that MPs may influence the nitrogen transformation processes in SDS sediments via the occurrence of denitrification processes on the surfaces of MPs. The abundance of MPs had no significant relationship with the various functional genes of microorganisms in the sediments (P > 0.05), which means that MPs could not profoundly influence the expression of microbial functional genes in SDS sediments.

Microplastics as vectors of organic pollutants in aquatic environment: A review on mechanisms, numerical models, and influencing factors.

Microplastics (MPs), a new class of emerging pollutants, have attracted exponentially increased attention due to the adverse ecological impacts on biota, not only by themselves but also by the combined corrosive substances. However, the occurrence mechanisms, numerical models and influencing factors of MPs adsorbing organic pollutants (OPs) show a significant variation with literatures. Therefore, this review is focused on the adsorption of OPs on MPs, including mechanisms, numerical models, and influencing factors, to obtain a comprehensive understanding. Research shows that MPs with strong hydrophobicity have high adsorption capacity for hydrophobic OPs. Hydrophobic distribution and surface adsorption are considered to be the main mechanisms by which MPs adsorb OPs. The available literature suggests that the pseudo-second-order model describes the adsorption kinetics of OPs on MPs better than the pseudo-first-order model, while the choice of Freundlich or Langmuir isotherm model depends mainly on the specific environmental conditions. Moreover, the characteristics of MPs (composition, particle size, aging, etc.), the nature of OPs (concentration, polarity, hydrophilicity, etc.), the environmental conditions (temperature, salinity, pH, ionic strength, etc.), and the substances co-existing in the environment (e.g., DOM and surfactants) are all important factors affecting the adsorption behavior of MPs for OPs. Environmental conditions can also indirectly affect the adsorption of hydrophilic OPs adsorbed on MPs by causing changes in the surface properties of MPs. Based on the current knowledge, the perspective shortening the knowledge gap is also suggested.

Aging dependent plastic bag derived-microplastics as a vector of metals in lake water.

The adsorption of microplastics (MPs) for metals in aquatic environment remains poorly understood due to the use of either commercial MPs, which have different property from the MPs in environments, or artificial solutions, which have not only the significantly higher concentration of metals than natural aqueous environment but also the different natures. In this study, we elaborated the adsorption throughout the aging process of plastic bag derived-MPs (initially 1-2 mm) by potassium persulfate (K2S2O8) solution to metals in lake water. Comparatively, plastic bag derived-MPs had the highest adsorption capacity for Zn2+ followed by Fe3+, Pb2+, Mn2+, Cr6+, Ni2+, Cu2+ and Cd2+, which is not completely consistent with the literature. Both the adsorption capacity and distribution coefficients of Cu2+, Ni2+, Zn2+, Mn2+ and Pb2+ had significant linear correlation with carbonyl index (p < 0.05). Although the aging overall enhanced the adsorption, the adsorption capacities of MPs might fluctuate depending on metal.

Microplastic pollution in sediments of urban rainwater drainage system.

The sink of microplastics (MPs) in sediments of urban rainwater drainage system (RDS) is of great concern, because the MPs deposited can be resuspended by flow disturbance. Previous research has confirmed the significant accumulation of MPs in sediments of urban RDS, but it remains poorly elucidated, such as pollution sources and influencing factors. In this study, we investigated the MPs in sediments from RDS of a university campus. MPs were detected from all sediment samples, showing the ubiquity of microplastic pollution. Among 11 samples MPs' abundance ranged from 80 to 2610 particles/kg (dry weight), with highly spatial variability, depending on land type and environmental management practice within the catchment. Sites from office & teaching area had the averaged abundance of 335.00 ± 196.85 particles/kg, while 270.00 ± 89.09 particles/kg for staff residential area, and 795.00 ± 1050.65 particles/kg for student living area, indicating that the sediments of RDS from student living area had the highest abundance of MPs. However, independent sample t-test analysis suggests there is no statistically significant difference between land types, because of effective environmental management practices in the catchment. The surfaces of MPs were much rough, which implies that the fragmentation of larger plastic particles resulted in the production of MPs. Although the MPs of <1000 µm were the most, 1000-2000 µm MPs also accounted for a significant proportion in this study, showing a slight difference from the previous study in which MPs over 1 mm were quite low. Polypropylene (PP) and polyester (PET) found to be dominant with 49.75 ± 18.69 % and 49.75 ± 18.69 % of the total number, respectively. As to shapes, the proportion of fiber and fragment MPs exceeded 80 %. The color of MPs diversified greatly, and the MPs with bright colors occupied over 80 %. Fabric fibers, food packaging and courier packaging materials were figured out to be the considerable contributors of MPs.

