RESUMO
Despite many years of experience in the incineration of solid fuels from waste, the heterogeneity of solid fuels and their varying properties still pose a challenge for a stable and clean combustion in large-scale incineration plants. In modern facilities such as municipal waste incineration plants there still exists a lack of knowledge on the exact amount and calorific value of waste entering onto the grate. Based on the works of Warnecke et al. and Zwiellehner et al., in our project 'AdOnFuelControl', we determined the initial bulk density at the feed hopper by measuring the weight of the waste via the crane weigher and the volume via a high-performance 3D laser scanner. With the help of the determined bulk density, the lower heating value (LHV) and the compression in the feed hopper were calculated. All this information was integrated into the combustion control system, which provided a high potential for an optimized operation of the plant. In this article, six different fuels (fresh and aged municipal solid waste, refuse-derived fuel (fluff), refuse-derived fuel (fine grain), waste wood and dried, grained sewage sludge) were examined for the elemental composition, the LHV, fuel-specific parameters and the compression behaviour. In addition, initial tests with the 3D laser scanner as well as formulas for the calculation of the density in the feed hopper were presented. Based on the results of the experiments, the chosen approach seems very promising for optimized combustion control in large-scale incineration plants. As a next step, the gained knowledge and technology should be integrated in the municipal waste incineration plant.
Assuntos
Incineração , Resíduos Sólidos , Incineração/métodos , Resíduos Sólidos/análise , EsgotosRESUMO
Nanoscale titanium dioxide (nTiO2 (Hombikat UV 100 WP)) was applied to sewage sludge that was incinerated in a large-scale waste treatment plant. The incineration ash produced was applied to soil as fertilizer at a realistic rate of 5% and investigated in pilot plant simulations regarding its leaching behavior for nTiO2. In parallel, the applied soil material was subject to standard column leaching (DIN 19528) in order to test the suitability of the standard to predict the leaching of nanoscale contaminants from treated soil material. Relative to the reference material (similar composition but without nTiO2 application before incineration) the test material had a total TiO2 concentration, increased by a factor of two or 3.8 g/kg, respectively. In contrast, the TiO2 concentration in the respective leachates of the simulation experiment differed by a factor of around 25 (maximum 91.24 mg), indicating that the added nTiO2 might be significantly mobilisable. Nanoparticle specific analysis of the leachates (spICP-MS) confirmed this finding. In the standard column elution experiment the released amount of TiO2 in the percolates between test and reference material differed by a factor of 4 to 6. This was also confirmed for the nTiO2 concentrations in the percolates. Results demonstrate that the standard column leaching, developed and validated for leaching prediction of dissolved contaminants, might be also capable to indicate increased mobility of nTiO2 in soil materials. However, experiments with further soils are needed to verify those findings.
RESUMO
The market for products containing engineered nanomaterial (ENM) is constantly expanding. At the end of their lifecycle, a significant fraction of the products will be disposed as ENM-containing waste in thermal treatment plants. Up to now there are still uncertainties on the fate and behaviour of ENM during waste incineration. In our investigations, nano titanium dioxide (nTiO2) was selected as an example for ENM, because of its high amount in consumer products and its relevance to the ENM-containing waste stream. Two test series were conducted at the municipal solid waste incineration plant "Gemeinschaftskraftwerk Schweinfurt". For each test series, background concentrations of titanium were measured first. Samples of bottom ash, bottom ash extractor water, fly ash (boiler ash, cyclone ash), flue gas cleaning products (spray absorber ash, fabric filter ash) and washing water from the wet scrubber were taken in order to determine the fate of nTiO2. The flue gas was sampled at three points: after boiler, after cyclone and before stack. The experiments showed that most of the used reference material was located in the solid residues (i.e. bottom ash) while a smaller part was detected in the products of the flue gas cleaning. In the purified flue gas before the stack, the concentration was negligible. The flue gas cleaning system at the Gemeinschaftskraftwerk Schweinfurt complies with the requirements of the best available techniques and the results cannot be transferred to plants with lower standards.
