Lateral electric field switching in thin ferroelectric nematic liquid crystal cells.

This study shows that, in cells with small thicknesses, the permanent polarization in the ferroelectric nematic phase of RM734 is aligned in the direction opposite to the rubbing direction. The electrode configuration induces an in-plane field near one substrate and a normal field near the other substrate. At low voltages, the permanent polarization rotates parallel to the substrate plane when its original orientation is at an angle with the electric field. The rotation occurs over a distance of more than 100 µm, where the applied electric field is very small. At higher voltages, the polarization aligns perpendicularly to the substrates under the influence of the transverse electric field. After removing the voltage, sometimes a slow reorientation of the polarization can be observed, which is ascribed to the slow release of ionic species. The results provide insight into the complex mechanisms that are involved in the switching of ferroelectric nematic liquid crystals.

Chiral liquid crystal based holographic reflective lens for spectral detection.

Flat optics based on chiral liquid crystal (CLC) can be achieved using holographic polarization recording with the help of a photoalignment technique to vary the orientation of the optical axis in a thin CLC layer. A variety of reflective diffractive optical components with high efficiency and polarization selectivity can be realized employing this technique. In this work we discuss the use of CLC diffractive lenses in a spectrometer. The functionalities of two mirrors and a linear grating used in a traditional spectrometer are combined into a single holographic CLC component. Circularly polarized light entering through the slit can be reflected and projected onto a linear detector by the CLC component, with over 90% efficiency. This excellent optical functionality can be achieved with a micrometer thin CLC layer, offering the opportunity for device integration.

Influence of period and surface anchoring strength in liquid crystal optical axis gratings.

Liquid crystal (LC) based geometric phase optical elements are widely used to effectively change the wavefront or propagation direction of light. Using photoalignment, the liquid crystal can be aligned according to the designed pattern, leading to components such as gratings, lenses or general wavefront shaping devices. The functionality and efficiency of the component is strongly influenced by how well the LC follows the imposed alignment pattern. Next to a considerable tilting of the LC at the air interface, we report on the observation of symmetry breaking in polymerized LC polarization gratings. By carefully analyzing the experimental and numerical data for gratings with different periods, we conclude that the non-negligible homeotropic anchoring strength at the air interface is responsible for the tilt angle and the symmetry breaking. The role of anchoring strength at the photoaligned and air interface and other parameters are investigated.

Photoaligned Liquid Crystal Devices with Switchable Hexagonal Diffraction Patterns.

Highly efficient optical diffraction can be realized with the help of micrometer-thin liquid crystal (LC) layers with a periodic modulation of the director orientation. Electrical tunability is easily accessible due to the strong stimuli-responsiveness in the LC phase. By using well-designed photoalignment patterns at the surfaces, we experimentally stabilize two dimensional periodic LC configurations with switchable hexagonal diffraction patterns. The alignment direction follows a one-dimensional periodic rotation at both substrates, but with a 60° or 120° rotation between both grating vectors. The resulting LC configuration is studied with the help of polarizing optical microscopy images and the diffraction properties are measured as a function of the voltage. The intricate bulk director configuration is revealed with the help of finite element Q-tensor simulations. Twist conflicts induced by the surface anchoring are resolved by introducing regions with an out-of-plane tilt in the bulk. This avoids the need for singular disclinations in the structures and gives rise to voltage induced tuning without hysteretic behavior.

Ring-shaped liquid crystal structures through patterned planar photo-alignment.

Patterned liquid crystal (LC) configurations find widespread applications in functional devices such as lenses, gratings, displays and soft-robots. In combination with external stimuli such as an applied electric field, photo-alignment at the surfaces offers an attractive way to stabilize different LC structures in the bulk of a device. Herein, a planar LC cell is developed using a photo-alignment layer at the bottom substrate and a rubbed nylon film at the top substrate. Patterned planar photo-alignment is achieved by modulating the linear polarization with a spatial light modulator (SLM) and projecting the pattern onto the bottom substrate. A ring pattern is written into the photo-alignment layer with a continuous rotation between an inner radius and an outer radius. In the other regions the alignment is parallel to the rubbing direction at the top substrate. Four different LC configurations are observed: structure A in which a ring-shaped region is formed with an out of plane (vertical) orientation perpendicular to the substrate, structure B which has a single disclination loop and a 180° twist at the inner region of the photo-patterned ring (r < rin), structure C which has no discontinuities but a 360° twist in the inner region of the photo-patterned ring (r < rin) and structure D with 2 disclination loops. The LC director configuration for all 4 structures is simulated through finite element (FE) Q-tensor simulations and the optical transmission for each structure is simulated using a generalized beam propagation method.

