Probing densified silica glass structure by molecular oxygen and E' center formation under electron irradiation.

This study aims to learn more about the structure of densified silica with focus on the metamict-like silica phase (density = 2.26 g/cm3) by examining the formation of E' point defects and interstitial molecular oxygen O2 by 2.5 MeV electron irradiation. High-dose (11 GGy) irradiation creates a metamict-like phase and a large amount of interstitial O2, which is destroyed upon subsequent additional lower-dose electron irradiation. The O2 cathodoluminescence (CL) data indicate that the formation of O2 from peroxy linkages Si-O-O-Si in silica network is strongly dependent on the intertetrahedral void sizes. The position and shape of the O2 emission line support the idea that the configuration of these voids in metamict phase is close to that of non-densified silica. Moreover, data support the strong correlation between the formation of 3-membered rings of Si-O bonds and E'-centers when silica density increases from 2.20 to 2.26 g/cm3.

An uranyl sorption study inside functionalised nanopores.

Sorption mechanism of uranyl by poly(bis[2-(methacryloyloxy)ethyl] phosphate) (PB2MP) functionalised polyvinylidene fluoride (PVDF) track-etched membranes, PB2MP-g-PVDF, was investigated. It was found that uranyl sorption obeyed Langmuir isotherm model giving a maximum U(VI) membrane uptake of 6.73 µmol g-1 and an affinity constant of 9.85 â‹… 106 L mol-1. XPS and TRPL measurements were performed to identify sorbed uranyl oxidation state and its environment. Uranyl was found to be mainly in its hexavalent state, i.e. U(VI), showing that the trapping inside the PB2MP-g-PVDF nanoporous membranes did not change the ion speciation. Two sorbed uranyl life-times (τ1 = 8.8 µs and τ2 = 102.8 µs) were measured by TRPL which pointed out different complexations taking place inside the nanopores. Uranyl sorption by PB2MP-g-PVDF membranes was also found to be pH dependent demonstrating the highest performance at circumneutral pH. In addition, TRPL was demonstrated to be not only a remarkable technique for U(VI) characterization, but also an alternative to voltammetry detection for trace on-site uranyl monitoring using PB2MP-g-PVDF nanoporous membranes.

In situ observation of the Yb2+ emission in the radiodarkening process of Yb-doped optical preform.

This Letter relates the clear evidence of Yb2+ formation under 2.5 MeV electron irradiation in optical fiber preforms showing a darkening of the core. We thus detected by in situ photoluminescence measurements the green emission of divalent Yb2+ under the 355 nm excitation. Moreover, we showed the existence of two types of Yb2+ ion species with different stabilities. We demonstrated that the radiodarkening mechanism is based on a pair association of Yb2+ with aluminum oxygen hole center point defects.

Clusters dissolution of Yb3+ in codoped SiO2-Al2O3-P2O5 glass fiber and its relevance to photodarkening.

Using a combination of pulse electron paramagnetic resonance and photoluminescence spectroscopy, we demonstrate the major role of phosphorous rather than aluminium in the rare-earth dissolution process, an essential advance in telecommunication and solid laser fields. Our results also provide new insight into the micro-structural origin of the photodarkening process occurring in Yb doped fiber.