Anthropogenic emissions from coal-water slurry combustion: Influence of component composition and registration methods.

The flue gas composition is often measured using a combination of techniques that differ in terms of both physical operation principle and type of output. Gas analyzers, FTIR spectrometers, and mass spectrometers are the most popular tools used for this purpose. In this research, we study the composition of the flue gas from the combustion of fuel slurries and dry composite fuels based on industrial and agricultural waste. It has been established that the use of slurry fuels makes the anthropogenic emissions 2-4 times lower than from the combustion of coal slime. For example, the CO2 emissions from the combustion of dry coal slime were 2.5-3.7 times higher than from the combustion of slurry fuels. In addition, the combustion of slurry fuels made it possible to cut down the nitrogen oxide emissions by 1.3-1.5 times and sulfur oxide emissions by 1.3-2.7 times. A comparison of the results obtained using different measurement techniques has shown that differences between the CO and CO2 content in the combustion products measured by a gas analyzer and an FTIR spectrometer did not exceed 20%. The use of FTIR spectroscopy provided new knowledge on the concentrations of hydrocarbons from the combustion of fuels based on promising industrial wastes.

Dissociation characteristics and anthropogenic emissions from the combustion of double gas hydrates.

Gas hydrates are an alternative and environmentally friendly energy source increasingly in the focus of scientific attention. The physicochemical processes behind gas hydrate combustion are studied experimentally and numerically with a view to improving the combustion efficiency and reducing gas emissions. It is important to estimate the pollutant emission concentrations in the context of combustion conditions. The research deals with the dissociation and combustion behavior of double gas hydrates in a tubular muffle furnace. Gas hydrates of different composition are considered: methane, methane-ethane, methane-propane and methane-isopropanol. Double gas hydrates are characterized by more stable combustion compared to methane hydrate. It is also shown that the double gas hydrate dissociation rate increases by 15-30% with increasing temperature. Dissociation and combustion processes were also modeled as part of the research, accounting for phase transitions in a gas hydrate layer. According to the simulation results, the total dissociation rate of gas hydrate increases by 3 times with an about 2.5-times increase in the powder layer thickness. Our experiments also focused on the impact of furnace temperature and gas hydrate composition on concentrations of anthropogenic gas emissions. We have found that the presence of heavy hydrocarbons such as ethane, propane and isopropanol in double gas hydrates reduce unburned CH4 emissions by 60%. Also, an increase in the combustion efficiency of double gas hydrates, accompanied by a decrease in the concentrations of unburned CH4 and CO, affects the yield of CO2, which increased by 13-35%. When we increased the temperature in the furnace from 750 °C to 1050 °C, concentrations of nitrogen oxides and carbon dioxide increased by up to five times. Thus, the resulting correlations between the key parameters of these processes and a set of the main inputs illustrate the possibility to predict the optimal conditions for the combustion of gas hydrates.

Composition of a gas and ash mixture formed during the pyrolysis and combustion of coal-water slurries containing petrochemicals.

This paper presents the results of experimental research into the component composition of gases and ash residue from the combustion of a set of high-potential coal-water slurries containing petrochemicals. We have established that the use of slurry fuels provides a decrease in the CO2, CH4, SO2, and NOx concentrations as compared to those from coal combustion. The content of carbon monoxide and hydrogen in the gas environment from the combustion of slurries is higher due to the intense water evaporation. It is shown that adding biomass allows a further 5-33% reduction in the emissions of nitrogen and sulfur oxides as compared to the coal-water slurry and the composition with added waste turbine oil and a 23-68% decrease as compared to coal (per unit mass of the fuel burnt). The mechanisms and stages of CO2, SO2, and NOx formation are explained with a view to controlling gaseous anthropogenic emissions and ash buildup. The values of the relative environmental performance indicator are calculated for slurry fuels. It is shown to exceed the same indicator of bituminous coal by 28-56%.

Anthropogenic emissions from the combustion of composite coal-based fuels.

Composite fuels made of waste from coal, petroleum and wood processing industries have a high environmental and economic potential. In this research, we experimentally studied the concentrations of the most hazardous gaseous anthropogenic emissions (CO2, SO2, NO) from waste-based fuel combustion. Using two techniques operating in complementary temperature ranges, we obtained data on SO2 and NO emissions in the temperature range from 300 °C to 1000°C, including all the stages of thermochemical conversion of fuels. A quasi-stationary technique was used, based on a setup of thermogravimetric analysis with mass spectrometry, to obtain information in a low-temperature range (300-600°C). This technique allows the conversion at a low controlled rate of heating a sample together with the furnace. To obtain data in a high-temperature range (700-1000°C), a non-stationary technique was used, where the sample was introduced into a pre-heated furnace. The conditions were established in which it was possible to reduce the concentration of flue gases from the combustion of the compositions under study (replacement of the coal part with water, injection of water vapor, addition of biomass, selection of the temperature range). The impact of water vapors was determined when they were injected into the chemical reaction zone together with air and when they were formed naturally by evaporation from the fuel sample. Unlike biomass that reduces the emissions of sulfur oxides from composite fuels due to the mechanical dilution of the mixture, water vapor present in the heterogeneous reaction zone decreases the gaseous anthropogenic emissions through chemical reactions and conversion of a part of fuel sulfur and nitrogen to an inactive form (neutral to the environment).

Effects of plant additives on the concentration of sulfur and nitrogen oxides in the combustion products of coal-water slurries containing petrochemicals.

