Chromium (III) and chromium (VI) removal and organic matter interaction with nanofiltration.

Chromium (Cr) is a toxic inorganic contaminant for drinking water, in which the concentration has to be controlled for human health and safety. Cr retention was investigated with stirred cell experiments using sulphonated polyethersulfone nanofiltration (NF) membranes of different molecular weight cut-off (MWCO). Cr(III) and Cr(VI) retention follow the order of the MWCO of the studied NF membranes; HY70-720 Da > HY50-1000 Da > HY10-3000 Da with a pH dependency, especially for Cr(III). The importance of the charge exclusion was highlighted when Cr(OH)4- (for Cr(III)) and CrO42- (for Cr(VI)) was the predominant species in the feed solution. In presence of organic matter, namely humic acid (HA), Cr(III) retention increased by 60 %, while no influence of HA was observed for Cr(VI). HA did not induce major modifications on the membrane surface charge for these membranes. Solute-solute interaction, in particular Cr(III)-HA complexation, was the responsible mechanism for the increase in Cr(III) retention. This was confirmed by asymmetric flow field-flow fractionation, coupled with inductively coupled plasma mass spectrometry (FFFF-ICP-MS) analysis. Cr(III)-HA complexation was significant at HA concentrations as low as 1 mgC/L. The chosen NF membranes were able to achieve the EU guideline (25 µg/L) for Cr in drinking water for a feed concentration of 250 µg/L.

Photoconductivity in Metal-Organic Framework (MOF) Thin Films.

Photoconductivity is a characteristic property of semi-conductors. Herein, we present a photo-conducting crystalline metal-organic framework (MOF) thin film with an on-off photocurrent ratio of two orders of magnitude. These oriented, surface-mounted MOF thin films (SURMOFs), contain porphyrin in the framework backbone and C60 guests, loaded in the pores using a layer-by-layer process. By comparison with results obtained for reference MOF structures and based on DFT calculations, we conclude that donor-acceptor interactions between the porphyrin of the host MOF and the C60 guests give rise to a rapid charge separation. Subsequently, holes and electrons are transported through separate channels formed by porphyrin and by C60 , respectively. The ability to tune the properties and energy levels of the porphyrin and fullerene, along with the controlled organization of donor-acceptor pairs in this regular framework offers potential to increase the photoconduction on-off ratio.