Preparation of degradable chemically cross-linked polylactic acid films and its application on disposable straws.

The semi-rigidity of the polylactic acid (PLA) molecular chain makes it brittle, poor impact resistance and barrier properties, which severely limits its practical applications. In this paper, a bio-based reactive plasticizer epoxy soybean oil (ESO) was used to improve the mechanical and barrier properties of maleic anhydride grafted polylactic acid (MAPLA) by the chemical reaction between the epoxy and anhydride group. Firstly, the optimum curing conditions were 93.5 °C, 100 °C, and 110.8 °C for 2 h. The effects of different mass fractions of ESO on the properties of MAPLA-ESO (ME) films were systematically investigated. It was found that when the content of ESO was 10 wt%, the tensile properties of the resulting ME films were the best, with a tensile strength of 35.2 MPa. And it had an elongation at break of 20.0 % and toughness of 5.4 MJ/m3, which increased to 690 % and 675 %, respectively, compared with pure MAPLA films. The chemically crosslinked ME films also displayed excellent water resistance, well degradation, low migration properties, and better performance than that of commercial paper straws and PLA straws, exhibiting great application potential as degradable disposable straws. Therefore, this work provides an effective way to develop high-performance, green, and degradable PLA films and products.

Water-Induced Self-Assembly and In Situ Mineralization within Plant Phenolic Glycol-Gel toward Ultrastrong and Multifunctional Thermal Insulating Aerogels.

Biopolymer/silica nanocomposite aerogels are highly attractive as thermally insulating materials for prevailing energy-saving engineering but are usually plagued by their lack of mechanical strength and environmental stability. Lignin is an appealing plant phenolic biopolymer due to its natural abundance, high stiffness, water repellency, and thermostability. However, integrating lignin and silica into high-performance 3D hybrid aerogels remains a substantial challenge due to the unstable co-sol process. In diatoms, the silicic acid stabilization prior to the condensation reaction is enhanced by the intervention of biomolecules in noncovalent interactions. Inspired by this mechanism, we herein rationally design an ultrastrong silica-mineralized lignin nanocomposite aerogel (LigSi) with an adjustable multilevel micro/nanostructure and arbitrary machinability through an unusual water-induced self-assembly and in situ mineralization based on ethylene glycol-stabilized lignin/siloxane colloid. The optimized LigSi exhibits an ultrahigh stiffness (a specific modulus of ∼376.3 kN m kg-1) and can support over 5000 times its own weight without obvious deformation. Moreover, the aerogel demonstrates a combination of outstanding properties, including superior and humidity-tolerant thermal insulation (maintained at ∼0.04 W m-1 K-1 under a relative humidity of 33-94%), excellent fire resistance withstanding an ∼1200 °C flame without disintegration, low near-infrared absorption (∼9%), and intrinsic self-cleaning/superhydrophobic performance (158° WCA). These advanced properties make it an ideal thermally insulating material for diversified applications in harsh environments. As a proof of concept, a dual-mode LigSi thermal device was designed to demonstrate the application prospect of combining passive heat-trapping and active heating in the building.

Design of Intrinsically Flame-Retardant Vanillin-Based Epoxy Resin for Thermal-Conductive Epoxy/Graphene Aerogel Composites.

Vanillin, as a lignin-derived mono-aromatic compound, has attracted increasing attention due to its special role as an intermediate for the synthesis of different biobased polymers. Herein, intrinsically flame-retardant and thermal-conductive vanillin-based epoxy/graphene aerogel (GA) composites were designed. First, a bifunctional phenol intermediate (DN-bp) was synthesized by coupling vanillin with 4, 4'-diaminodiphenylmethane and DOPO, and the epoxy monomer (MEP) was obtained by the epoxidation reaction with DN-bp and epichlorohydrin. Then, various amounts of MEP and diglycidyl ether of bisphenol A (DER) were mixed and cured. Interestingly, the flexural strength and modulus were greatly enhanced from 72.8 MPa and 1.3 GPa to 90.3 MPa and 2.8 GPa, respectively, at 30 wt % MEP, due to the rigidity of MEP and strong intermolecular N-H hydrogen bonding interactions. Meanwhile, the cured epoxy achieved a UL-94 V0 rating with a low P content of 1.06%. The flame-retardant vanillin-based epoxy was then impregnated into the thermal conductive 3D GA networks. The obtained epoxy/graphene composite showed excellent flame retardancy and thermal conductivity [λ = 0.592 W/(m·K)] with only 0.5 wt % graphene in the system. Based on these results, we believe that this work would represent a novel solution for the preparation of high-performance biobased flame-retardant multipurpose epoxies.

Effects of SiO2 Filler in the Shell and Wood Fiber in the Core on the Thermal Expansion of Core-Shell Wood/Polyethylene Composites.

The influence of nano-silica (nSiO2) and micro-silica (mSiO2) in the shell and wood fiber filler in the core on the thermal expansion behavior of co-extruded wood/polyethylene composites (Co-WPCs) was investigated to optimize the thermal expansion resistance. The cut Co-WPCs samples showed anisotropic thermal expansion, and the thermal expansion strain and linear coefficient of thermal expansion (LCTE) decreased by filling the shell layer with rigid silica, especially nSiO2. Finite element analysis indicated that the polymer-filled shell was mainly responsible for the thermal expansion. The entire Co-WPCs samples exhibited a lower thermal expansion strain than the cut Co-WPCs samples due to protection by the shell. Increasing the wood fiber content in the core significantly decreased the thermal expansion strain and LCTE of the Co-WPCs. The Co-WPCs whose core layer was filled with 70% wood fiber exhibited the greatest anisotropic thermal expansion.