1.
Chem Commun (Camb)
; 51(50): 10194-7, 2015 Jun 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26015999
RESUMO
The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.