RESUMO
OBJECTIVES: The coordination of glenohumeral (GH) and scapular movements is central to the injury prevention of baseball pitchers. However, there is no objective data establishing the direct relationship between pitching injuries and associated GH and scapular movements. Therefore, this study demonstrated the biomechanical differences in the scapular and GH movements during pitching between injury-prone pitchers and healthy college baseball pitchers. METHODS: A total of 30 collegiate baseball pitchers were classified into two groups according to their injury status: injury-prone group (n = 15) and control group (n = 15). We obtained pitching motion data using three-dimensional motion analysis technique. RESULTS: The horizontal abduction angles of the GH joint during cocking and acceleration phases were considerably greater in the injury-prone pitchers (19.0° at stride foot contact [SFC], -4.0° at maximum external rotation [MER], and -0.3° at ball release) than those in healthy controls (11.7° at SFC, -10.0° at MER, and -6.9° at ball release). Additionally, in the cocking phase, the amount of angular change in the scapular external rotation (ER) was significantly smaller in the injury-prone group than that in the control group (mean difference, -13.0). CONCLUSION: These results suggest that the injury-prone pitchers have less internal rotation of the scapula and a more horizontal abduction of the GH joint during the cocking and acceleration phases. Therefore, sports medicine practitioners may need to pay considerable attention to the coordination of scapular and GH horizontal movements during pitching for prevention of shoulder injuries.
RESUMO
Most nonplatinum group metal (non-PGM) catalysts for polymer electrolyte fuel cell cathodes have so far been limited to iron(cobalt)/nitrogen/carbon [Fe(Co)/N/C] composites owing to their high activity in both half-cell and single-cell cathode processes. Group IV and V metal oxides, another class of non-PGM catalysts, are stable in acidic media; however, their activities have been mostly evaluated for half-cells, with no single-cell performances comparable to those of Fe/N/C composites reported to date. Herein, we report successful syntheses of zirconium oxynitride catalysts on multiwalled carbon nanotubes, which show the highest oxygen reduction reaction activity among oxide-based catalysts. The single-cell performance of these catalysts reached 10 mA cm-2 at 0.9 V, being comparable to that of state-of-the-art Fe/N/C catalysts. This new record opens up a new pathway for reaching the year 2020 target set by the U.S. Department of Energy, that is, 44 mA cm-2 at 0.9 V.
RESUMO
Titanium oxides crystals are widely used in a variety of fields, but little has been reported on the functionalities of noncrystalline intermediates formed in their structural transformation. We measured the oxygen reduction reaction activity of titanium oxide nanoparticles heat-treated for a different time and found that the activity abruptly increased at a certain time of the treatment. We analyzed their structures by using X-ray pair distribution functions with the help of high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy and ascertained that the abrupt increase in the activity corresponded to a structural transformation from a reduced lepidocrocite-type layered titanate to a disordered structure consisting of domains of brookite-like TiO6 octahedral linkages. The further treatment transformed these brookite-like domains into another phase having more edge-sharing sites like the TiO-type cubic structure. This finding would position noncrystalline, disordered structure as a possible origin of the catalytic activity, though nanocrystalline rutile particles might be also considered as the origin.