The active use of solid fossil fuels (coal) in the production of heat and electricity has led to significant pollution, climate change, environmental degradation, and an increase in morbidity and mortality. Many countries (in particular, European ones, China, Japan, the USA, Canada, etc.) have launched programs for using plant and agricultural raw materials to produce heat and electricity by burning them instead of or together with traditional fuels. It is a promising solution to produce slurry fuels, based on a mixture of coal processing, oil refining and agricultural waste. This paper presents the results of experimental research into the formation and assessment of the most hazardous emissions (sulfur and nitrogen oxides) from the combustion of promising coal slurry fuels with straw, sunflower and algae additives, i.e. the most common agricultural waste. A comparative analysis has been carried out to identify the differences in the concentrations of sulfur and nitrogen oxides from the combustion of typical coal, coal processing waste, as well as fuel slurries with and without plant additives. It has been shown that the concentration of sulfur and nitrogen oxides can be reduced by 62-87% and 12-57%, respectively, when using small masses of plant additives (no more than 10 wt%) and maintaining high combustion heat of the slurry fuel. However, the use of algae and straw in the slurry composition can increase the HCl emissions, which requires extra measures to fight corrosion. A generalizing criterion of slurry fuel vs. coal efficiency has been formulated to illustrate significant benefits of adding plant solid waste to coal-water slurries containing petrochemicals. Straw and sunflower waste (10 wt%) were found to be the best additives to reduce the air pollutant emissions.

Prospects of thermal power plants switching from traditional fuels to coal-water slurries containing petrochemicals.

The amount of thermal and electric energy produced by coal combustion increases nonlinearly, because the production capacities and consumption of the corresponding energy are on the rise. The prospects of excluding coal from the picture are slim, because it has been traditionally considered one of the most attractive fuels in terms of cost and heat of combustion. What we need is major changes in the energy industry towards environmentally effective use of coals and their processing wastes. In this research, we show the possibility of coal-fired thermal power plants and steam shops switching to coal-water slurries containing petrochemicals (CWSP). Extra calculations are made for fuel oil and natural gas. The scientific novelty of the research consists in the comprehensive consideration of all the possible technological modifications in the fuel feeding, storage, and preparation system. We focus on potential benefits of thermal power plants and steam shops switching from coal, gas, and fuel oil to coal-water slurries containing petrochemicals, while taking into account all the main and most important environmental, economic, and energy performance indicators. Using CWSP instead of coal is much more environmentally friendly. By varying the content of water and additives in CWSP, we can lower the proportion of sulfur and nitrogen and slow down their oxidation. It is also possible to reduce temperature in the combustion zone and improve oxide retention in the ash without its release in the form of anthropogenic emissions. Throughout the world, tens of thousands of fuel oil and coal-fired TPPs with the annual gross electric output of 1.8 TW can switch to CWSP. The integrated performance indicators of CWSP fuels are only inferior to those of natural gas but these slurries are prepared from numerous industrial wastes.

The influence of liquid plant additives on the anthropogenic gas emissions from the combustion of coal-water slurries.

At present, coal is considered one of the main components for the production of cheap, high-energy and environmentally attractive slurry fuels. The latter can be produced on the basis of low-grade coal dust or coal processing wastes. Thus, coal-water slurries and coal-water slurries containing petrochemicals are produced. The involvement of coal and oil processing wastes expands the scope of raw materials, reduces the fuel costs from traditional energy sources and modifies the main economic characteristics of power plant performance. However, it also increases the impact of coal-fired thermal power stations on the environment. In the last 30-50 years, many efforts have been made to decrease the negative impact of human industrial activity on climate. Involving plant-based components in the process of energy generation to save energy and material resources looks very promising nowadays. This research studies the influence of adding typical bioliquids (bioethanol, turpentine, glycerol) on the concentration of anthropogenic emissions from coal-water slurry combustion. Relative mass concentrations of bioliquids varied in a small range below 20%. We focused on the concentration of the most hazardous sulfur and nitrogen oxides from the combustion of typical filter cakes, as well as plant-containing slurries. It was established that the concentration of sulfur oxides can be decreased (as compared to coal) by 75%, whereas that of nitrogen oxides by almost 30%. Using a generalizing criteria expression, we illustrated the main benefits of adding bioliquids to slurry fuels in comparison with coal. Adding 20% of glycerol was found to provide maximum advantages.

Environmental benefits and drawbacks of composite fuels based on industrial wastes and different ranks of coal.

A promising solution to many problems that thermal power industry is facing today would be switching from conventional coal dust combustion to coal-water slurries containing petrochemicals (CWSP). Here, we perform an experimental study of the most hazardous anthropogenic emissions (sulfur and nitrogen oxides) from the combustion of high-potential CWSP. We identify the main benefits and potential drawbacks of using CWSP in thermal power industry. A set of components and additives to CWSP are explored that significantly affect the environmental and energy performance of fuels. The anthropogenic emissions from the combustion of CWSP made of widespread coal and oil processing wastes are no higher than those from coal dust combustion. Using specialized additives to CWSP, we can change the concentrations of NOx and SOx several times. The most appealing additives to CWSP are sawdust, straw, charcoal, limestone, and glycerol. They provide better environmental, economic, and energy performance and improve the rheological properties of CWSP. Waste oils and oil sludge added to CWSP may impair the environmental performance but boost the cost and energy efficiency. Using coal-water slurries containing petrochemicals as a fuel at thermal power plants is an environmentally friendly as well as cost- and energy-efficient way to recover industrial wastes.