Dual Light and Temperature Responsive Micrometer-Sized Structural Color Actuators.

Externally induced color- and shape-changes in micrometer-sized objects are of great interest in novel application fields such as optofluidics and microrobotics. In this work, light and temperature responsive micrometer-sized structural color actuators based on cholesteric liquid-crystalline (CLC) polymer particles are presented. The particles are synthesized by suspension polymerization using a reactive CLC monomer mixture having a light responsive azobenzene dye. The particles exhibit anisotropic spot-like and arc-like reflective colored domains ranging from red to blue. Electron microscopy reveals a multidirectional asymmetric arrangement of the cholesteric layers in the particles and numerical simulations elucidate the anisotropic optical properties. Upon light exposure, the particles show reversible asymmetric shape deformations combined with structural color changes. When the temperature is increased above the liquid crystal-isotropic phase transition temperature of the particles, the deformation is followed by a reduction or disappearance of the reflection. Such dual light and temperature responsive structural color actuators are interesting for a variety of micrometer-sized devices.

Mode coupling by scattering in chiral nematic liquid crystal ring lasing.

Lasing in dye-doped chiral nematic liquid crystal can be realized with low pump energy and relatively high efficiency, thanks to the high reflectivity of the periodic structure. When the helical axis is oriented perpendicular to the substrates, the main lasing peak is normal to the substrates. In some cases, ring lasing of a particular wavelength is observed into an emission cone with axial symmetry. In this paper we explain how scattering of light in the liquid crystal layer leads to optical coupling between normal modes and inclined modes. Based on a numerical model that takes into account spontaneous emission, gain and scattering we show that scattering leads to emission characteristics that are similar to experimental results.

Voltage-controlled formation of short pitch chiral liquid crystal structures based on high-resolution surface topography.

Chiral nematic liquid crystals (CLCs) offer interesting perspectives for device applications and are fascinating materials to study because of their ability to self-assemble into complex structures. This work demonstrates that narrow lines of electron-beam resist on top of an ITO coated glass surface can dramatically influence the formation and growth of short pitch chiral superstructures in the bulk. By applying a voltage to the cell, directional growth of CLC structures along the corrugated surface can be controlled. Below the electric unwinding threshold, chiral structures start to grow along the grating lines with their helical axis parallel to the substrates. This results in a uniform lying helix-like structure at intermediate voltages and a chiral configuration with periodic undulations of the helical axis at low voltages.

Complex liquid crystal superstructures induced by periodic photo-alignment at top and bottom substrates.

The formation of nematic liquid crystal (LC) superstructures in cells with non-uniform photo-alignment at the confining substrates is studied experimentally and by simulations. An interference pattern of left- and right-handed circularly polarized light is used to define the alignment at both substrates separately, so that the alignment varies along the x-coordinate on one substrate and along the y-coordinate on the other substrate. The interplay between the complex surface alignment and the liquid crystalline soft matter leads to the formation of interesting 3D configurations. The periodic LC structures that are formed in the bulk of the cell are analyzed experimentally by polarizing optical microscopy (POM) for different applied voltages. In the region with strong photo-alignment at both substrates, a 2D LC polarization grating (PG) with a complex 3D director configuration is formed. Distinct periodic structures with different symmetry properties are observed in the regions with weak illumination at the top and/or bottom substrate. The director configuration in the different regions was successfully simulated with the help of finite element (FE) Q-tensor simulations. The agreement between the simulations and the experiments was verified by comparing the POM images with simulated results for the transmission between crossed polarizers.

Multi-electrode tunable liquid crystal lenses with one lithography step.

Electrically tunable lenses offer the possibility to control the focal distance by applying an electric field. Different liquid crystal tunable lenses have been demonstrated. In order to minimize lens aberrations, multi-electrode designs allow us to fine-tune the applied voltages for every possible focal distance. In this Letter, we provide a novel multi-electrode design in which only one lithography step is necessary, thereby offering a greatly simplified fabrication procedure compared to earlier proposed designs. The key factor is the use of a high-permittivity layer, in combination with floating electrodes.