[Characteristics of Microplastic Present in Urban Road Dust].

Microplastics (MPs), as an emerging contaminant, have attracted wide attention due to their potentially negative impact on the ecosystem. However, information on microplastic pollution in terrestrial environments, especially road dust, is still rare. In this study, the microplastic pollution in road dust from the Yushan District of Ma'anshan City was characterized. The abundances of MPs accumulated per square meter of road and dust were (18.11±32.36) n·m-2 and (223.00±197.01) n·kg-1, respectively, and the contents were (27.29±72.64) mg·m-2 and (385.23±628.93) mg·kg-1, respectively, with polypropylene (PP, 58.90%) and polyethylene (PE, 30.08%) as the major polymers based on the number fraction in dust. Additionally, in a given road area, the abundance of MPs in commercial areas was the highest[(78.32±101.24) n·m-2], followed by residential[(19.81±14.30) n·m-2], industrial[(10.95±5.54) n·m-2], suburban[(8.56±8.13) n·m-2], and educational[(6.99±5.74) n·m-2] areas. In the case of the same area, the microplastic pollution from the commercial area was heavier. Regarding the shape of the MPs detected in road dust, 66.64% were present as films, 16.14% as granules, 14.13% as fibers, and 3.10% as spheres out of the total number detected. Most of the MPs were less than 1000 µm in size. For a particular road area, the abundance of MPs was significantly correlated with the mass of dust (r=0.599, P<0.01), whereas there was no obvious correlation for the mass of MPs (r=0.067, P=0.780). Generally, the road dust can accumulate continuously prior to cleaning, whereas the mass of the MPs will not increase unless there is external input. Otherwise, MPs on the road will be broken down under the action of external forces such as vehicles, resulting in an increase in the number of MPs.

Heavy Metals Present in the Soils from Extremely Large Opencast Iron Mine Pit.

The mining areas have faced severe pollution by caustic metals. In this study, heavy metals (Cu, Zn, Cr, Cd, Pb and Ni) in the soil of an extremely large iron mine pit from Ningwu-Luohe metallogenic belt, one of the seven iron ore areas in China was characterized. SiO2 was predominant soil mineral composition as 57.0 ± 1.3 %, followed by considerable Al2O3 (23.1 ± 2.5 %) and Fe2O3 (8.58 ± 1.2 %). Cu, Zn, Cr, Cd, Pb and Ni had the range of 7.62-237, 97.8-313, 1.73-43.8, 0.119-0.512, 5.13-44.7 and 7.87-23.9 mg/kg, respectively, wherein, Cu, Zn, Cr and Pb were likely to have relatively low concentration in the soil from the boom of mining pit. Comparatively, both Cu and Zn arose at the level of 1-fold higher than that of local background values, indicating that the soil from mining pit had been subjected to Cu and Zn accumulation. BCR (European Communities Bureau of Reference) sequential extraction analysis showed that these metals mainly existed in residual fraction, with averaged percentages of 42.0 ± 18 %, 70.3 ± 8.1 %, 76.6 ± 18 %, 30.2 ± 14 %, 52.5 ± 11 % and 61.0 ± 9.7 % for Cu, Zn, Cr, Cd, Pb and Ni, respectively. Geo-accumulation index indicates that the soil was moderately contaminated by Cu, practically uncontaminated or uncontaminated to moderately contaminated by Zn, while practically uncontaminated by Cr, Cd, Pb and Ni. There were just significant relationships between Zn and Cd and between Cd and Pb, indicating that Cd in the soil investigated possibly had at least two sources and for most of the elements the sources were different. The effects of pit depth and major soil composition on the distribution of trace metals varied depending on the element itself and its chemical forms.

[Characterization of Microplastic Pollution of Sediments from Urban Lakes].

In recent years, microplastics (MPs) in the environment has become a topic of increasing concern. In this study, typical urban lakes, such as Yushan Lake and Nanhu Lake in Maanshan City, were selected to study the physical morphology and spatial distribution characteristics of MPs in sediments in spring and summer and to explore the sources of MPs in the lakes. On average, MPs in sediments occurred with a content of (0.0284±0.0597) g·kg-1 and abundance of (278.9±529.1) n·kg-1 in spring, and (0.0317±0.0778) g·kg-1 and (277.1±395.6) n·kg-1 in summer, respectively. Using a paired sample T-test, it was found that there was no significant correlation difference between the content (N=22, t=-0.269, P=0.791) and the abundance (N=22, t=0.035, P=0.973) of MPs in the spring and summer sediments. Regarding shape, the MPs in the sediments in the study area were divided into three types:fiber, film, and particle, accounting for 52.9%, 28.9%, and 18.2%, respectively. Size-fraction analysis indicated MPs<1 mm made up the majority, accounting for 83.9% of the total number. It was found that the MPs were mainly polyethylene (PE) and polypropylene (PP) polymers with seriously weathered surfaces. The sediments, which were adjacent either to land with a large stream of people and vehicles or to areas with frequent watersports, had notably high abundance of MPs, revealing the close correlation between the spatial distribution of MPs in lake sediments and human activities. It is thought that atmospheric precipitation (fiber), stormwater, washing of clothes (fiber), degradation of large plastics in the lake, and fishing activities (fishing nets, foam) are the main sources of MPs in lake sediments.

