Particles-involved photochemical processes: A review for the case of mercury reduction in relation to aquatic mercury cycling.

Mercury (Hg) is one of the toxic metals of global and environmental concern, with aquatic Hg cycling being central in determining the production of highly toxic methylmercury and the air-water Hg exchange influencing the long-range intercontinental atmospheric Hg transport. Both inorganic and organic forms of Hg can be bound by suspended particles, including inorganic minerals (in particular metal oxides/sulfides) and particulate organic matter. Photochemical transformation is a critical process in surface water, and the role of suspended particles in Hg redox photoreactions has increasingly emerged, albeit in limited studies in comparison to extensive studies on aqueous (homogeneous) photoreactions of Hg. The lack of understanding of what roles suspended particles play might result in inaccurate estimation of how Hg species transform and/or cycle in the environment. In view of this gap, this paper critically reviews and synthesizes information on the studies conducted on different natural surface waters with respect to the potential roles of suspended particles on Hg photo-redox reactions. It robustly discusses the various possible pathways and/or mechanisms of particle-mediated Hg (II) reduction, in enhancing or lowering the production of dissolved gaseous mercury. These processes include photo hole-electron pair formation and reactive oxygen species generation from particle excitation and their involvement in Hg photoreduction, in addition to the light attenuation effect of particles. This paper highlights the necessity of future studies exploiting these particles-mediated Hg photoreactions pathways and the implications of including these heterogeneous photoreactions (together with particulate elemental Hg species) on the air-water Hg exchange estimation.

Facile fabrication and antibacterial properties of chitosan/acrylamide/gold nanocomposite hydrogel incorporated with Chaetomium globosium extracts from Gingko biloba leaves.

Microorganisms are a unique part of our ecosystem because they affect the survival of living organisms. Although pathogenic microorganisms could be detrimental to the plants, animals, and humans, beneficial microbes have provided significant improvement in the growth and development of living organisms. In this study, the fungus Chaetomium globosium was isolated from the medicinal tree Gingko biloba, and then incorporated into a polymerization system to fabricate chitosan/acrylamide/gold (CS/Am/Au) nanocomposite hydrogels. The as-prepared hydrogel displayed increased mechanical strength due to the reinforcement of Au (gold) nanocomposites within the hydrogel matrix. Also, the equilibrium pH responsive swelling rates of the hydrogels gradually increased as the pH increases due to partial acid and basic hydrolysis occurring in the hydrogel as well as formation of hydrogen bond. In addition, the hydrogel demonstrated promising antibacterial activities against selected gram-positive (Staphylococcus epidermidis and Staphylococcus aureus) and gram-negative (Pseudomonas aeruginosa) bacterial strains with an average MIC90 of 0.125 mg/mL at a dosage of 1.0 mg/L. The obtained results are quite promising towards resolving several health challenges and advancing the pharmaceutical industries.

Engineered yeasts and lignocellulosic biomaterials: shaping a new dimension for biorefinery and global bioeconomy.

The next milestone of synthetic biology research relies on the development of customized microbes for specific industrial purposes. Metabolic pathways of an organism, for example, depict its chemical repertoire and its genetic makeup. If genes controlling such pathways can be identified, scientists can decide to enhance or rewrite them for different purposes depending on the organism and the desired metabolites. The lignocellulosic biorefinery has achieved good progress over the past few years with potential impact on global bioeconomy. This principle aims to produce different bio-based products like biochemical(s) or biofuel(s) from plant biomass under microbial actions. Meanwhile, yeasts have proven very useful for different biotechnological applications. Hence, their potentials in genetic/metabolic engineering can be fully explored for lignocellulosic biorefineries. For instance, the secretion of enzymes above the natural limit (aided by genetic engineering) would speed-up the down-line processes in lignocellulosic biorefineries and the cost. Thus, the next milestone would greatly require the development of synthetic yeasts with much more efficient metabolic capacities to achieve basic requirements for particular biorefinery. This review gave comprehensive overview of lignocellulosic biomaterials and their importance in bioeconomy. Many researchers have demonstrated the engineering of several ligninolytic enzymes in heterologous yeast hosts. However, there are still many factors needing to be well understood like the secretion time, titter value, thermal stability, pH tolerance, and reactivity of the recombinant enzymes. Here, we give a detailed account of the potentials of engineered yeasts being discussed, as well as the constraints associated with their development and applications.

Metabolic pathways of an organism depict its chemical repertoire and its genetic makeup.Autonomous synthetic microbes can be developed for lignocellulose biorefinery (LCB).LCBs can be harnessed with synthetic microbes to boost global bioeconomy.Yeasts can be engineered to enhance downstream process of LCB.

Analytical approaches for screening of per- and poly fluoroalkyl substances in food items: A review of recent advances and improvements.

Per and polyfluoroalkyl substances (PFAS) are a group of man-made chemicals characterized by their ubiquitous nature in all environmental compartments which makes them of increasing concern due to their persistence, bioaccumulation, and toxicity (PBT). Several instrumental methodologies and separation techniques have been identified in the literature for the detection and quantification of PFAS in environmental samples. In this review, we have identified and compared common separation techniques adopted for the extraction of PFAS in food items, and analytical methodologies for identification and quantification of PFAS in food items of plant and animal origin, highlighting recent advances in tandem techniques for the high selectivity and separation of PFAS related compounds as well as knowledge gaps and research needs on current analytical methodologies.

