RESUMO
In traditional dual-ion systems, the cathode usually is employed as anion-storage materials. Herein, we propose a new dual-ion hybrid supercapacitor with reverse anion/cation-storage mechanism, consisting of a mesoporous (MPs) VN anode as a pivotal anion-storage material and K2-xMn8O16 nanosheet arrays grown on carbon cloth (NSs/CC) as (K-storage) cathode. During charge/discharge, the anode and cathode reversibly store/release OH- ions and K+ ions, respectively. Herein, the MPs VN as anion-storage electrode can operate in an alkaline condition and deliver a high capacitance of 251 mF cm-2 with desired low-voltage plateau. More importantly, benefiting from unique reverse dual-ion mechanism, the (MPs VN-K2-xMn8O16 NSs/CC) hybrid device displays excellent rate performance and satisfying area capacitance along with good durability of 92.2% after 10,000 cycles at a scan rate of 100 mV s-1. It offers new ideas to expand the range of anion-storage materials in dual-ion hybrid supercapacitors.
RESUMO
Lithium-sulfur (Li-S) batteries show great potential in future electric transportation and large-scale grid storage applications because of their attractive theoretical energy density (2600 W h kg-1) and relatively abundant sulfur reserves. However, the rapid capacity decay and unsatisfactory sulfur loading caused by the lithium polysulphide (LiPS) dissolution and low electrical conductivity of sulfur are the most urgent issues plaguing its practical applications. Herein, we report a multifunctional nanoporous (NP) VN/V2O5 binary host that can efficiently resolve the above conflicts by the synergy between the functions of two materials. The inner V2O5 facilitates rapid trapping of numerous LiPSs while the outer porous VN with abundant NP channels offers high conductivity and mild chemisorption, thereby improving the localization and catalytic conversion ability of LiPSs. Accordingly, the designed cathodes with 1.87 mg cm-2 sulfur content achieve an acceptable areal specific capacity (2.72 mA h cm-2), excellent rate capability (963 mA h g-1 at 5.0C), and cycling stability. Remarkably, the cathodes with ultrahigh sulfur loading of 9.02 mg cm-2 deliver a satisfactory areal specific capacity (12.12 mA h cm-2) and still maintain excellent durability.
RESUMO
The exploitation of clean energy promotes the exploration of next-generation lithium-ion batteries (LIBs) with high energy-density, long life, high safety, and low cost. Ni-rich layered cathode materials are one of the most promising candidates for next-generation LIBs. Numerous studies focusing on the synthesis and modifications of the layered cathode materials are published every year. Many physical features of precursors, such as density, morphology, size distribution, and microstructure of primary particles pass to the resulting cathode materials, thus significantly affecting their electrochemical properties and battery performance. This review focuses on the recent advances in the controlled synthesis of hydroxide precursors and the growth of particles. The essential parameters in controlled coprecipitation are discussed in detail. Some innovative technologies for precursor modifications and for the synthesis of novel precursors are highlighted. In addition, future perspectives of the development of hydroxide precursors are presented.
RESUMO
Hybrid supercapacitors (HSCs) with the characteristics of high energy density, long cycle life and without altering their power density need to be developed urgently. Herein, a novel dual-ion hybrid supercapacitors (DHSCs) with Ni(OH)2 nanotube arrays (NTAs) as positive electrode and V2O5 directly grown on freestanding carbon nanotubes (CNTs) as negative electrode is assembled. In charging mechanism of DHSCs, K+ are inserted into the V2O5 negative while OH- react with Ni(OH)2 positive; during discharge, the K+ and OH- are released from V2O5 negative and Ni(OH)2 positive, respectively, and return back to the electrolyte, which is quite different from traditional metal ion or alkaline supercapacitors. Because of the merits combining dual-ion mechanism and HSCs, the DHSC displays excellent capacity retention of â¼ 81.4% after 10,000 cycles, high energy density of â¼ 25.4 µWh cm-2 and high power density of â¼ 4.66 mW cm-2, indicating the potential applications in the further on flexible wearable electronics.
RESUMO
In this work, combining both advantages of aqueous energy storage systems (ESS) and conventional dual-ion ESS, a novel aqueous dual-ion ESS is developed based on K+ and OH- electrochemistry by employing semi-coherent K1.33Mn8O16-CuO (sc-Mn-Cu) cathode. Profting from the elaborate design, the electrolyte and cathode simultaneously act as source of cations. In the novel aqueous dual-ion ESS configuration, the dependence of the performance on the electrolyte salt concentration is reduced and the sc-Mn-Cu cathode can host OH- with lower working potentials by conversion mechanism. Furthermore, based on the sc-Mn-Cu cathode and freestanding V2O3-VC (fs-V2O3-VC) anode, we developed a flexible quasi-solid-state device. Remarkably, it exhibits an ultrahigh energy density of ~39.9 µW h cm-2 together with high power density of carbon-based devices, which outperforms most previously reported flexible storage devices to our knowledge. These results indicating that the unique mechanism of the sc-Mn-Cu cathode opens up a promising direction for low-cost and high-performance novel aqueous ESS.