Microplastics in Sediments of River Yongfeng from Maanshan City, Anhui Province, China.

This study was performed to evaluate the microplastics (MPs) pollution of sediments from River Yongfeng. It was observed that the MPs in sediments were present with contents of 0.5-16.75 mg/kg and abundances of 5-72 items/kg, coupled by variation coefficients of 109% and 91%, respectively, indicating that the distribution of MPs had high spatial variation. The land-based source of business zone is thought to be the significant contributor to accumulation of MPs in those sites with high quantity of MPs. Film was the predominant shape of MPs in river sediments followed by the line and fragment ones. Meanwhile, the MPs detected were mainly composed by four types including Polypropylene (24%), Polyethylene (61%), Polyethylene Terephthalate (8%) and Polystyrene (7%) based on number fraction, respectively, which indicates that Polypropylene and Polyethylene were the major types of MPs in the sediments. Size fraction performance suggests that those MPs < 1000 µm were of ubiquitous presence. The weathering of fringes was universally observed regardless of varying surface among MPs. Despite digestion with oxidative acid solution and subsequent washing by distilled water unexpected elements can still be detected, which should be considered as determining the materials associated.

Pollution reduction by recirculated fill-and-drain mesocosm wetlands packed with woodchip/pumice treating impervious road stormwater.

Constructed wetlands (CWs) are natural-friendly method to eliminate the pollutants stormwater pollutants. For this study, a pilot-scale treatment system consisting of a sedimentation tank (ST) and five recirculated fill-and-drain wetlands (namely CW-1, CW-2, CW-3, CW-4 and CW-5) were constructed to treat the first-flush from the impervious road. From bottom to top, the main substrates of CWs were selected as 0 cm woodchip + 60 cm pumice for CW-1, 15 cm woodchip + 45 cm pumice for CW-2, 30 cm woodchip + 30 cm pumice CW-3, 45 cm woodchip + 15 cm pumice CW-4 and 60 cm woodchip + 0 cm pumice for CW-5. During the operational period, the reduction efficiencies of TSS, total COD, total nitrogen and total phosphorus were 89-100%, 52-100%, 31-87% and 72-100% by CW-1, 92-100%, -27% to 78%, 8-85%, 49-94% by CW-2, 89-100%, -97% to 77%, -29% to 86%, -46% to 94% by CW-3, 89-100%, -115 to 69%, -21% to 99%, 35-94% by CW-4 and 59-100%, -342%to 88%, -20% to 88%, -77% to 99% by CW-5, respectively. Overall, the reduction efficiency, except for nitrogen, declined as the amount of woodchip increased. As excepted, the employment of woodchip improved denitrification via providing with carbon sources, resulting in low NO3-N but unfavourable COD concentrations in the effluent. And the combination use of woodchip and pumice as CW-3 or CW-4 is suggested, whereas the specific amount of woodchip and pumice should be determined based on the regional environmental goal.

Characteristics of particle size distribution and related contaminants of highway-deposited sediment, Maanshan City, China.