Nanomaterials as catalysts for CO2 transformation into value-added products: A review.

Carbon dioxide (CO2) is the most important greenhouse gas (GHG), accounting for 76% of all GHG emissions. The atmospheric CO2 concentration has increased from 280 ppm in the pre-industrial era to about 418 ppm, and is projected to reach 570 ppm by the end of the 21st century. In addition to reducing CO2 emissions from anthropogenic activities, strategies to adequately address climate change must include CO2 capture. To promote circular economy, captured CO2 should be converted to value-added materials such as fuels and other chemical feedstock. Due to their tunable chemistry (which allows them to be selective) and high surface area (which allows them to be efficient), engineered nanomaterials are promising for CO2 capturing and/or transformation. This work critically reviewed the application of nanomaterials for the transformation of CO2 into various fuels, like formic acid, carbon monoxide, methanol, and ethanol. We discussed the literature on the use of metal-based nanomaterials, inorganic/organic nanocomposites, as well as other routes suitable for CO2 conversion such as the electrochemical, non-thermal plasma, and hydrogenation routes. The characteristics, steps, mechanisms, and challenges associated with the different transformation technologies were also discussed. Finally, we presented a section on the outlook of the field, which includes recommendations for how to continue to advance the use of nanotechnology for conversion of CO2 to fuels.

Occurrence, detection and ecotoxicity studies of selected pharmaceuticals in aqueous ecosystems- a systematic appraisal.

Pharmaceutical compounds (PCs) have globally emerged as a significant group of environmental contaminants due to the constant detection of their residues in the environment. The main scope of this review is to fill the void of information on the knowledge on the African occurrence of selected PCs in environmental matrices in comparison with those outside Africa and their respective toxic actions on both aquatic and non-aquatic biota through ecotoxicity bioassays. To achieve this objective, the study focused on commonly used and detected pharmaceutical drugs (residues). Based on the conducted literature survey, Africa has the highest levels of ciprofloxacin, sulfamethoxazole, lamivudine, acetaminophen, and diclofenac while Europe has the lowest of all these PC residues in her physical environments. For ecotoxicity bioassays, the few data available are mostly on individual groups of pharmaceuticals whereas there is sparsely available data on their combined forms.

Phytoremediation technology and food security impacts of heavy metal contaminated soils: A review of literature.

Heavy metal accumulation in soil and water is one of major problems caused by inorganic contaminants. Their presence in agricultural soils in high quantities have impacted the food security significantly and, by extension, the human health. Amongst various physico-chemical methods available for remediation of heavy-metals-polluted-sites, phytoremediation approaches have been found to be safe and environment friendly. This review gathered scattered information on heavy metal phytoremediation studies published in both review and research articles. It described the impact of heavy metals on food security and comprehensively discussed the application of different phytoremediation approaches for treatment of heavy metal-polluted soils, the basic principles underlining them, their strengths and weaknesses. Our findings indicated that, while hundreds of hyper-accumulator plants are being reported yearly, only few describe limitations inherent in them, such as low growth rate, low biomass production, and low metal tolerance. Hence, this review also gave a detailed overview of research gaps in phytotechnology and advocates consideration of the 'omics' studies; genomics, proteomics, metabolomics and likes in selecting and enhancing potential plants for phytoremediation. For a sustainable large-scale phytoremediation application, we established a multi-technology repair strategy via the combination of different methods like application of biological composts, plant-growth promoting microorganisms, and phytohormones for stimulation of the plant-growth during phytoremediation. We also gave comprehensive insights to proper disposal of plants used for phytoremediation, this subject is often not well considered/planned while deciding the application of plants for removal of heavy metals from polluted environments.

Natural, low-cost adsorbents for toxic Pb(II) ion sequestration from (waste)water: A state-of-the-art review.

Pb(II) ions is an inorganic pollutant that is present in the environment. Its presence affects both human health and ecosystem. Economically, amongst many wastewater treatment approaches, adsorption is both cheap and environmentally friendly for removing Pb(II) ion from contaminated water. In this state of the art review, about 227 research and review based publications on adsorption-based studies between 1989 and 2021, which have used various materials as adsorbents of Pb (II) ions, were selected and reviewed for more evaluation. A number of adsorbents which have been reported in these literatures for the adsorption of Pb(II) ion are agrobased, modified agrobased, clay minerals, modified/nanocomposite clay minerals, silica-based, zeolite-based and chitosan-based adsorbents, respectively. The adsorption potential of the adsorbents is exhibited under optimum experimental conditions. The unmodified and modified agro based adsorbents were shown to exhibit the greatest Pb(II) adsorption capacity, with great potential for further exploration, compared to the others afore-listed. The effects of operating parameters such as pH, initial metal ion concentration, adsorbent dose and reaction time are discussed. Furthermore, in order to comprehend the nature of adsorption process between the adsorbent and contaminant (Pb(II)), thermodynamic analyses of adsorption systems are intensively described. All these discussions revealed the applicability of adsorption process for toxic Pb(II) ions removal with respect to wastewater treatment techniques. The review concludes by commenting on the various adsorbents' adsorption capacity and proposes some studies that should also be considered in future works.