[Luminescence characteristics of PVK doped with Ir(ppy)3].

With the increasing development of organic light emitting devices (OLED), interest in the mechanisms of charge carrier photogeneration, separation, transport and recombination continues to grow. Electromodulation of photoluminescence has been used as an efficient probe to investigate the evolution of primary excitation in all electric field. This method can provide useful information on carrier photogeneration, the formation and dissociation of excitons, energy transfer, and exciton recombination in the presence of electric field. The operation of OLED brings electrons and holes from opposite electrodes and generates singlet and triplet excitons. However, triplet excitons are wasted because a radiative transition from triplets is spin-forbidden. Spin statistics predicts that singlet-to-triplet ratio is 1 : 3 in organic semiconductors. One way to harvest light from triplet excitons is to use phosphorescent materials. These materials incorporate a heavy metal atom to mix singlet and triplet states by the strong spin-orbit coupling. As a result, a spin forbidden transition may occur allowing an enhanced triplet emission. Among phosphorescent materials, Ir(ppy)3 has attracted much attention because of its short triplet lifetime to minimize the triplet-triplet annihilation. High quantum efficiencies have been obtained by doping organic molecules and in polymers with Ir(ppy)3. In the present paper, the photoluminescence and electroluminescence spectra of Ir(ppy)3 doped PVK film are measured at room temperature. The device structure is ITO/PEDOT : PSS/PVK Ir(ppy)3/BCP/Alq3/Al. The results show that the luminescence capabilities of devices are different when the concentration of Ir(ppy)3 is different. When the concentration of Ir(ppy)3 is suitable, the luminescence of PVK is lower but that of Ir(ppy)3 is stronger relatively, indicating that the energy transfer from the host materials to the guest materials is sufficient. It is concluded that the device with 5% of Ir(ppy)3 has the best luminescence properties according to its light power-current-voltage curve, meaning that the best concentration of Ir(ppy)3 in such kind of device is 5%.

[Measurement and analysis of discharge current in dielectric barrier glow discharge at atmospheric pressure].

Dielectric barrier discharge has become a hot issue in low temperature plasma research field because of wide prospect for its application in industry. In the present paper, an uniform glow discharge was realized in atmospheric pressure helium with a parallel planar dielectric barrier discharge device and an uniform plasma was generated in helium at atmospheric pressure. Electrical method was used to separate the discharge current from the total current signal and the waveform of discharge current could be obtained. The relations among the discharge current, applied voltage, gap voltage and wall charge during the uniform glow discharge were used to analyze the dynamical behavior of wall charges during their accumulation. The results show that the wall charges were mainly accumulated during the existence of discharge current pulse, while the quantity of wall charges continued to increase until the gap voltage changed its polarity after the disappearance of discharge current pulse, and finally the quantity of wall charges decreased until the next breakdown. These experimental results are important for the further study of wall charges' effect in the dielectric barrier glow discharge and its application in industry.

[Measurement of molecular vibrational temperature in dielectric barrier discharge in argon/air at atmospheric pressure].

Vibrational temperature of N2 (C 3IIu) molecules in dielectric barrier discharge (DBD) in argon/air at atmospheric pressure, in which the water electrodes were employed, was measured by using a method of spectrum diagnosis. Emission spectral lines of the N2 second positive band system(C 3IIu --> B 3IIg) and the sequences of vibrational bands with deltav = -1, deltav = -2 and deltav = -3 were used in the calculation. The experiment results show that the molecular vibrational temperature of N2 is in the range from 1 938 K to 2 720 K, and it increases almost linearly with increasing the air content in gas mixture. These results are of great importance to the study of plasma dynamics of DBD.