Road-deposited sediment (RDS) has been identified as both the source and sink of various pollutants. In this study, the highway-deposited sediment (HDS) in Spring, Summer, Autumn and Winter was characterized. On average, the mass proportions of particles with the size of 830-4750 µm, 500-830 µm, 250-500 µm, 150-250 µm, 63-150 µm and < 63 µm were 23.6 ± 8.6%, 16.9 ± 3.4%, 28.4 ± 3.5%, 10.0 ± 4.3%, 15.7 ± 5.8% and 5.3 ± 2.0%, respectively, wherein the HDS of 63-830 µm accounted for 71% of the total mass load. It was observed that the particle size distribution of HDS could be described using the gamma distribution function based on gravimetric and cumulative basis (R2 (determination coefficient) = 0.9960-0.9995). The bulk pollutant contents of HDS showed seasonal variation with the mean of COD (chemical oxygen demand), nitrogen, phosphorus, Zn (zinc), Pb (lead) and Cd (cadmium) as 57 g/kg, 839 mg/kg, 97 mg/kg, 627 mg/kg, 110 mg/kg and 1.00 mg/kg and the highest COD of 83 g/kg in Autumn, nitrogen 1164 mg/kg Autumn, phosphorus 133 mg/kg Winter, Zn 801 mg/kg Summer, Pb 133 mg/kg Spring and the highest Cd of 1.36 mg/kg in Summer, respectively. The contents of Zn, Pb and Cd in HDS were significantly above their local soil background values. Moreover, the size fractional pollutant contents overall increased as particles' size increased. Averagely, 40-52% pollutant loads were associated with the particles < 250 µm, which can be moved easily by runoff. This study suggests that the behaviors of HDS different from city RDS should be considered as nonpoint source pollution control is performed.

Endocrine Disrupting Compounds from the Source Water of the Huai River (Huainan City), China.

The occurrence and environmental risk of eight endocrine disrupting compounds (EDCs), namely dimethyl phthalate (DMP), diethyl phthalate (DEP), benzyl butyl phthalate (BBP), dibutyl phthalate (DBP), nonyl phenol (NP), bisphenol A (BPA), 17α-ethinylestradiol (EE2) and estrone (E1), from four water sources (Pingshantou, Wanfenggang, Shisi, and Shiyi) of Huai River (Huainan section) were investigated in this study. Except for DMP only found in Pingshantou, all of the selected EDCs existed widely in the source water. DMP, DEP, BBP, DBP, NP, BPA, EE2, and E1 had the ranges of nd (cannot be detected)-130 ng/L, 25-310, 76-1351, 431-1299, 215-627, 23-107, nd-0.174, and 0.143-0.334 ng/L, respectively. Therefore, the studied water sources were associated with notable levels of EDCs, wherein the concentrations of BBP, DBP, and NP were much higher than the other five chemicals. The selected EDCs appeared to be higher in upstream than in downstream (p < 0.05) for each water source, suggesting that EDCs were subjected to a decreasing with water flow. Correlation analysis suggests that DEP-BP-DBP, NP-BPA, and EE2-E1 might have the same sources, respectively; and the source of NP, EE2, and E1 was different from that of BBP, BEP and BBP, and DEP, respectively. It was observed that both the TAS (total ambient severity) and RQ (risk quotient) were less than 1, indicating that EDCs in Huai River (Huainan section) posed little or no thread to the health of local inhabitants and ecological environmental.

Heavy metals in the soils and plants from a typical restored coal-mining area of Huainan coalfield, China.

This study was conducted to pursue the heavy metals in the soil and plants of a typical restored coal-mining area, China. The average concentrations of Cu, Zn, Cr, Ni, and Pb in soil were 26.4, 76.1, 188.6, 34.3, and 50.2 mg kg-1, respectively, implying a significant accumulation of Cr, Ni, and Pb compared with the background values. Contamination factor indicates that the soil underwent none to medium pollution by Cu and Zn, medium to strong by Cr, none to strong by Pb, and medium pollution by Ni while the pollution load index means that the soil was subjected to intermediate contamination. Based on the critical threshold values to protect the plants, the investigated metals were unable to affect the plants. One-way ANOVA analysis shows that Cu, Zn, and Pb in plants varied with plant tissues. Cu-Cr, Cu-Ni, Zn-Ni, Zn-Pb, Cr-Ni, and Ni-Pb pairs had significant positive correlation both in soil and in plants due to the similar soil characteristics and plant physiologies. Correspondence analysis indicates that Pb was more likely to be accumulative in stems and leaves. In addition, the levels of Cu and Cr in plant followed an order of roots > stems > leaves; Zn and Ni leaves ≥ stems > roots; and Pb followed stems ≥ leaves > roots. Generally, this study suggests that the plants like Ligustrum lucidum Aiton and Weigela hortensis, which are capable of accumulating Cr, Ni, and Pb, should be the predominant species in the studied area.

An investigation into the relationship between water quality volume (design storage volume) and stormwater wetland performance.

An investigation on free water surface wetland, which has an area of 0.23 ha and is employed to control the non-point source pollution from a watershed of 7.4 ha, was carried out to examine how the WQvr (the ratio of stormwater inflow volume to water quality volume (WQv)) affects the wetland treatment performance. As stormwater went through the wetland, TSS (total suspended solids), TCOD (total chemical oxygen demand), TN (total nitrogen) and TP (total phosphorus) were reduced by 85%, 57%, 6% and 68%, on average, respectively. Increase in the WQvr resulted in a decrease in the reduction efficiencies of TSS, TCOD and TP, but a slight increase in TN removal. WQv was identified as a useful parameter for the design of stormwater wetlands, as this volumetric design approach overcomes the variation in flow rate and pollutant concentrations with respect to time and rainfall conditions. However, the design goal of 80% TSS reduction was not accomplished as inflow water volume equal to designed WQv. On the other hand, it was found that TCOD and TP reduction could also be considered as wetland design goals together with TSS. However, TN reduction did not show any significant relationship with the WQv.

Operation and performance evaluation of high-speed filter using porous non-woven filamentous fibre for the treatment of turbid water.

This study was carried out to identify the filter performance of fibre filter module treating high-turbidity water at extremely high filtration rates (1000-2500 m/day). The effects of filter aid chemical (polyaluminium chloride (PAC)), filtration rate and particles size on filter performance were investigated. It was found that PAC was a crucial factor influencing the separation process. Even though the optimum PAC dose for the raw water with turbidity of 50 nephelometric turbidity units (NTU) was 0.5 mg/L, the turbidity removal efficiencies were similar as the raw water turbidity was no more than 50 NTU. As expected, the filter performance was negatively affected by the increased filtration rate. However, the turbidity removal efficiency at an extremely high filtration rate still was amazing and attractive (∼80% at 2500 m/day). Moreover, the D50 and uniformity coefficient of the particles in raw water were not the factors greatly affecting the filter performance. The empirical model for the filter processes of granular filters did not work; therefore, an empirical model towards fibre filters at a high flow rate was suggested, which can be used to predict the treatment performance.

Risk Analysis of Metals in Soil from a Restored Coal Mining Area.

This study was conducted to evaluate ecological impacts of metals in soil from the restored Panyi coal mining area of China. Zn, Cr, Ni, Pb and Cd had significantly accumulated in the studied soil compared with regional background values (p<0.05). Geo-accumulation indices indicate that the soil was at low risk for Cu, Zn, Ni and Pb contamination, while a low to moderate risk for Cr and Cd contamination existed. The ecological impact of all the selected metals was identified by ecological soil screening levels, apart from Cr, the impact of which was determined based on Dutch Target and Intervention Values. Results suggest that plants may be significantly affected by Ni, the avian population by Zn, Pb and Cd, while mammals are possibly influenced by Cd.

Experimental study on non-woven filamentous fibre micro-filter with high filtration speed.

A laboratory study was undertaken to pursue the filter performance of a micro-filter module employing highly porous fibre media under a high filtration rate (≥1,500 m/day), faster than that of any conventional filter process. The effects of filtration rate, head loss, raw water turbidity, and filter aid chemicals on filter performance were analysed. In spite of the extremely high filtration rate, the filter achieved an attractive efficiency, reducing the raw water turbidity by over 80%. As with other filter systems, the filter aid used ((polyaluminium chloride (PAC)) greatly affected the performance of this particular fibre filter. Long-term repetitive runs were additionally carried out to confirm the reproducibility of the filter performance. Also, a comparison was carried out with other high-rate filter systems which are either being tested for use in experimental studies, or are already commercially available. This study reveals that the filter performance under a high filtration speed is still attractive especially as PAC is used. Due to the high porosity of the fibre, the filter had small head loss even though the filtration rate was high. These results ascertain that it is possible to operate the filters with high filtration rate achieving reliable treatment performance.

Effect of sampling duration on the performance evaluation of a stormwater wetland.

In this study, the effect of sampling duration on the performance estimate for a stormwater wetland over both rainy and dry days was evaluated for the appropriate design of sampling duration. As the cumulative percentage volume (Vp), the ratio of cumulative stormwater volume concerning time to the total stormwater volume, varied between 60 and 100%, generally, the inflow total suspended solids, turbidity and total chemical oxygen demand (TCOD) event mean concentrations (EMCs) did not vary significantly, whereas the total nitrogen (TN) and total phosphorus (TP) EMCs were relatively stable. Compared to the inflow, the corresponding outflow EMCs changed much less as Vp changed. And these variations both from inflow and outflow EMCs did not result in significant changes in the removal efficiencies. The investigation during the dry days between two consecutive storm events showed that outflow pollutants did not change to a considerable extent after 1 day of the previous rainfall event. This study identifies the possibility of shortening the rainy sampling duration, because the performance of stormwater wetlands is usually estimated based on removal efficiencies rather than pollutant concentrations. Also, the sampling during dry days should be performed at least 1 day after a rainfall event.